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1. 发明授权

US08628682B2 Compositions comprising a fluorosurfactant and a hydrotrope 失效
标题翻译：包含含氟表面活性剂和水溶助长剂的组合物
公开(公告)号：US08628682B2
公开(公告)日：2014-01-14
申请号：US13279536
申请日：2011-10-24
申请人： Thomas G. Calvarese , Yamaira Gonzalez , Viacheslav A. Petrov , Weiming Qiu , Anilkumar Raghavanpillai
发明人： Thomas G. Calvarese , Yamaira Gonzalez , Viacheslav A. Petrov , Weiming Qiu , Anilkumar Raghavanpillai
IPC分类号： C09K13/08
CPC分类号： C11D1/004 , C09D7/45 , C09D7/63 , C11D3/245 , C11D3/30 , C11D3/3418 , C11D3/367
摘要： Compositions comprising a fluorosurfactant and a hydrotrope are disclosed. The hydrotropes are either cationic or anionic benzene derivatives comprising fluoro-substituted functional groups and polar groups. The compositions are useful in various surfactant applications.
摘要翻译：公开了包含含氟表面活性剂和水溶助长剂的组合物。水溶助长剂是包含氟取代官能团和极性基团的阳离子或阴离子苯衍生物。该组合物可用于各种表面活性剂应用。

2. 发明申请

US20140073707A1 COMPOSITIONS COMPRISING A FLUOROSURFACTANT AND A FLUORO-FREE HYDROTROPE 审中-公开
标题翻译：包含氟化物和无氟氢化合物的组合物
公开(公告)号：US20140073707A1
公开(公告)日：2014-03-13
申请号：US13612960
申请日：2012-09-13
申请人： Thomas G. Calvarese , Weiming Qiu , Anilkumar Raghavanpillai , Yamaira Gonzalez
发明人： Thomas G. Calvarese , Weiming Qiu , Anilkumar Raghavanpillai , Yamaira Gonzalez
IPC分类号： A01N57/12 , C09D7/12 , C09D11/00 , C09K3/00 , C11D1/58 , C09K13/00 , C09G1/18 , C09K15/30 , A61K8/69 , C11D1/34 , A01N43/40 , C09K15/20
CPC分类号： A01N57/12 , A01N25/30 , A01N43/40 , A61K8/0208 , A61K8/416 , A61K8/69 , A61Q17/005 , A61Q19/00 , C08K5/09 , C08K5/17 , C08K5/42 , C08K5/52 , C08K5/53 , C09D7/47 , C09D11/00 , C09D11/03 , C09G1/18 , C09K3/00 , C09K13/00 , C09K15/20 , C09K15/30 , C11D1/004 , C11D1/345 , C11D1/58 , C11D3/2079 , C11D3/2089 , C11D3/30 , C11D3/3409 , C11D3/361 , C11D3/362
摘要： Compositions comprising a fluorosurtactant and a fluoro-free hydrotrope are disclosed. The fluoro-free hydrotropes are cationic aromatic compounds, anionic aromatic compounds, or water soluble azo derivatives.
摘要翻译：公开了包含含氟乳化剂和无氟水溶助长剂的组合物。无氟水溶助长剂是阳离子芳香族化合物，阴离子芳香族化合物或水溶性偶氮衍生物。

3. 发明申请

US20130102685A1 COMPOSITIONS COMPRISING A FLUOROSURFACTANT AND A HYDROTROPE 失效
标题翻译：包含氟化物和氢化物的组合物
公开(公告)号：US20130102685A1
公开(公告)日：2013-04-25
申请号：US13279536
申请日：2011-10-24
申请人： Thomas G. Calvarese , Yamaira Gonzalez , Viacheslav A. Petrov , Weiming Qiu , Anilkumar Raghavanpillai
发明人： Thomas G. Calvarese , Yamaira Gonzalez , Viacheslav A. Petrov , Weiming Qiu , Anilkumar Raghavanpillai
IPC分类号： C09K3/00 , C09K15/00 , C09K13/00 , C09D11/00 , C09K3/16 , A01P1/00 , C09D7/12 , C11D3/00 , A01N25/00
CPC分类号： C11D1/004 , C09D7/45 , C09D7/63 , C11D3/245 , C11D3/30 , C11D3/3418 , C11D3/367
摘要： Compositions comprising a fluorosurfactant and a hydrotrope are disclosed. The hydrotropes are either cationic or anionic benzene derivatives comprising fluoro-substituted functional groups and polar groups. The compositions are useful in various surfactant applications.
摘要翻译：公开了包含含氟表面活性剂和水溶助长剂的组合物。水溶助长剂是包含氟取代官能团和极性基团的阳离子或阴离子苯衍生物。该组合物可用于各种表面活性剂应用。

4. 发明授权

US08212064B2 Ethylene tetrafluoroethylene intermediates 失效
标题翻译：乙烯四氟乙烯中间体
公开(公告)号：US08212064B2
公开(公告)日：2012-07-03
申请号：US12152312
申请日：2008-05-14
申请人： Weiming Qiu , Anilkumar Raghavanpillai , Michael Francis Vincent
发明人： Weiming Qiu , Anilkumar Raghavanpillai , Michael Francis Vincent
IPC分类号： C07C331/02 , C07C19/16 , C07C31/34 , C07C213/00 , C07C69/62
CPC分类号： C08F214/262 , C08F210/02 , C08F214/26 , C08F2/34
摘要： An oligomer of the formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]mG (I) wherein G is an I; OH; OC(O)CH═CH2; OC(O)CCH3═CH2; OC(O)CCl═CH2; NR1H; N3; NCO; SQ wherein Q is H, alkyl, (CH2)nOH, (CH2)nNH2, (CH2)nOC(O)C(Me)=CH2, or (CH2)nNHC(O)C(Me)=CH2; SCN; COOH; SO3H; NHCOCH═CH2; NHCOC(CH3)═CH2); OC(O)NHCH2CH2OC(O)C(CH3)═CH2; or OC(O)NHCH2CH2OC(O)C(CH3)═CH2; subscript n is an integer from 1 to about 6, subscript x is an integer from 1 to about 6, subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof, the total number of carbons in said formula (I) excluding G ranges from about 8 to about 22, and a process for preparation thereof.
摘要翻译：式（I）的低聚物：CnF2n + 1（CH2）x [（CF2CF2）y（CH2CH2）z] mG（I）其中G是I; 哦; OC（O）CH = CH 2; OC（O）CCH 3 = CH 2; OC（O）CCl = CH 2; NR1H; N3; NCO; SQ其中Q是H，烷基，（CH2）nOH，（CH2）nNH2，（CH2）nOC（O）C（Me）= CH2或（CH2）nNHC（O）C（Me）= CH2; SCN; COOH; SO3H; NHCOCH = CH2; NHCOC（CH 3）= CH 2）; OC（O）NHCH 2 CH 2 OC（O）C（CH 3）= CH 2; 或OC（O）NHCH 2 CH 2 OC（O）C（CH 3）= CH 2; 下标n是1至约6的整数，下标x是1至约6的整数，下标y，z和m各自独立地为1,2或3，或其混合物，所述式中的碳总数（I），其中不包括G范围为约8至约22，及其制备方法。

5. 发明授权

US08128711B2 Fluoropolymer compositions and treated substrates 失效
标题翻译：含氟聚合物组合物和经处理的基材
公开(公告)号：US08128711B2
公开(公告)日：2012-03-06
申请号：US13108507
申请日：2011-05-16
申请人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
发明人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
IPC分类号： D06M15/423 , B32B27/40 , B32B27/00
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—xH (I) wherein Rf is a perfluoroalkyl group having 1 to about 6 carbon atoms; the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22; and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译：具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R1）r-xH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; 和（ii）任选地与（c）水，连接剂或其混合物反应。

6. 发明申请

US20110217506A1 FLUOROPOLYMER COMPOSITIONS AND TREATED SUBSTRATES 失效
标题翻译：氟聚合物组合物和处理的基材
公开(公告)号：US20110217506A1
公开(公告)日：2011-09-08
申请号：US13108507
申请日：2011-05-16
申请人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
发明人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
IPC分类号： D05C17/00 , D06M15/576 , B05D1/02 , B05D1/28 , B05D1/18 , D02G3/00 , B32B27/00
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—XH (I) wherein Rf is a perfluoroalkyl group having 1 to about 6 carbon atoms; subscript x is 1 to about 6; subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof; subscript r is 0 or 1; the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22; X is —O—, —NR—, —S—, —S(CH2)tO—, or —S(CH2)tNR—; subscript t is from 1 to about 10; R is H or C1-4 alkyl; R1 is certain divalent radicals; n is 2 to 4; s is 1 to about 50; R2, R3, and R4 are each independently hydrogen or a C1-C6 alkyl group; and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译：具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R 1）r -XH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 下标x为1〜6; 下标y，z和m各自独立地为1,2或3，或其混合物; 下标r为0或1; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; X是-O-，-NR - ， - S - ， - S（CH 2）t O-或-S（CH 2）t NR-; 下标t为1〜10; R是H或C 1-4烷基; R1是一定的二价基团; n为2〜4; s为1至约50; R2，R3和R4各自独立地为氢或C1-C6烷基; 和（ii）任选地与（c）水，连接剂或其混合物反应。

7. 发明申请

US20090287010A1 Ethylene-tetrafluoroethylene intermediates 失效
标题翻译：乙烯 - 四氟乙烯中间体
公开(公告)号：US20090287010A1
公开(公告)日：2009-11-19
申请号：US12152312
申请日：2008-05-14
申请人： Weiming Qiu , Anilkumar Raghavanpillai , Michael Francis Vincent
发明人： Weiming Qiu , Anilkumar Raghavanpillai , Michael Francis Vincent
IPC分类号： C07C331/02 , C07C19/16 , C07C31/34 , C07C213/00 , C07C69/62
CPC分类号： C08F214/262 , C08F210/02 , C08F214/26 , C08F2/34
摘要： An oligomer of the formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]mG (I) wherein G is an I; OH; OC(O)CH═CH2; OC(O)CCH3═CH2; OC(O)CCl═CH2; NR1H; N3; NCO; SQ wherein Q is H, alkyl, (CH2)nOH, (CH2)nNH2, (CH2)nOC(O)C(Me)═CH2, or (CH2)nNHC(O)C(Me)═CH2; SCN; COOH; SO3H; NHCOCH═CH2; NHCOC(CH3)═CH2); OC(O)NHCH2CH2OC(O)C(CH3)═CH2; or OC(O)NHCH2CH2OC(O)C(CH3)═CH2; subscript n is an integer from 1 to about 6, subscript x is an integer from 1 to about 6, subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof, the total number of carbons in said formula (I) excluding G ranges from about 8 to about 22, and a process for preparation thereof.
摘要翻译：式（I）的低聚物：CnF2n + 1（CH2）x [（CF2CF2）y（CH2CH2）z] mG（I）其中G是I; 哦; OC（O）CH-CH 2; OC（O）CCH 3 -CH 2; OC（O）CCl-CH 2; NR1H; N3; NCO; SQ其中Q为H，烷基，（CH2）nOH，（CH2）nNH2，（CH2）nOC（O）C（Me）-CH2或（CH2）nNHC（O）C（Me） SCN; COOH; SO3H; NHCOCH-CH2; NHCOC（CH 3）-CH 2）; OC（O）NHCH 2 CH 2 OC（O）C（CH 3）-CH 2; 或OC（O）NHCH 2 CH 2 OC（O）C（CH 3）-CH 2; 下标n是1至约6的整数，下标x是1至约6的整数，下标y，z和m各自独立地为1,2或3，或其混合物，所述式中的碳总数（I），其中不包括G范围为约8至约22，及其制备方法。

8. 发明授权

US07968669B2 Fluoropolymer compositions and treated substrates 失效
标题翻译：含氟聚合物组合物和经处理的基材
公开(公告)号：US07968669B2
公开(公告)日：2011-06-28
申请号：US12152736
申请日：2008-05-16
申请人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
发明人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
IPC分类号： C08G18/08 , C08G18/16
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r-xH (I) wherein Rf is a perfluoroalkyl group having 1 to about 6 carbon atoms; the total number of carbons in said formula (I) excluding (R1)r-XH ranges from about 8 to about 22; and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译：具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R1）r-xH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; 和（ii）任选地与（c）水，连接剂或其混合物反应。

9. 发明申请

US20090286949A1 Fluoropolymer compositions and treated substrates 失效
标题翻译：含氟聚合物组合物和经处理的基材
公开(公告)号：US20090286949A1
公开(公告)日：2009-11-19
申请号：US12152736
申请日：2008-05-16
申请人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
发明人： Weiming Qiu , Yun Yang , Michael Henry Ober , Anilkumar Raghavanpillai
IPC分类号： C08G18/74
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—XH (I) whereinRf is a perfluoroalkyl group having 1 to about 6 carbon atoms;subscript x is 1 to about 6;subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof;subscript r is 0 or 1;the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22;X is —O—, —NR—, —S—, —S(CH2)tO—, or —S(CH2)tNR—;subscript t is from 1 to about 10;R is H or C1-4 alkyl;R1 is certain divalent radicals;n is 2 to 4;s is 1 to about 50;R2, R3, and R4 are each independently hydrogen or a C1-C6 alkyl group; and(ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译：具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R 1）r -XH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 下标x为1〜6; 下标y，z和m各自独立地为1,2或3，或其混合物; 下标r为0或1; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; X是-O-，-NR - ， - S - ， - S（CH 2）t O-或-S（CH 2）t NR-; 下标t为1〜10; R是H或C 1-4烷基; R1是一定的二价基团; n为2〜4; s为1至约50; R2，R3和R4各自独立地为氢或C1-C6烷基; 和（ii）任选地与（c）水，连接剂或其混合物反应。

10. 发明授权

US08318877B2 Ethylene tetrafluoroethylene (meth)acrylate copolymers 失效
标题翻译：乙烯四氟乙烯（甲基）丙烯酸酯共聚物
公开(公告)号：US08318877B2
公开(公告)日：2012-11-27
申请号：US12154082
申请日：2008-05-20
申请人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
发明人： Weiming Qiu , Anilkumar Raghavanpillai , Peter Michael Murphy , Jessica Louise Flatter
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译：共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） y（CH 2 CH 2）z] mLC（O）-C（R）= CH 2（I）其中R是H，Cl，F或CH 3，L是O，S，NH，S-（CH 2））R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是 C1至C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。

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