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    • 3. 发明授权
    • Aromatic alkylation process
    • 芳香烷基化工艺
    • US06313362B1
    • 2001-11-06
    • US09213798
    • 1998-12-17
    • John R. GreenThomas F. DegnanYun-Yang HuangChaya R. VenkatRonald A. Weiss
    • John R. GreenThomas F. DegnanYun-Yang HuangChaya R. VenkatRonald A. Weiss
    • C07C264
    • C07C15/085C07C15/073
    • Akylation product is contacted with a purification medium in a liquid phase pre-reaction step to remove impurities and form a purified stream. The purified stream may then be further processed by liquid phase transalkylation to convert the polyalkylated aromatic compound to a monoalkylated aromatic compound. The process may use a large pore molecular sieve catalyst such as MCM-22 as the purification medium in the pre-reaction step because of its high reactivity for alkylation, strong retention of catalyst poisons and low reactivity for oligomerization under the pre-reactor conditions. Olefins, diolefins, styrene, oxygenated organic compounds, sulfur containing compounds, nitrogen containing compounds and oligomeric compounds are removed.
    • 将Akylation产物在液相预反应步骤中与净化介质接触以除去杂质并形成纯化的物流。 然后可以通过液相烷基转移进一步处理纯化的物流,以将多烷基化芳族化合物转化为单烷基化芳族化合物。 在预反应步骤中,该方法可以使用大孔分子筛催化剂例如MCM-22作为纯化介质,因为其在烷基化反应活性高,催化剂毒物强烈的保留和在反应器前条件下的低聚反应低。 除去烯烃,二烯烃,苯乙烯,含氧有机化合物,含硫化合物,含氮化合物和低聚物。
    • 7. 发明授权
    • Catalyst and process for producing low-aromatics distillates
    • 用于生产低芳烃馏出物的催化剂和方法
    • US5451312A
    • 1995-09-19
    • US143407
    • 1993-10-26
    • Minas R. ApelianThomas F. DegnanStuart S. Shih
    • Minas R. ApelianThomas F. DegnanStuart S. Shih
    • B01J23/58B01J29/04B01J37/00C10G45/54C10G65/08C10G45/12C10G45/52
    • C10G45/54B01J29/041B01J37/0009
    • This invention provides a process for producing a distillate boiling-range hydrocarbon product which comprises hydrotreating a hydrodesulfurized aromatic, substantially dealkylated hydrocarbon feed produced by the catalytic cracking of a hydrocarbon fraction, the feed having an initial boiling point of at least 300.degree. F., an aromatic content of at least about 30 weight percent, a hydrogen content not more than about 12 weight percent and a sulfur content of not more than 5000 ppmw, in the presence of a catalyst comprising an inorganic, non-layered, porous, crystalline phase material having pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one peak with a relative intensity of 100 at a d-spacing greater than about 18 .ANG., said material containing at least one Group VIII metal and less than 5000 ppm Na, said process being carried out at a hydrogen partial pressure of not more than 1000 psig to evolve product containing less than about 10 weight percent aromatics and less than 300 ppmw sulfur at a 390.degree. F.+ feed conversion of less than about 30 weight percent.
    • 本发明提供了一种生产馏出物沸点烃产物的方法,该方法包括加氢处理通过烃馏分的催化裂化产生的加氢脱硫的芳族,基本上脱烷基化的烃进料,该原料的起始沸点至少为300°F, 在包含无机,非层状,多孔的结晶相的催化剂存在下,至少约30重量%的芳族含量,不超过约12重量%的氢含量和不大于5000ppmw的硫含量 具有直径至少约为13的孔的材料,并且在煅烧后表现出具有至少一个在d-间距大于约18的相对强度为100的峰的X射线衍射图,所述材料至少包含 一个Ⅷ族金属和小于5000ppm的Na,所述方法在不超过1000psig的氢分压下进行,以产生pr 含量小于约10重量%的芳族化合物和小于300ppmw的硫在390°F +进料转化率小于约30重量%。