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1. 发明授权

US08129470B2 Adhesive masses based on block copolymers of structure P(A)-P(B)-P(A) and P(B)-P(A)-P(B) 有权
标题翻译：基于结构P（A）-P（B）-P（A）和P（B）-P（A）-P（B）的嵌段共聚物的粘合剂块
公开(公告)号：US08129470B2
公开(公告)日：2012-03-06
申请号：US10529845
申请日：2002-03-04
申请人： Thilo Dollase , Marc Husemann , Bernd Luhmann
发明人： Thilo Dollase , Marc Husemann , Bernd Luhmann
IPC分类号： C09J153/00 , C08L53/00
CPC分类号： C09J153/00 , C08F293/005 , C08L53/00 , C08L53/02 , C08L2666/24 , C09J153/02 , Y10T428/14 , Y10T428/1452 , Y10T428/24942 , Y10T428/2495 , Y10T428/24959
摘要： A pressure-sensitive adhesive comprising a blend of at least two components, one of which comprises a block copolymer having at least the unit P(A1)-P(B1)-P(A1) and the second of which comprises a block copolymer having at least the unit P(B2)-P(A2)-P(B2); the blend forming an at least two-phase system.
摘要翻译：一种压敏粘合剂，其包含至少两种组分的共混物，其中一种组分包含至少具有单元P（A1）-P（B1）-P（A1）的嵌段共聚物，其中第二组分包含具有至少单元P（B2）-P（A2）-P（B2）; 所述共混物形成至少两相系统。

2. 发明授权

US07459499B2 Pressure-sensitive adhesive based on acrylate block copolymers 有权
标题翻译：基于丙烯酸酯嵌段共聚物的压敏粘合剂
公开(公告)号：US07459499B2
公开(公告)日：2008-12-02
申请号：US11013237
申请日：2004-12-15
申请人： Marc Husemann , Thilo Dollase , Bernd Luhmann
发明人： Marc Husemann , Thilo Dollase , Bernd Luhmann
IPC分类号： C08L53/00 , B32B27/28
CPC分类号： C09J153/00 , C08F293/005 , C08L2666/02 , C09J7/387 , C09J2433/00 , Y10T428/31935
摘要： Pressure-sensitive adhesive comprising an acrylate block copolymer having at least two chemically distinguishable, covalently interlinked acrylate polymer blocks P in microphase-separated regions and each having a softening temperature of between −125 and +20° C.
摘要翻译：包含丙烯酸酯嵌段共聚物的压敏粘合剂，其在微相分离区域中具有至少两个化学上可区分的，共价连接的丙烯酸酯聚合物嵌段P，并且各自具有-125℃和+ 20℃之间的软化温度。

3. 发明申请

US20050187346A1 Pressure-sensitive adhesive based on acrylate block copolymers 有权
标题翻译：基于丙烯酸酯嵌段共聚物的压敏粘合剂
公开(公告)号：US20050187346A1
公开(公告)日：2005-08-25
申请号：US11013237
申请日：2004-12-15
申请人： Marc Husemann , Thilo Dollase , Bernd Luhmann
发明人： Marc Husemann , Thilo Dollase , Bernd Luhmann
IPC分类号： C08F293/00 , C09J7/02 , C09J153/00 , C08L31/00
CPC分类号： C09J153/00 , C08F293/005 , C08L2666/02 , C09J7/387 , C09J2433/00 , Y10T428/31935
摘要： Pressure-sensitive adhesive comprising an acrylate block copolymer having at least two chemically distinguishable, covalently interlinked acrylate polymer blocks P in microphase-separated regions and each having a softening temperature of between −125 and +20° C.
摘要翻译：包含丙烯酸酯嵌段共聚物的压敏粘合剂，其在微相分离区域中具有至少两个化学上可区分的，共价连接的丙烯酸酯聚合物嵌段P，并且各自具有-125℃和+ 20℃之间的软化温度。

4. 发明申请

US20050154137A1 Pressure-sensitive adhesive based on acrylate block copolymers 有权
标题翻译：基于丙烯酸酯嵌段共聚物的压敏粘合剂
公开(公告)号：US20050154137A1
公开(公告)日：2005-07-14
申请号：US10992860
申请日：2004-11-19
申请人： Marc Husemann , Thilo Dollase , Bernd Luhmann
发明人： Marc Husemann , Thilo Dollase , Bernd Luhmann
IPC分类号： A61B6/00 , C08L35/00 , C09J7/02 , C09J133/08 , C09J153/00 , G01T1/164 , G01T1/20 , H04N5/225 , H04N5/321 , H05G1/64
CPC分类号： A61B6/00 , A61B6/4233 , C08L2205/02 , C08L2666/24 , C09J153/00 , H04N5/2254 , H04N5/321
摘要： The invention provides an acrylate-based pressure-sensitive adhesive comprising a polymer blend having (a) at least a first component Kc which comprises a first acrylate block copolymer having at least two chemically distinguishable, covalently interlinked acrylate polymer blocks P, the at least two polymer blocks P independently of one another each being a homopolymer block of a first monomer or a copolymer block of a second monomer and a comonomer, and the first monomer of the homopolymer block and the second monomer of the copolymer block can be identical or different from one another, and the at least two polymer blocks P being present under application conditions in microphase-separated regions and each having a softening temperature of between −125 and +20° C., and (b) at least one second component LD, which is a second acrylate block copolymer, distinguishable from component Kc, having at least two chemically distinguishable, covalently interlinked acrylate polymer blocks P, with the features specified under (a), or is an acrylate polymer PS, which is a homopolymer of a first monomer or a copolymer of a second monomer and a comonomer, the acrylate polymer PS and the acrylate polymer blocks P having softening temperatures of between −125 and +20° C.
摘要翻译：本发明提供了一种丙烯酸酯基压敏粘合剂，其包含聚合物共混物，其具有（a）至少第一组分K c C，其包含具有至少两个化学上可区分的，共价连接的丙烯酸酯的第一丙烯酸酯嵌段共聚物聚合物嵌段P，所述至少两个聚合物嵌段P彼此独立地各自为第一单体的均聚物嵌段或第二单体和共聚单体的共聚物嵌段，并且均聚物嵌段的第一单体和共聚物嵌段可以相同或不同，并且所述至少两个聚合物嵌段P在微相分离区域中存在于施加条件下，并且各自具有-125℃和+ 20℃之间的软化温度，和（b）至少一个第二组分L D D，其是与组分K区别的第二丙烯酸酯嵌段共聚物，其具有至少两个化学上可区分的共价杂交具有（a）中规定的特征的丙烯酸酯聚合物嵌段P或作为第一单体的均聚物或第二单体和共聚单体的共聚物的丙烯酸酯聚合物P S S，丙烯酸酯聚合物P S S和丙烯酸酯聚合物嵌段P的软化温度在-125℃和+ 20℃之间。

5. 发明申请

US20060235150A1 Adhesive masses based on block co-colymers of structure p(a)-p(b)-p(a) and p(b)-p(a)-p(b) 有权
标题翻译：基于结构p（a）-p（b）-p（a）和p（b）-p（a）-p（b））的嵌段共聚物的粘合剂块，
公开(公告)号：US20060235150A1
公开(公告)日：2006-10-19
申请号：US10529845
申请日：2002-03-04
申请人： Thilo Dollase , Marc Husemann , Bernd Luhmann
发明人： Thilo Dollase , Marc Husemann , Bernd Luhmann
IPC分类号： C08L53/00
CPC分类号： C09J153/00 , C08F293/005 , C08L53/00 , C08L53/02 , C08L2666/24 , C09J153/02 , Y10T428/14 , Y10T428/1452 , Y10T428/24942 , Y10T428/2495 , Y10T428/24959
摘要： A pressure-sensitive adhesive comprising a blend of at least two components, one of which comprises a block copolymer having at least the unit P(A1)-P(B1)-P(A1) and the second of which comprises a block copolymer having at least the unit P(B2)-P(A2)-P(B2); the blend forming an at least two-phase system.
摘要翻译：一种压敏粘合剂，其包含至少两种组分的共混物，其中一种组分包含至少具有单元P（A1）-P（B1）-P（A1）的嵌段共聚物，其中第二组分包含具有至少单元P（B2）-P（A2）-P（B2）; 所述共混物形成至少两相系统。

6. 发明授权

US07923510B2 Adhesive sheet based on nitrile rubber blends for attaching metal parts to plastics 失效
标题翻译：基于丁腈橡胶混合物的粘合片，用于将金属部件连接到塑料上
公开(公告)号：US07923510B2
公开(公告)日：2011-04-12
申请号：US11996519
申请日：2006-07-27
申请人： Marc Husemann , Frank Hannemann , Matthias Koop , Thilo Dollase , Thorsten Krawinkel
发明人： Marc Husemann , Frank Hannemann , Matthias Koop , Thilo Dollase , Thorsten Krawinkel
IPC分类号： C08L9/02 , C08L61/04 , C08L61/14 , C08L63/00 , C08L63/02 , C08L63/04 , C08L75/04
CPC分类号： C08L9/02 , C08L63/00 , C08L2205/02 , C09J7/10 , C09J2409/00 , Y10T428/2813 , C08L2666/02
摘要： Heat-activable adhesive sheet of an adhesive comprising a blend of at least three synthetic nitrile rubber compositions S1, S2 and S3, each of which comprises at least one synthetic nitrile rubber, and at least one reactive resin which is capable of crosslinking with itself, with other reactive resins and/or with the nitrile rubbers of synthetic rubber compositions S1, S2 and S3, in which a) the blend of the heat-activable sheet being microphase-separated, characterized by at least three different glass transition temperatures in a DSC, b) at least one of said glass transition temperatures being greater than 10° C. and at least one of said glass transition temperature lower than −20° C., c) the nitrile rubber or rubbers S1 having an acrylonitrile fraction of greater than/equal to 35%, d) the nitrile rubber or rubbers S2 having an acrylonitrile fraction of greater than 25% and less than 35%, e) the nitrile rubber S3 having an acrylonitrile fraction of less than/equal to 25%.
摘要翻译：包含至少三种合成腈橡胶组合物S1，S2和S3的共混物的粘合剂的热可活化粘合片，每种合成腈橡胶组合物包含至少一种合成腈橡胶和至少一种能与其自身交联的反应性树脂，与其它反应性树脂和/或与合成橡胶组合物S1，S2和S3的丁腈橡胶相结合，其中a）可热活化的片材的共混物被微相分离，其特征在于DSC中至少三种不同的玻璃化转变温度 b）所述玻璃化转变温度中的至少一个大于10℃，所述玻璃化转变温度中的至少一个低于-20℃，c）腈橡胶或橡胶S1的丙烯腈分数大于 /等于35％，d）丙烯腈分数大于25％且小于35％的丁腈橡胶或橡胶S2，e）丙烯腈分数小于或等于25％的丁腈橡胶S3。

7. 发明申请

US20060154098A1 Self-adhesive article 审中-公开
标题翻译：自粘物品
公开(公告)号：US20060154098A1
公开(公告)日：2006-07-13
申请号：US10537469
申请日：2003-11-11
申请人： Thilo Dollase , Marc Husemann
发明人： Thilo Dollase , Marc Husemann
IPC分类号： B32B27/30 , B32B7/12
CPC分类号： C09J153/00 , C09J7/21 , C09J7/38 , C09J7/387 , C09J2400/283 , C09J2433/00 , Y10T428/28 , Y10T428/2839 , Y10T428/2843 , Y10T428/31935
摘要： A self-adhesive article made from a sheet or strip support at least partly coated on at least one side with a pressure-sensitive adhesive material based on polyacrylate, comprising at least one polyacrylate block copolymer with a sequence of hard polymer blocks [P(A)], having a glass transition temperature of not more than 10° C., preferably of 0 to −80° C. and of soft polymer blocks [P(B)], having a glass transition temperature of more than 10° C., preferably 20 to 175° C. A microstructuring is thus generated, which permits the exchange of the smallest adhering and non-adhering regions and thus generates the desired easily stuck and easily removed adhesive action such as required for self-adhesive note pads.
摘要翻译：至少部分地用基于聚丙烯酸酯的压敏粘合剂材料至少部分地涂覆有片状或带状载体的自粘物品，其包含至少一种具有一定硬聚合物嵌段的聚丙烯酸酯嵌段共聚物[P（A ）]，玻璃化转变温度为10℃以下，优选为0〜-80℃，玻璃化转变温度为10℃以上的软质聚合物嵌段[P（B）]。，优选为20至175℃。因此产生微结构，其允许最小粘附和非粘附区域的交换，从而产生所需的容易粘贴和容易去除的粘合剂作用，例如自粘贴纸垫所需要的。

8. 发明申请

US20060057372A1 Adhesive materials having a high refractive index based on acrylate block copolymers 有权
$Adhesive materials having a high refractive index based on acrylate block copolymers$
标题翻译：基于丙烯酸酯嵌段共聚物具有高折射率的粘合材料
公开(公告)号：US20060057372A1
公开(公告)日：2006-03-16
申请号：US10522233
申请日：2003-06-24
申请人： Thilo Dollase , Marc Husemann
发明人： Thilo Dollase , Marc Husemann
IPC分类号： B32B27/32 , B32B27/30 , B32B7/12
CPC分类号： C09J153/00 , C08F293/005 , C08L2666/02 , C08L2666/24 , Y10T428/1082 , Y10T428/2891 , Y10T428/31645 , Y10T428/31935
摘要： A pressure-sensitive adhesive based on at least 50% of one or more block copolymers, at least one block copolymer being composed at least in part on the basis of (meth)acrylic acid derivatives, the at least one block copolymer comprising at least the unit P(A)-P(B)-P(A), comprising at least one polymer block P(B) and at least two polymer blocks P(A), where P(A) independently of one another represent homopolymer or copolymer blocks made up of monomers of group A, the (co)polymer blocks P(A) each having a softening temperature in the range from 0° C. to +175° C., P(B) represents a homopolymer or copolymer block comprising monomers of group B, the (co)polymer block P(B) having a softening temperature in the range from −130° C. to +10° C., and the (co)polymer blocks P(A) and P(B) are not homogeneously miscible with one another at 25° C., characterized in that the adhesive has a refractive index nd,a of nd,a≧1.52 at 25° C., at least one of the (co)polymer blocks P(A) have a refractive index nd,A of nd,A≧1.58 at 25° C., and the (co)polymer block P(B) has a refractive index nd,B of nd,B≧1.43 at 25° C.
摘要翻译：基于至少50％的一种或多种嵌段共聚物的压敏粘合剂，至少一种嵌段共聚物至少部分基于（甲基）丙烯酸衍生物构成，所述至少一种嵌段共聚物至少包含单元P（A）-P（B）-P（A），其包含至少一个聚合物嵌段P（B）和至少两个聚合物嵌段P（A），其中P（A）彼此独立地表示均聚物或共聚物由组A的单体构成的嵌段，（共）聚合物嵌段P（A）各自具有0℃至+ 175℃的软化温度，P（B）表示均聚物或共聚物嵌段，其包含 B组单体，（共）聚合物嵌段P（B）的软化温度在-130℃至+ 10℃的范围内，和（共）聚合物嵌段P（A）和P（B ）在25℃下不能彼此均匀混溶，其特征在于t

9. 发明申请

US20080166554A1 Adhesive Sheet Based on Nitrile Rubber Blends for Attaching Metal Parts to Plastics 失效
标题翻译：基于用于将金属零件连接到塑料的腈橡胶混合物的粘合片
公开(公告)号：US20080166554A1
公开(公告)日：2008-07-10
申请号：US11996519
申请日：2006-07-27
申请人： Marc Husemann , Frank Hannemann , Matthias Koop , Thilo Dollase , Thorsten Krawinkel
发明人： Marc Husemann , Frank Hannemann , Matthias Koop , Thilo Dollase , Thorsten Krawinkel
IPC分类号： B32B25/04
CPC分类号： C08L9/02 , C08L63/00 , C08L2205/02 , C09J7/10 , C09J2409/00 , Y10T428/2813 , C08L2666/02
摘要： Heat-activable adhesive sheet of an adhesive comprising a blend of at least three synthetic nitrile rubber compositions S1, S2 and S3, each of which comprises at least one synthetic nitrile rubber, and at least one reactive resin which is capable of crosslinking with itself, with other reactive resins and/or with the nitrile rubbers of synthetic rubber compositions S1, S2 and S3, in which a) the blend of the heat-activable sheet being microphase-separated, characterized by at least three different glass transition temperatures in a DSC, b) at least one of said glass transition temperatures being greater than 10° C. and at least one of said glass transition temperature lower than −20° C., c) the nitrile rubber or rubbers S1 having an acrylonitrile fraction of greater than/equal to 35%, d) the nitrile rubber or rubbers S2 having an acrylonitrile fraction of greater than 25% and less than 35%, e) the nitrile rubber S3 having an acrylonitrile fraction of less than/equal to 25%.
摘要翻译：包含至少三种合成腈橡胶组合物S1，S2和S3的共混物的粘合剂的热可活化粘合片，每种合成腈橡胶组合物包含至少一种合成腈橡胶和至少一种能与其自身交联的反应性树脂，与其它反应性树脂和/或与合成橡胶组合物S1，S2和S3的丁腈橡胶相结合，其中a）可热活化的片材的共混物被微相分离，其特征在于DSC中至少三种不同的玻璃化转变温度 b）所述玻璃化转变温度中的至少一个大于10℃，所述玻璃化转变温度中的至少一个低于-20℃，c）腈橡胶或橡胶S1的丙烯腈分数大于 /等于35％，d）丙烯腈分数大于25％且小于35％的丁腈橡胶或橡胶S2，e）丙烯腈分数小于或等于25％的丁腈橡胶S3。

10. 发明授权

US06723407B2 Strippable systems based on acrylic block copolymers 有权
标题翻译：基于丙烯酸嵌段共聚物的可剥离体系
公开(公告)号：US06723407B2
公开(公告)日：2004-04-20
申请号：US10075482
申请日：2002-02-13
申请人： Thilo Dollase , Marc Husemann , Bernd Lühmann
发明人： Thilo Dollase , Marc Husemann , Bernd Lühmann
IPC分类号： B32B3300
CPC分类号： C09J153/00 , C08F293/005 , C08L53/00 , C08L53/02 , C08L2666/24 , C09J153/02 , Y10T428/14 , Y10T428/1452 , Y10T428/24942 , Y10T428/2495 , Y10T428/24959
摘要： Strippable systems comprising at least one pressure sensitive adhesive based on at least one block copolymer, wherein said at least one block copolymer is based at least in part on (meth)acrylic acid derivatives, the block copolymers containing at least the unit P(A)-P(B)-P(A) composed of at least one polymer block P(B) and at least two polymer blocks P(A), where P(A) independently of one another represent homopolymer or copolymer blocks of monomers A, the polymer blocks P(A) each having a softening temperature in the range from +20° C. to +175° C., P(B) represents a homopolymer or copolymer block of monomers B, the polymer block P(B) having a softening temperature in the range from −100° C. to +10° C., and the polymer blocks P(A) and P(B) are not homogeneously miscible with one another.
摘要翻译：包括至少一种基于至少一种嵌段共聚物的压敏粘合剂的可剥离体系，其中所述至少一种嵌段共聚物至少部分基于（甲基）丙烯酸衍生物，所述嵌段共聚物至少含有单元P（A）由至少一个聚合物嵌段P（B）和至少两个聚合物嵌段P（A）组成的-P（B）-P（A），其中P（A）彼此独立地表示单体A的均聚物或共聚物嵌段，聚合物嵌段P（A）各自具有+ 20℃至+ 175℃的软化温度，P（B）表示单体B的均聚物或共聚物嵌段，聚合物嵌段P（B）具有软化温度在-100℃至+ 10℃的范围内，聚合物嵌段P（A）和P（B）彼此不能均匀地混溶。

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