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1. 发明申请

US20110033665A1 USE OF A MICROCRYSTALLINE POLYAMIDE TO OBTAIN A PARTICULAR SURFACE FINISH 失效
标题翻译：使用微晶聚酰胺获得特殊表面处理
公开(公告)号：US20110033665A1
公开(公告)日：2011-02-10
申请号：US12908383
申请日：2010-10-20
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： D06N7/04 , B29C47/06
CPC分类号： C09D177/00 , Y10T428/24364 , Y10T428/31725
摘要： The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection moulding and sheet extrusion/calendering. Advantageously, the microcrystalline polyamide is such that its degree of crystallinity is greater than 10% and less than 30% (1st DSC heating according to ISO 11357 at 40° C./min) and the enthalpy of melting is greater than 25 J/g and less than 75 J/g (1st DSC heating according to ISO 11357 at 40° C./min).Preferably, it such that its Tg (glass transition temperature) is between 40° C. and 90° C. and its Tm (melting point) is between 150° C. and 200° C.Advantageously, it results from the chain-linking of monomers such that 50% or more, by weight, of these monomers are ≧C9 monomers (i.e. having a number of carbon atoms equal to 9 or higher).
摘要翻译：本发明涉及微晶聚酰胺用于获得具有由该微晶聚酰胺形成的全部或部分外表面并具有特定表面光洁度的物体的用途，其中：物体的制造包括在 Tg（玻璃化转变温度）和该微晶聚酰胺的Tm（熔点）微晶聚酰胺的透明度使得在1mm厚度的抛光对象上的560nm处的透光度大于80％，有利地大于88％，对通过标准加工方法获得的物体，例如注射成型和片材挤出/压延。有利地，微晶聚酰胺的结晶度大于10％且小于30％（根据ISO 11357的第一次DSC加热在40℃/ min），并且熔融焓大于25J / g 和小于75J / g（根据ISO 11357的第一次DSC加热在40℃/分钟）。优选地，其Tg（玻璃化转变温度）在40℃和90℃之间，其Tm（熔点）在150℃和200℃之间。有利地，它是由链连接的单体，使得这些单体的50重量％以上是≥C9单体（即碳原子数为9以上）。

2. 发明授权

US07122233B2 Polyamide-based transparent composition 有权
公开(公告)号：US07122233B2
公开(公告)日：2006-10-17
申请号：US11041928
申请日：2005-01-26
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08L77/00 , C08L77/12 , B29D23/00 , A63C5/00
CPC分类号： C08L77/00 , A63C5/003 , C08L77/06 , C08L77/12 , Y10S428/914 , Y10T428/1352 , Y10T428/24 , Y10T428/31725 , Y10T428/31739
摘要： The invention relates to a transparent composition comprising, by weight, the total being 100%: 5 to 40% of an amorphous polyamide (B) which results essentially from the condensation: either of at least one diamine chosen from cycloaliphatic diamines and aliphatic diamines and of at least one diacid chosen from cycloaliphatic diacids and aliphatic diacids, at least one of these diamine or diacid units being cycloaliphatic, or of a cycloaliphatic α,ω-aminocarboxylic acid, or of a combination of these two possibilities, and optionally of at least one monomer chosen from α,ω-aminocarboxylic acids or the possible corresponding lactams, aliphatic diacids and aliphatic diamines, 0 to 40% of a supple polyamide (C) chosen from copolymers containing polyamide blocks and polyether blocks and copolyamides, 0 to 20% of a compatabilizer (D) for (A) and (B), 0 to 40% of a supple modifier (M), with the condition that (C)+(D)+(M) is between 0 and 50%, the remainder to 100% being a semi-crystalline polyamide (A). The invention also relates to the articles obtained, such as plates, films, sheets, tubes and profiles, the articles obtained by injection moulding and in particular the films and sheets which are then bonded to skis.The invention also relates to the above articles decorated, for example, by sublimation, and coated with a transparent protective layer consisting of the composition of the invention.

3. 发明授权

US06916517B2 Polyamide-based transparent composition 失效
标题翻译：聚酰胺类透明组合物
公开(公告)号：US06916517B2
公开(公告)日：2005-07-12
申请号：US10054868
申请日：2002-01-25
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： A63C5/14 , C08J5/00 , C08L77/00 , C08L77/02 , C08L77/04 , C08L77/06 , C08L77/12 , A63C5/00 , B29D23/00
CPC分类号： C08L77/02 , C08L77/00 , C08L77/06 , C08L77/12 , Y10S428/914 , Y10T428/1352 , Y10T428/24 , Y10T428/31725 , Y10T428/31739
摘要： A composition comprising, by weight, the total being 100%: 5 to 40% of an amorphous polyamide (B) which results from the condensation of at least one aromatic diacid and with at least one diamine said diamine being optionally cycloaliphatic, and, optionally with at least one monomer chosen from: α,ω-aminocarboxylic acids, aliphatic diacids, aliphatic diamines, 0 to 40% of a supple polyamide (C) chosen from copolymers containing polyamide blocks, polyether blocks and copolyamides, 0 to 20% of a compatibilizer (D) for (A) and (B), (C)+(D) is between 2% and 50%, with the condition that (B)+(C)+(D) is not less than 30%, and the difference to 100% is made up with a semi-crystalline polyamide (A). This composition can be molded into transparent sheets treated by a sublimation printing process at relatively low temperatures.
摘要翻译：一种组合物，其包含总重量的100％：5-40％的无定形聚酰胺（B），其由至少一种芳族二酸与至少一种二胺缩合产生，所述二胺任选为脂环族，和任选地与选自以下的至少一种单体：α，ω-氨基羧酸，脂族二酸，脂族二胺，0至40％的选自包含聚酰胺嵌段，聚醚嵌段和共聚酰胺的共聚物的柔软聚酰胺（C），0至20％（A）和（B），（C）+（D）的增容剂（D）在2％至50％之间，条件是（B）+（C）+（D）不小于30％并且与100％的差异由半结晶聚酰胺（A）组成。该组合物可以模塑成在较低温度下通过升华印刷方法处理的透明片材。

4. 发明授权

US07833450B2 Use of a microcrystalline polyamide to obtain a particular surface finish 失效
标题翻译：使用微晶聚酰胺获得特定的表面光洁度
公开(公告)号：US07833450B2
公开(公告)日：2010-11-16
申请号：US11158650
申请日：2005-06-22
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08L77/00 , C08L77/12 , B29D23/00
CPC分类号： C09D177/00 , Y10T428/24364 , Y10T428/31725
摘要： The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection moulding and sheet extrusion/calendering.
摘要翻译：本发明涉及微晶聚酰胺用于获得具有由该微晶聚酰胺形成的全部或部分外表面并具有特定表面光洁度的物体的用途，其中：物体的制造包括在 Tg（玻璃化转变温度）和该微晶聚酰胺的Tm（熔点）微晶聚酰胺的透明度使得在1mm厚度的抛光对象上的560nm处的透光度大于80％，有利地大于88％，对通过标准加工方法获得的物体，例如注射成型和片材挤出/压延。

5. 发明申请

US20060030692A1 Use of a microcrystalline polyamide to obtain a particular surface finish 失效
标题翻译：使用微晶聚酰胺获得特定的表面光洁度
公开(公告)号：US20060030692A1
公开(公告)日：2006-02-09
申请号：US11158650
申请日：2005-06-22
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08G69/08
CPC分类号： C09D177/00 , Y10T428/24364 , Y10T428/31725
摘要： The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection moulding and sheet extrusion/calendering. Advantageously, the microcrystalline polyamide is such that its degree of crystallinity is greater than 10% and less than 30% (1st DSC heating according to ISO 11357 at 40° C./min) and the enthalpy of melting is greater than 25 J/g and less than 75 J/g (1st DSC heating according to ISO 11357 at 40° C./min). Preferably, it such that its Tg (glass transition temperature) is between 40° C. and 90° C. and its Tm (melting point) is between 150° C. and 200° C. Advantageously, it results from the chain-linking of monomers such that 50% or more, by weight, of these monomers are ≧C9 monomers (i.e. having a number of carbon atoms equal to 9 or higher).
摘要翻译：本发明涉及微晶聚酰胺用于获得具有由该微晶聚酰胺形成的全部或部分外表面并具有特定表面光洁度的物体的用途，其中：物体的制造包括在（玻璃化转变温度）和该微晶聚酰胺的T m（熔点）; 微晶聚酰胺的透明度使得在1mm厚度的抛光对象上的560nm处的透光度大于80％，有利地大于88％，对通过标准加工方法获得的物体，例如注射成型和片材挤出/压延。有利地，微晶聚酰胺的结晶度大于10％且小于30％（根据ISO 11357的第一次DSC加热在40℃/ min），并且熔融焓大于25J / g 和小于75J / g（根据ISO 11357的第一次DSC加热在40℃/分钟）。优选地，其T T（玻璃化转变温度）在40℃和90℃之间，其T m（熔点）在150℃之间有利地，它是由单体的链连接引起的，使得这些单体的重量百分比为50％或更多是> = C9单体（即具有等于9或更高数目的碳原子）。

6. 发明申请

US20050165175A1 Polyamide-based transparent composition 有权
标题翻译：聚酰胺类透明组合物
公开(公告)号：US20050165175A1
公开(公告)日：2005-07-28
申请号：US11041928
申请日：2005-01-26
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08J5/00 , A63C5/00 , C08L77/00 , C08L77/06 , C08L77/12 , C08L101/00 , C08G63/91
CPC分类号： C08L77/00 , A63C5/003 , C08L77/06 , C08L77/12 , Y10S428/914 , Y10T428/1352 , Y10T428/24 , Y10T428/31725 , Y10T428/31739
摘要： The invention relates to a transparent composition comprising, by weight, the total being 100%: 5 to 40% of an amorphous polyamide (B) which results essentially from the condensation: either of at least one diamine chosen from cycloaliphatic diamines and aliphatic diamines and of at least one diacid chosen from cycloaliphatic diacids and aliphatic diacids, at least one of these diamine or diacid units being cycloaliphatic, or of a cycloaliphatic α,ω-aminocarboxylic acid, or of a combination of these two possibilities, and optionally of at least one monomer chosen from α,ω-aminocarboxylic acids or the possible corresponding lactams, aliphatic diacids and aliphatic diamines, 0 to 40% of a supple polyamide (C) chosen from copolymers containing polyamide blocks and polyether blocks and copolyamides, 0 to 20% of a compatabilizer (D) for (A) and (B), 0 to 40% of a supple modifier (M), with the condition that (C)+(D)+(M) is between 0 and 50%, the remainder to 100% being a semi-crystalline polyamide (A). The invention also relates to the articles obtained, such as plates, films, sheets, tubes and profiles, the articles obtained by injection moulding and in particular the films and sheets which are then bonded to skis. The invention also relates to the above articles decorated, for example, by sublimation, and coated with a transparent protective layer consisting of the composition of the invention.
摘要翻译：本发明涉及一种透明组合物，其包含重量百分比为100％：5-40％的无定形聚酰胺（B），其基本上由缩合产生：至少一种选自脂环族二胺和脂族二胺的二胺和的至少一种选自脂环族二酸和脂族二酸的二酸，这些二胺或二酸单元中的至少一种是脂环族的，或脂环族的α，ω-氨基羧酸，或这两种可能性的组合，以及任选地至少选自α，ω-氨基羧酸或可能的相应的内酰胺，脂族二酸和脂族二胺的一种单体，0至40％选自含聚酰胺嵌段和聚醚嵌段和共聚酰胺的共聚物的柔性聚酰胺（C），0-20％（A）和（B）的组合物（D），0至40％的柔顺改性剂（M），条件是（C）+（D）+（M）为0至50％以100％为半结晶性聚酰胺（A）。本发明还涉及获得的制品，例如板，膜，片，管和型材，通过注射成型获得的制品，特别是然后粘合到滑雪板上的薄膜和薄片。本发明还涉及通过例如升华装饰并涂覆有由本发明的组合物组成的透明保护层的上述制品。

7. 发明授权

US08211344B2 Use of a microcrystalline polyamide to obtain a particular surface finish 失效
标题翻译：使用微晶聚酰胺获得特定的表面光洁度
公开(公告)号：US08211344B2
公开(公告)日：2012-07-03
申请号：US12908383
申请日：2010-10-20
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08L77/00 , C08L77/12
CPC分类号： C09D177/00 , Y10T428/24364 , Y10T428/31725
摘要： The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection molding and sheet extrusion/calendering. Advantageously, the microcrystalline polyamide is such that its degree of crystallinity is greater than 10% and less than 30% (1st DSC heating according to ISO 11357 at 40° C./min) and the enthalpy of melting is greater than 25 J/g and less than 75 J/g (1st DSC heating according to ISO 11357 at 40° C./min).Preferably, it such that its Tg (glass transition temperature) is between 40° C. and 90° C. and its Tm (melting point) is between 150° C. and 200° C.Advantageously, it results from the chain-linking of monomers such that 50% or more, by weight, of these monomers are ≧C9 monomers (i.e. having a number of carbon atoms equal to 9 or higher).
摘要翻译：本发明涉及微晶聚酰胺用于获得具有由该微晶聚酰胺形成的全部或部分外表面并具有特定表面光洁度的物体的用途，其中：物体的制造包括在 Tg（玻璃化转变温度）和该微晶聚酰胺的Tm（熔点）微晶聚酰胺的透明度使得在1mm厚度的抛光对象上的560nm处的透光度大于80％，有利地大于88％，对通过标准加工方法获得的物体，例如注射成型和片材挤出/压延。有利地，微晶聚酰胺的结晶度大于10％且小于30％（根据ISO 11357的第一次DSC加热在40℃/ min），并且熔融焓大于25J / g 和小于75J / g（根据ISO 11357的第一次DSC加热在40℃/分钟）。优选地，其Tg（玻璃化转变温度）在40℃和90℃之间，其Tm（熔点）在150℃和200℃之间。有利地，它是由链连接的单体，使得这些单体的50重量％以上是≥C9单体（即碳原子数为9以上）。

8. 发明授权

US07014919B2 Polyamide-based transparent composition 有权
标题翻译：聚酰胺类透明组合物
公开(公告)号：US07014919B2
公开(公告)日：2006-03-21
申请号：US10055907
申请日：2002-01-28
申请人： Thibaut Montanari , Christelle Recoquille
发明人： Thibaut Montanari , Christelle Recoquille
IPC分类号： C08L77/00
CPC分类号： C08L77/00 , A63C5/003 , C08L77/06 , C08L77/12 , Y10S428/914 , Y10T428/1352 , Y10T428/24 , Y10T428/31725 , Y10T428/31739
摘要： A composition comprising, by weight, the total being 100%: a semi-crystalline polyamide (A); 5 to 40% of an amorphous polyamide (B) which results from the condensation: of (B1) at least one cycloaliphatic diamine or aliphatic diamine, with at least one cycloaliphatic diacid or aliphatic diacid, at least one of the diamine or diacid units being cycloaliphatic, or (B2) of a cycloaliphatic α,ω-aminocarboxylic acid, or (B3) of a combination of (B1), and (B2), and optionally at least one of (B1), (B2) and (B) being condensed with at least one monomer selected from the group consisting of a α,ω-aminocarboxylic acid or the corresponding lactam, an aliphatic diacid, and an aliphatic diamine; 0 to 40% of a supple polyamide (C) selected from the group consisting of (C1) copolymers containing polyamide blocks and polyether blocks, and (C2) copolyamides; 0 to 20% of a compatabilizer (D) for (A) and (B); 0 to 40% of a supple modifier (M); with the condition that (C)+(D)+(M) is between 0 and 50%, the remainder to 100% being said semi-crystalline polyamide (A), this composition can be injection molded into transparent articles.
摘要翻译：一种组合物，其按总重量计为100％：半结晶聚酰胺（A）; 5％至40％的由（B1）至少一种脂环族二胺或脂族二胺与至少一种脂环族二酸或脂族二酸的缩合产生的无定形聚酰胺（B），至少一种二胺或二酸单元是（B1）和（B2）的组合的（B3）和（B1），（B2）和（B）中的至少一个的脂环族α，ω-氨基羧酸或（B3）与选自α，ω-氨基羧酸或相应的内酰胺，脂族二酸和脂族二胺的至少一种单体缩合; 0至40％选自（C1）含聚酰胺嵌段和聚醚嵌段的共聚物和（C2）共聚酰胺的柔性聚酰胺（C）; （A）和（B）的化合物（D）的0至20％; 0至40％的柔顺调节剂（M）; （C）+（D）+（M）为0〜50％，其余为100％为半结晶性聚酰胺（A）的情况下，可将该组合物注塑成透明制品。

9. 发明申请

US20090306308A1 AMORPHOUS COPOLYAMIDES COMPRISING P-BIS (AMINOCYCLOHEXYL) METHANE AND TEREPHTALIC ACID 审中-公开
标题翻译：包含P-BIS（AMINOCYCLOHEXYL）甲烷和非对苯二酸的非晶态共聚物
公开(公告)号：US20090306308A1
公开(公告)日：2009-12-10
申请号：US12280737
申请日：2007-02-19
申请人： Philippe Blondel , Thibaut Montanari
发明人： Philippe Blondel , Thibaut Montanari
IPC分类号： C08L77/06 , C08G69/26
CPC分类号： C08G69/02 , C08G69/26 , C08G69/265 , C08L23/16 , C08L51/06 , C08L77/00 , C08L77/06 , C08L2205/02 , C08L2666/20 , C08L2666/06
摘要： The present invention relates to amorphous transparent copolyamides of formula: PACM.T/D.X/X1.Y1 resulting from the condensation of PACM, terephtalic acid, a diamine D, a diacid X, a diamine X1 and a diacid Y1 in which: PACM denotes the p-bis(aminocyclohexyl)methane, T denotes terephtalic acid, D denotes a diamine chosen from aromatic, arylaliphatic and cycloaliphatic diamines, X denotes a diacid HOOC—(CH2)n—COOH having from 8 to 20 carbon atoms, X1 denotes an aliphatic diamine, Y1 denotes a diacid HOOC—(CH2)n—COOH having from 6 to 20 carbon atoms, the mol proportion of PACM.T is such as (PACM.T)/(PACM.T+D.X) is above 0.5, and can be increased to 1, the mol proportion of X1 is between 16% and 38%, X1.Y1 can be replaced partly or totally by Z, a lactam or an alpha-omega aminocarboxylic acid, having from 9 to 20 carbon atoms, and in this case the mol proportion of Z is between 33% and 75%.
摘要翻译：本发明涉及由PACM，对苯二甲酸，二胺D，二酸X，二胺X1和二酸Y1的缩合产生的式PACM.T / DX / X1.Y1的无定形透明共聚酰胺，其中：PACM表示对 - 双（氨基环己基）甲烷，T表示对苯二甲酸，D表示选自芳族，芳基脂族和脂环族二胺的二胺，X表示具有8至20个碳原子的二酸HOOC-（CH 2）n -COOH，X 1表示脂肪族二胺，Y1表示具有6〜20个碳原子的二酸HOOC-（CH 2）n -COOH，PACM.T的摩尔比例如（PACM.T）/（PACM.T + DX）高于0.5，并且可以增加到1，X1的摩尔比例在16％和38％之间，X1.Y1可以部分或全部被Z取代，具有9至20个碳原子的内酰胺或α-ω氨基羧酸，在这种情况下，Z的摩尔比例在33％至75％之间。

10. 发明申请

US20090269532A1 MULTILAYER STRUCTURE COMPRISING AT LEAST ONE STABILIZED LAYER 有权
标题翻译：包含至少一个稳定层的多层结构
公开(公告)号：US20090269532A1
公开(公告)日：2009-10-29
申请号：US12395826
申请日：2009-03-02
申请人： Vincent Ferreiro , Thibaut Montanari , Fabrice Montezin
发明人： Vincent Ferreiro , Thibaut Montanari , Fabrice Montezin
IPC分类号： B32B1/08 , B32B27/34
CPC分类号： B32B27/34 , B32B1/02 , B32B1/08 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/285 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/36 , B32B2250/24 , B32B2270/00 , B32B2307/21 , B32B2307/30 , B32B2307/306 , B32B2307/50 , B32B2307/546 , B32B2307/714 , B32B2307/7265 , B32B2439/40 , B32B2597/00 , B32B2605/00 , C08K3/16 , C08K5/005 , F02M37/0017 , F16L11/04 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1393 , Y10T428/31728 , C08L77/00
摘要： The invention relates to a multilayer structure comprising at least two layers; a layer, referred to as the inner layer, intended to be in contact with a fluid, comprising a composition comprising at least one polymer and not comprising any copper, and a layer, referred to as the outer layer, intended to be in contact with the air, comprising a composition containing at least one polymer and at least one copper-based stabilizer. The invention also relates to a pipe comprising such a multilayer structure, and also to its use for transporting or storing fluids.
摘要翻译：本发明涉及包括至少两层的多层结构; 被称为内层的旨在与流体接触的层，包括包含至少一种聚合物并且不包含任何铜的组合物和称为外层的层，旨在与空气，包含含有至少一种聚合物和至少一种铜基稳定剂的组合物。本发明还涉及一种包括这种多层结构的管，以及其用于输送或储存流体的用途。

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