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    • 5. 发明申请
    • ACTIVE LAYER-INCORPORATED, SPECTRALLY-TUNED NANOSTRUCTURE-BASED LIGHT TRAPPING FOR ORGANIC PHOTOVOLTAIC DEVICES
    • 用于有机光伏器件的主动层叠式,基于纳米结构的基于光谱的光束捕获
    • US20160035990A1
    • 2016-02-04
    • US14775079
    • 2014-03-13
    • THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    • Vladan JankovicYang YangYang YangJane Chang
    • H01L51/44H01L51/42
    • H01L51/447H01L51/4253H01L51/4266H01L51/448Y02E10/549
    • Core/shell resonant light absorption and scattering materials and methods incorporated into active layers for increasing the short circuit current and photo conversion efficiency of organic photovoltaic systems are provided. In particular, resonant light absorption and scattering methods and materials for improving the efficiency (short circuit current Qsc) and photo conversion efficiency (PCE)) of organic photovoltaic polymer systems (OPV) that include multilayer nano structures having a noble metal core and a passivated and functionalized outer shell disposed with the active layer of the OPV in the form of nanospheres and nanorods have been synthesized, characterized and incorporated into the active layers of OPV devices to enhance light absorption through plasmonic light trapping (PLT). In some embodiments the peak extinction wavelength of the nanoparticles is designed to coincide with the wavelength region of the OPV band edge in order to ensure that light trapping is occurring at wavelengths of poor absorption. In other embodiments, a second shell consisting of an optically active material is deposited onto the nanoparticles, the material being selected such that the extinction peak of the core of the nanoparticles is designed to coincide with the emission peak of the rare earth energy transition in order to increase the spontaneous emission rate at that wavelength by taking advantage of the Purcell effect.
    • 提供了用于增加有机光伏系统的短路电流和光转换效率的并入有源层的核/壳谐振光吸收和散射材料和方法。 特别地,有机光聚合物体系(OPV)的共振光吸收和散射方法和用于提高效率(短路电流Qsc)和光转换效率(PCE))的材料包括具有贵金属核和钝化的多层纳米结构 并且已经合成了以纳米球和纳米棒形式设置的具有OPV的有源层的功能化外壳,其特征在于并入OPV器件的有源层中以增强通过等离激元光阱(PLT)的光吸收。 在一些实施例中,纳米颗粒的峰值消光波长被设计为与OPV带边缘的波长区域一致,以便确保在不良吸收波长处发生光捕获。 在其它实施方案中,由光学活性材料组成的第二壳被沉积到纳米颗粒上,该材料被选择为使得纳米颗粒的芯的消光峰被设计为与稀土能量转变的发射峰值一致 通过利用Purcell效应来增加该波长处的自发发射速率。