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    • 7. 发明授权
    • Anionically-polymerized-rubber-modified styrene copolymers
    • 阴离子聚合橡胶改性苯乙烯共聚物
    • US4972024A
    • 1990-11-20
    • US224329
    • 1988-07-26
    • Mune IwamotoNorifumi ItoKazuo SugazakiTetsuyuki MatsubaraToshihiko AndoYasuo Furuta
    • Mune IwamotoNorifumi ItoKazuo SugazakiTetsuyuki MatsubaraToshihiko AndoYasuo Furuta
    • C08F279/04C08F287/00C08F297/04
    • C08F287/00C08F279/04C08F297/04
    • Disclosed herein is a rubber-modified styrene copolymer which contains as an impact strength modifier a rubbery polymer having a viscosity of 2-250 centipoises as measured at 25.degree. C. as a 5 wt. % styrene solution and a styrene insoluble content lower than 0.1 wt. %, produced by anionic polymerization and dispersed in a continuous phase of a styrene-acrylonitrile copolymer. The rubbery polymer contains small particles of the same styrene-acrylonitrile copolymer occluded in the form of cells. The areas of particles in each of which the maximum cell diameter is smaller than 0.1 .mu.m are at least 40% of the area of all the particles of the rubbery polymer and the volume average particle size of these particles is 0.1-0.4 .mu.m. The weight ratio of the monomers in the styrene-acrylonitrile copolymer is 90/10.gtoreq.styrene/acrylonitrile.gtoreq.55/45. Per 100 parts by weight of the copolymer, the proportions of polymers having a molecular weight greater than 1,000,000 is smaller than 0.5 part by weight while the proportion of polymers having a molecular weight greater than 1,200,000 is smaller than 0.01 part by weight.
    • 本文公开了一种橡胶改性苯乙烯共聚物,其包含作为冲击强度改性剂的橡胶状聚合物,其粘度为2550厘泊,在25℃下测量为5重量% %苯乙烯溶液和低于0.1重量%的苯乙烯不溶物含量。 %,通过阴离子聚合制备并分散在苯乙烯 - 丙烯腈共聚物的连续相中。 橡胶状聚合物含有以细胞形式封闭的相同苯乙烯 - 丙烯腈共聚物的小颗粒。 最大电池直径小于0.1μm的颗粒面积至少为橡胶状聚合物颗粒面积的40%,这些颗粒的体积平均粒径为0.1-0.4μm。 苯乙烯 - 丙烯腈共聚物中单体的重量比为90/10> / =苯乙烯/丙烯腈> / = 55/45。 每100重量份共聚物,分子量大于1,000,000的聚合物的比例小于0.5重量份,而分子量大于1,200,000的聚合物的比例小于0.01重量份。