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    • 7. 发明申请
    • Method for Producing 2-Hydroxyester Compounds
    • 生产2-羟基酯化合物的方法
    • US20080214861A1
    • 2008-09-04
    • US11997856
    • 2006-08-08
    • Ichiro KozonoNaoki FujiwaraDaisuke Hino
    • Ichiro KozonoNaoki FujiwaraDaisuke Hino
    • C07C67/22
    • C07C67/22C07C67/58C07C69/734C07C69/675
    • A simple and easy-to-use method for producing a 2-hydroxyester compound using a cyanohydrin compound, as a raw material, is provided. A method for producing a 2-hydroxyester compound represented by the general formula (1) (provided that ethyl 2-hydroxy-4-phenylbutyrate is excluded), wherein an acid is introduced into a mixture of a cyanohydrin compound represented by the general formula (2), an alcohol, an organic solvent and water:(Chemical Formula 1) R1—CH(OH)—COOR2   (1) R1—CH(OH)(CN)   (2) wherein, R1 is a hydrogen atom, a substituted or unsubstituted aliphatic hydrocarbon group having 1 to 12 carbon atoms, which may contain an oxygen atom, a sulfur atom or a nitrogen atom, a substituted or unsubstituted alicyclic hydrocarbon group having 3 to 12 carbon atoms, which may contain an oxygen atom, a sulfur atom or a nitrogen atom, and a substituted or unsubstituted aryl group or aralkyl group having 3 to 14 carbon atoms, which may contain an oxygen atom, a sulfur atom or a nitrogen atom; and R2 is an alkyl group having 1 to 12 carbon atoms, which may contain an oxygen atom, a sulfur atom or a nitrogen atom.
    • 提供了使用氰醇化合物作为原料制备2-羟基酯化合物的简单且易于使用的方法。 制备由通式(1)表示的2-羟基酯化合物的方法(不包括2-羟基-4-苯基丁酸乙酯),其中将酸引入由通式(2)表示的羟腈化合物的混合物中 2),醇,有机溶剂和水:(化学式1)<?in-line-formula description =“In-line formula”end =“lead”?> R 1 -CH (OH)-COOR 2(1)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In- 线型公式“end =”lead“?> R <1> -CH(OH)(CN)(2)<?in-line-formula description =”In-line Formulas“end =”tail“ 其中,R 1是氢原子,取代或未取代的碳原子数1〜12的脂肪族烃基,可以含有氧原子,硫原子或氮原子,取代或未取代的 可以含有氧原子,硫原子或氮原子的碳原子数3〜12的未取代的脂环式烃基 d可以含有氧原子,硫原子或氮原子的取代或未取代的具有3〜14个碳原子的芳基或芳烷基; R 2是具有1〜12个碳原子的烷基,可以含有氧原子,硫原子或氮原子。
    • 8. 发明授权
    • Insulated wire
    • 绝缘电线
    • US08741441B2
    • 2014-06-03
    • US12829528
    • 2010-07-02
    • Yuki HondaTomiya AbeHideyuki KikuchiDaisuke Hino
    • Yuki HondaTomiya AbeHideyuki KikuchiDaisuke Hino
    • B32B15/08C08L79/08H01B17/60
    • C09D179/08H01B3/305Y10T428/31681Y10T428/31721
    • An insulated wire includes a conductor, and an insulating covering layer formed on a periphery of the conductor and including two or more insulating coatings. The insulating coatings include a polyamide-imide resin insulating material represented by chemical formula 1: where R indicates a divalent aromatic diamine including three or more aromatic rings. The insulating coatings are formed by applying and baking the polyamide-imide resin insulating material, and the polyamide-imide resin insulating material is obtained by reacting an imide group containing dicarboxylic acid with a diisocyanate, the imide group containing dicarboxylic acid being obtained by dehydration reaction of a diamine comprising a divalent aromatic diamine including three or more aromatic rings with an acid using an azeotropic solvent.
    • 绝缘线包括导体和形成在导体的周边上并包括两个或更多个绝缘涂层的绝缘覆盖层。 绝缘涂层包括由化学式1表示的聚酰胺酰亚胺树脂绝缘材料:其中R表示包含三个或更多个芳环的二价芳族二胺。 通过涂布和烘烤聚酰胺酰亚胺树脂绝缘材料形成绝缘涂层,并且通过使含有二羧酸的酰亚胺基与二异氰酸酯反应获得聚酰胺 - 酰亚胺树脂绝缘材料,通过脱水反应得到含有二羧酸的酰亚胺基 的二胺,其包含使用共沸溶剂的含有三个或更多个芳族环的二价芳族二胺与酸。