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1. 发明授权

US06756420B2 Coating composition and a process to form a coating film with use thereof 失效
标题翻译：涂料组合物和使用它形成涂膜的方法
公开(公告)号：US06756420B2
公开(公告)日：2004-06-29
申请号：US10266593
申请日：2002-10-09
申请人： Tetsuo Ogawa , Hisashi Isaka
发明人： Tetsuo Ogawa , Hisashi Isaka
IPC分类号： C08F250
CPC分类号： C09D201/06 , B05D1/02 , B05D3/061 , B05D3/067 , B05D7/536 , B05D7/576 , C08G18/341 , C08G18/4291 , C08G18/6254 , C08G18/792 , C08G18/8077 , C09D175/06 , G03F7/032 , G03F7/038 , C08L2666/16
摘要： This invention provides a high-solids coating composition which comprises (A) a compound which has at least one radically polymerizable unsaturated group per molecule, (B) a hydroxyl group-containing ester compound which is obtained by ester-forming addition reaction between 2,2-dimethylolalkanoic acid having 6 to 8 carbon atoms and alkanoic acid monoglycidylester, and which has an acid value of 20 mgKOH/g or less, (C) a curing agent which is reactive with the above-mentioned hydroxyl group-containing ester compound (B), and (D) a photopolymerization initiator, and also provides a process to form a coating film by spray coating of said coating composition, which process is characterized by irradiating flying paint particles which have been sprayed and/or paint which has been applied onto a substrate with active energy ray so as to make the coating composition partially react, and by subsequently heating the coating composition.
摘要翻译：本发明提供了一种高固含量涂料组合物，其包含（A）每分子具有至少一个可自由基聚合的不饱和基团的化合物，（B）含羟基的酯化合物，其通过酯化形成加成反应获得，具有6至8个碳原子的2-二羟甲基链烷酸和链烷酸单缩水甘油酯，其酸值为20mgKOH / g以下，（C）与上述含羟基酯化合物反应的固化剂（ B）和（D）光聚合引发剂，并且还提供通过所述涂料组合物的喷涂形成涂膜的方法，该方法的特征在于照射已经喷涂的飞溅涂料颗粒和/或涂布的涂料到具有活性能量射线的基底上，以使涂料组合物部分反应，随后加热涂料组合物。

2. 发明授权

US06649786B2 Ester-forming addition reaction product 有权
标题翻译：酯形成加成反应产物
公开(公告)号：US06649786B2
公开(公告)日：2003-11-18
申请号：US10224426
申请日：2002-08-21
申请人： Hisashi Isaka
发明人： Hisashi Isaka
IPC分类号： C07C6966
CPC分类号： C09D175/06 , C07C67/26 , C07C69/675 , C08G18/4283
摘要： This invention provides a process to produce a hydroxyl group-containing ester-forming addition reaction product having an acid value of 20 mgKOH/g or less, which process is characterized in that 2,2-dimethylolalkanoic acid having 6 to 8 carbon atoms is melted, and is then mixed with alkanoic acid monoglycidylester having 8 to 24 carbon atoms so that an ester-forming addition reaction may occur. Thus obtained reaction product contains almost no undesirable high-molecular components, is quite excellent in reactivity and compatibility with a curing agent, and is useful for the manufacture of high-solids paint etc.
摘要翻译：本发明提供一种具有酸值为20mgKOH / g以下的含羟基的酯形成加成反应产物的方法，该方法的特征在于将具有6-8个碳原子的2,2-二羟甲基链烷酸熔融然后与具有8至24个碳原子的链烷酸单缩水甘油酯混合，从而可能发生酯形成加成反应。这样得到的反应产物几乎不包含不期望的高分子组分，反应性和与固化剂的相容性相当优异，可用于制造高固体涂料等。

3. 发明授权

US5691002A Coating method 失效
标题翻译：涂布方法
公开(公告)号：US5691002A
公开(公告)日：1997-11-25
申请号：US596094
申请日：1996-01-31
申请人： Hiroaki Oda , Masaru Mitsuji , Yasumasa Okumura , Hiroshi Inoue , Hisashi Isaka
发明人： Hiroaki Oda , Masaru Mitsuji , Yasumasa Okumura , Hiroshi Inoue , Hisashi Isaka
IPC分类号： B05D1/00 , B05D7/00 , B05D1/36
CPC分类号： B05D7/52 , B05D7/542 , B05D7/587 , B05D1/007
摘要： The coating method of the present invention comprises sequentially applying an amine-neutralized type aqueous intermediate coating composition and an amine-neutralized type aqueous top coating composition, the method being characterized in that a coating composition mainly comprising (A) an amine-neutralized base resin having a hydroxyl value of 30 to 150 KOH mg/g and an acid value of 15 to 50 KOH mg/g, (B) an amino resin and (C) an organic sulfonic acid amine salt is used as the amine-neutralized type aqueous intermediate coating composition. The method of the present invention can improve the adhesion between layers of a multi-layer coating film formed from aqueous coating compositions and chipping resistance of said coating film.
摘要翻译： PCT No.PCT / JP95 / 01079 Sec。 371日期1996年1月31日 102（e）日期1996年1月31日PCT归档1995年6月1日PCT公布。出版物WO95 / 33578 日期1995年12月14日本发明的涂布方法包括依次施加胺中和型水性中间体涂料组合物和胺中和型水性顶涂料组合物，其特征在于，主要包含（A）使用羟基值为30〜150KOHmg / g，酸值为15〜50KOHmg / g，（B）氨基树脂和（C）有机磺酸胺盐的胺中和基础树脂作为胺中和型水性中间体涂料组合物。本发明的方法可以提高由水性涂料组合物形成的多层涂膜和所述涂膜的耐崩裂性之间的粘合力。

4. 发明授权

US06894124B2 High solid paint compositions 失效
标题翻译：高固含量组合物
公开(公告)号：US06894124B2
公开(公告)日：2005-05-17
申请号：US09984793
申请日：2001-10-31
申请人： Yoshizumi Matsuno , Hiroyuki Onoda , Takashi Noguchi , Hisashi Isaka
发明人： Yoshizumi Matsuno , Hiroyuki Onoda , Takashi Noguchi , Hisashi Isaka
IPC分类号： C08G18/42 , C08G18/62 , C08G18/63 , C08G18/79 , C09D175/04 , C09D161/28 , C08L61/28 , C08L75/06 , C09D175/06
CPC分类号： C08G18/792 , C08G18/4269 , C08G18/4291 , C08G18/6254 , C08G18/63 , C09D175/04 , C08L2666/16
摘要： This invention provides high solid paint compositions comprising as the basic components a hydroxyl-containing compound having a weight-average molecular weight of not more than 1,000 and a hydroxyl value of 200-800 mgKOH/g, and a polyisocyanate compound, and a process for forming multi-layered coating film using any of said compositions.
摘要翻译：本发明提供高固体涂料组合物，其包含重均分子量不大于1,000，羟基值为200-800mgKOH / g的羟基化合物和多异氰酸酯化合物作为碱性组分，和使用任何所述组合物形成多层涂膜。

5. 发明授权

US5635251A Wet-on-wet coating method 失效
标题翻译：湿法湿法涂布法
公开(公告)号：US5635251A
公开(公告)日：1997-06-03
申请号：US442702
申请日：1995-05-17
申请人： Hiroaki Oda , Yasumasa Okumura , Hiroshi Inoue , Hisashi Isaka
发明人： Hiroaki Oda , Yasumasa Okumura , Hiroshi Inoue , Hisashi Isaka
IPC分类号： B05D7/00 , C09D201/08 , B05D1/36 , B05D3/02 , B05D7/26
CPC分类号： B05D7/542 , C09D201/08
摘要： The present invention provides a wet-on-wet coating method comprising applying a thermosetting aqueous coating composition (A), and applying a thermosetting aqueous coating composition (B) to the uncured coating surface of the aqueous coating composition (A) wherein the aqueous coating composition (A) contains a base resin with a neutralization value of 20 to 30 KOH mg/g and the aqueous coating composition (B) contains a base resin with a neutralization value higher by 10 to 20 KOH mg/g than the base resin of the aqueous coating composition (A).
摘要翻译：本发明提供一种湿式湿式涂布方法，其包括涂布热固性水性涂料组合物（A），并向所述水性涂料组合物（A）的未固化涂料表面涂布热固性水性涂料组合物（B），其中所述水性涂料组合物（A）含有中和值为20〜30KOHmg / g的基础树脂，水性涂料组合物（B）含有中和值高于10〜20KOHmg / g的基础树脂，水性涂料组合物（A）。

6. 发明授权

US5374665A Antifouling paint composition 失效
标题翻译：防污漆组成
公开(公告)号：US5374665A
公开(公告)日：1994-12-20
申请号：US110676
申请日：1993-08-09
申请人： Hisashi Isaka , Osamu Isozaki
发明人： Hisashi Isaka , Osamu Isozaki
IPC分类号： C09D5/00 , C09D5/14 , C09D5/16 , C09D151/00 , C08L51/00 , B32B9/04
CPC分类号： C09D151/003 , Y10S525/902 , Y10T428/31504
摘要： An antifouling paint composition comprising a resin vehicle, an antifouling agent and a liquid medium, at least part of the resin vehicle being composed of a nonaqueous dispersion-type resin of a skin-core structure having in the core component an acid group or an acid precursor group convertible into the acid group by hydrolysis, and said antifouling composition being capable of maintaining an effect of preventing adhesion of microorganisms over along term.
摘要翻译：一种防污涂料组合物，其包含树脂载体，防污剂和液体介质，所述树脂载体的至少一部分由在芯组分中具有酸基或酸的皮芯结构的非水分散型树脂前体基团可通过水解转化成酸基，并且所述防污组合物能够保持防止微生物粘附的效果。

7. 发明授权

US5705595A Aqueous intercoat composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US5705595A
公开(公告)日：1998-01-06
申请号：US595788
申请日：1996-02-02
申请人： Hiroaki Oda , Mikio Shimakawa , Hisashi Isaka , Naoji Matsumoto
发明人： Hiroaki Oda , Mikio Shimakawa , Hisashi Isaka , Naoji Matsumoto
IPC分类号： C09D5/00 , C08G18/30 , C08G18/42 , C09D167/00 , C09D175/00 , C09D175/06 , C08G18/34
CPC分类号： C09D175/06 , C08G18/302 , C08G18/4263 , C08G18/4286 , C09D167/00
摘要： This invention provides an aqueous intercoat composition comprising, as main components, (A) a polyester resin having a hydroxyl group and a carboxyl group in one molecule, (B) a blocked product of at least one polyisocyanate selected from a polymer of aliphatic polyisocyanate, an adduct of said polymer with an active hydrogen-containing compound and an adduct of aliphatic polyisocyanate with an active hydrogen-containing compound, and (C) water. The aqueous intercoat composition of the invention is capable of forming a coating film excellent in chipping resistance.
摘要翻译：本发明提供一种水性涂料组合物，其包含作为主要成分的（A）在一个分子中具有羟基和羧基的聚酯树脂，（B）至少一种选自脂族多异氰酸酯的聚合物的多异氰酸酯的封端产物，所述聚合物与活性含氢化合物的加合物和脂族多异氰酸酯与活性含氢化合物的加合物，和（C）水。本发明的水性涂料组合物能够形成耐崩裂性优异的涂膜。

8. 发明授权

US5426135A Composition for forming soil preventing coating 失效
标题翻译：防止涂层的成分
公开(公告)号：US5426135A
公开(公告)日：1995-06-20
申请号：US177934
申请日：1994-01-06
申请人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
发明人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
IPC分类号： C08F8/42 , C08F8/46 , C08G77/442 , C09D5/16 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10
CPC分类号： C08G77/442 , C08F8/42 , C08F8/46 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10 , C09D5/165
摘要： The present invention provides a soil preventing coating forming composition which consists essentially of a resin having at least two acid anhydride groups in the molecule on the average, the acid anhydride groups being represented by the formula ##STR1## wherein R is a C.sub.1-40 monovalent hydrocarbon group or a monovalent chain polysiloxane group represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and are each alkyl, cycloalkyl, aryl, aralkyl or ##STR3## group, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are the same or different and are each alkyl, cycloalkyl, aryl or aralkyl, n is an integer of 1 to 6, m is an integer of 0 or 1, p is an integer of 2 to 50, and q is an integer of 0 to 50.
摘要翻译：本发明提供一种防污涂层形成组合物，其基本上由分子中具有至少两个酸酐基团的树脂组成，平均酸酐基由式碳基团表示，或由式式（II）其中R 1和R 2相同或不同并且各自为烷基，环烷基，芳基，芳烷基或者基团，R 3，R 4，R 5，R 6和R 7相同或不同，各自为烷基，环烷基，芳基或芳烷基，n为1〜6的整数，m为0或1的整数，p为2〜50的整数，q为0〜50的整数。

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