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1. 发明授权

US08536274B2 Paint composition and painted objects 失效
标题翻译：油漆成分和油漆物体
公开(公告)号：US08536274B2
公开(公告)日：2013-09-17
申请号：US11995405
申请日：2006-07-03
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nimi
IPC分类号： C08F8/30 , C08L75/06
CPC分类号： C09D175/04 , C08G18/6233 , C08G18/6237 , C08G18/7831
摘要： Disclosed herein is a clear paint composition, comprising (A) an acrylic copolymer comprising from 35 to 50 wt % ε-caprolactone structural units, based on the resin solid fraction, and wherein the hydroxyl number is from 200 to 340 mgKOH/g and the weight average molecular weight is from 5,000 to 15,000 and (B) a non-yellowing type polyisocyanate compound, wherein the isocyanate group of the (B) component is included in a proportion of from 0.5 to 2 equivalents per 1 equivalent of hydroxyl group of the (A) component, wherein the Young's modulus of the hardened paint film obtained from said paint composition is not more than 1.5 Pa, wherein the molecular weight of intercrosslinking of the cured coating film (Mc) is not more than 350 g/mol, and wherein the glass transition temperature (Tg) of the hardened paint film is at least 65° C.
摘要翻译：本文公开了一种透明涂料组合物，其包含（A）基于树脂固体部分包含35至50重量％ε-己内酯结构单元的丙烯酸共聚物，其中羟基数为200至340mgKOH / g，重均分子量为5,000〜15,000，（B）不泛黄型多异氰酸酯化合物，其中，（B）成分的异氰酸酯基的比例为0.5〜2当量/ 1当量的羟基（A）成分，其中由所述涂料组合物获得的硬化漆膜的杨氏模量不大于1.5Pa，其中固化涂膜（Mc）的交联分子量不大于350g / mol，其中硬化漆膜的玻璃化转变温度（Tg）至少为65℃。

2. 发明授权

US07981964B2 Thermosetting paint compositions 有权
标题翻译：热固性涂料组合物
公开(公告)号：US07981964B2
公开(公告)日：2011-07-19
申请号：US11917360
申请日：2006-06-13
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nimi
IPC分类号： C08F212/08 , C08F8/16 , C08F220/20
CPC分类号： C08G81/027 , C08G18/672 , C08G18/7831 , C08L33/066 , C08L67/04 , C09D133/066 , C09D167/04 , C09D175/16 , C08G18/0823 , C08G18/62 , C08L2666/04 , C08L2666/18
摘要： Disclosed herein is a heat-hardenable paint composition comprising a base resin, wherein the base resin comprises (A) a lactone modified resin comprising hydroxyl groups, wherein 20 to 70 weight percent of the structural units are based on the lactone compound, and the hydroxyl group value is from 50 to 400 mgKOH/g, and (B) an acrylic resin comprising hydroxyl groups and cyclic structures, wherein 10 to 80 weight percent of structural units are based on a radically polymerizable monomer comprising a cyclic structure, the hydroxyl group value is from 50 to 150 mgKOH/g, and the crosslinking resin is an isocyanate compound, wherein the weight ratio of the solid fractions of (A):(B) in the base resin is from 95:5 to 20:80.
摘要翻译：本文公开了一种包含基础树脂的热硬化性涂料组合物，其中所述基础树脂包含（A）包含羟基的内酯改性树脂，其中20至70重量％的结构单元是基于内酯化合物，和羟基基团值为50-400mgKOH / g，（B）包含羟基和环状结构的丙烯酸树脂，其中10至80重量％的结构单元基于包含环状结构的自由基聚合单体，羟基值为50〜150mgKOH / g，交联树脂为异氰酸酯化合物，其中，（A）:( B）的固体成分在基础树脂中的重量比为95:5〜20:80。

3. 发明授权

US07906580B2 Paint composition, a method of paint finishing and painted objects 有权
标题翻译：油漆成分，油漆涂装方法和涂漆物品
公开(公告)号：US07906580B2
公开(公告)日：2011-03-15
申请号：US11997631
申请日：2006-07-13
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nmi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Nmi
IPC分类号： C08F290/14 , C08L33/02 , C08L37/00
CPC分类号： C09D133/066 , C08L33/066 , C08L2205/02 , C08L2666/04
摘要： Disclosed herein is a paint composition, comprising a hydroxyl group containing resin (A), having a hydroxyl group value of from 200 to 400 mgKOH/g, and comprising in a resin solid fraction less than 25 weight % of structural units based on a lactone compound, a hydroxyl group containing resin (B), having a hydroxyl group value of from 50 to 200 mgKOH/g, and comprising in the resin solid fraction from 25 to 75 weight % of structural units based on a lactone compound, and a crosslinking agent (C) comprising at least one functional group which reacts with hydroxyl groups, wherein the proportions by weight (A)/(B) of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), based on the resin solid fraction, are from 90/10 to 10/90.
摘要翻译：本文公开了一种涂料组合物，其包含含羟基的树脂（A），其羟基值为200-400mgKOH / g，并且包含基于内酯的结构单元小于25重量％的树脂固体部分化合物，含羟基的树脂（B），羟基值为50〜200mgKOH / g，在树脂固体成分中含有25〜75重量％的基于内酯化合物的结构单元，交联包含至少一个与羟基反应的官能团的试剂（C），其中基于羟基的树脂（A）和含羟基的树脂（B）的重量比（A）/（B）树脂固体成分为90/10〜10/90。

4. 发明申请

US20080227918A1 Paint Composition, a Method of Paint Finishing and Painted Objects 有权
标题翻译：油漆成分，油漆成品和涂漆物体的方法
公开(公告)号：US20080227918A1
公开(公告)日：2008-09-18
申请号：US11997631
申请日：2006-07-13
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
IPC分类号： C08L33/02
CPC分类号： C09D133/066 , C08L33/066 , C08L2205/02 , C08L2666/04
摘要： Disclosed herein is a paint composition, comprising a hydroxyl group containing resin (A), having a hydroxyl group value of from 200 to 400 mgKOH/g, and comprising in a resin solid fraction less than 25 weight % of structural units based on a lactone compound, a hydroxyl group containing resin (B), having a hydroxyl group value of from 50 to 200 mgKOH/g, and comprising in the resin solid fraction from 25 to 75 weight % of structural units based on a lactone compound, and a crosslinking agent (C) comprising at least one functional group which reacts with hydroxyl groups, wherein the proportions by weight (A)/(B) of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), based on the resin solid fraction, are from 90/10 to 10/90.
摘要翻译：本文公开了一种涂料组合物，其包含含羟基的树脂（A），其羟基值为200-400mgKOH / g，并且包含基于内酯的结构单元小于25重量％的树脂固体部分化合物，含羟基的树脂（B），羟基值为50〜200mgKOH / g，在树脂固体成分中含有25〜75重量％的基于内酯化合物的结构单元，交联包含至少一个与羟基反应的官能团的试剂（C），其中基于羟基的树脂（A）和含羟基的树脂（B）的重量比（A）/（B）树脂固体成分为90/10〜10/90。

5. 发明申请

US20080227915A1 Paint Composition and Painted Objects 失效
标题翻译：油漆成分和绘画物体
公开(公告)号：US20080227915A1
公开(公告)日：2008-09-18
申请号：US11995405
申请日：2006-07-03
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
IPC分类号： C09D175/12
CPC分类号： C09D175/04 , C08G18/6233 , C08G18/6237 , C08G18/7831
摘要： Disclosed herein is a clear paint composition, comprising (A) an acrylic copolymer comprising from 35 to 50 wt % ε-caprolactone structural units, based on the resin solid fraction, and wherein the hydroxyl number is from 200 to 340 mgKOH/g and the weight average molecular weight is from 5,000 to 15,000 and (B) a non-yellowing type polyisocyanate compound, wherein the isocyanate group of the (B) component is included in a proportion of from 0.5 to 2 equivalents per 1 equivalent of hydroxyl group of the (A) component, wherein the Young's modulus of the hardened paint film obtained from said paint composition is not more than 1.5 Pa, wherein the molecular weight of intercrosslinking of the cured coating film (Mc) is not more than 350 g/mol, and wherein the glass transition temperature (Tg) of the hardened paint film is at least 65° C.
摘要翻译：本文公开了一种透明涂料组合物，其包含（A）基于树脂固体部分包含35至50重量％ε-己内酯结构单元的丙烯酸共聚物，其中羟基数为200至340mgKOH / g，重均分子量为5,000〜15,000，（B）不泛黄型多异氰酸酯化合物，其中，（B）成分的异氰酸酯基的比例为0.5〜2当量/ 1当量的羟基（A）成分，其中由所述涂料组合物获得的硬化漆膜的杨氏模量不大于1.5Pa，其中固化涂膜（Mc）的交联分子量不大于350g / mol，其中硬化漆膜的玻璃化转变温度（Tg）至少为65℃。

6. 发明申请

US20080177006A1 Paint Composition, a Painting and Finishing Method, and Painted Articles 审中-公开
标题翻译：油漆成分，绘画和表面处理方法以及绘画文章
公开(公告)号：US20080177006A1
公开(公告)日：2008-07-24
申请号：US11910671
申请日：2006-04-11
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Tagkagi , Rui Niimi
IPC分类号： C08G65/26
CPC分类号： C08G18/6237 , C08G18/7831 , C09D4/06 , C09D175/04
摘要： The provision of a paint composition that affords a paint film of excellent acid rain resistance, contamination resistance, water resistance, weather resistance and painting workability, with particularly excellent resistance to vehicle wash damage; and a painting and finishing method, and painted articles. [Overcoming means] A paint composition, characterized in that it has as indispensable components (A) a hydroxyl group-containing resin that is obtained by the addition and polymerization of (a) a compound that contains one carboxyl group and does not have a radical polymerizable double bond, (b) a lactone compound, and (c) an epoxy group-containing radical polymerizable monomer, and, if necessary, (d) another radical polymerizable monomer, and which has a resin hydroxyl value of from 180 to 400 mgKOH/g and a weight average molecular weight of from 2000 to 30,000, and in which the structural unit based on the lactone compound component (b) is from 20 to 60% by mass of the resin solids content; and (B) a crosslinking agent containing per molecule at least one functional group that reacts with hydroxyl groups.
摘要翻译：提供具有优异耐酸雨性，耐污染性，耐水性，耐候性和涂漆加工性的漆膜的涂料组合物，具有特别优异的耐车辆洗涤损伤性; 和一个绘画和整理方法，并绘制文章。 [克服方法]一种涂料组合物，其特征在于，其具有通过（a）含有一个羧基并且不具有自由基的化合物的加成和聚合而获得的含羟基树脂作为不可缺少的成分（A）可聚合双键，（b）内酯化合物和（c）含环氧基的可自由基聚合的单体，如果需要，（d）另一种可自由基聚合的单体，其树脂羟值为180-400mgKOH / g，重均分子量为2000〜30,000，其中基于内酯化合物成分（b）的结构单元的树脂固含量为20〜60质量％和（B）每分子含有至少一个与羟基反应的官能团的交联剂。

7. 发明申请

US20100130668A1 THERMOSETTING PAINT COMPOSITIONS 有权
标题翻译：热固性涂料组合物
公开(公告)号：US20100130668A1
公开(公告)日：2010-05-27
申请号：US11917360
申请日：2006-06-13
申请人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Takagi , Rui Niimi
发明人： Tetsu Konishi , Shinji Mitsumune , Masayuki Takemoto , Takehito Ito , Hiroyuki Takagi , Rui Niimi
IPC分类号： C08G18/83
CPC分类号： C08G81/027 , C08G18/672 , C08G18/7831 , C08L33/066 , C08L67/04 , C09D133/066 , C09D167/04 , C09D175/16 , C08G18/0823 , C08G18/62 , C08L2666/04 , C08L2666/18
摘要： Disclosed herein is a heat-hardenable paint composition comprising a base resin, wherein the base resin comprises (A) a lactone modified resin comprising hydroxyl groups, wherein 20 to 70 weight percent of the structural units are based on the lactone compound, and the hydroxyl group value is from 50 to 400 mgKOH/g, and (B) an acrylic resin comprising hydroxyl groups and cyclic structures, wherein 10 to 80 weight percent of structural units are based on a radically polymerizable monomer comprising a cyclic structure, the hydroxyl group value is from 50 to 150 mgKOH/g, and the crosslinking resin is an isocyanate compound, wherein the weight ratio of the solid fractions of (A):(B) in the base resin is from 95:5 to 20:80.
摘要翻译：本文公开了一种包含基础树脂的热硬化性涂料组合物，其中所述基础树脂包含（A）包含羟基的内酯改性树脂，其中20至70重量％的结构单元基于内酯化合物，并且羟基基团值为50-400mgKOH / g，（B）包含羟基和环状结构的丙烯酸树脂，其中10至80重量％的结构单元基于包含环状结构的自由基聚合单体，羟基值为50〜150mgKOH / g，交联树脂为异氰酸酯化合物，其中，（A）:( B）的固体成分在基础树脂中的重量比为95:5〜20:80。

8. 发明授权

US4883858A Thermosetting resin from amine terminated amic acid and bis-maleimide 失效
标题翻译：胺封端的酰胺酸和双马来酰亚胺的热固性树脂
公开(公告)号：US4883858A
公开(公告)日：1989-11-28
申请号：US234411
申请日：1988-08-19
申请人： Masayuki Takemoto , Osamu Nagura , Yukio Nomura , Minoru Yasuda
发明人： Masayuki Takemoto , Osamu Nagura , Yukio Nomura , Minoru Yasuda
IPC分类号： C08G73/10 , C08G73/12
CPC分类号： C08G73/101 , C08G73/10 , C08G73/121
摘要： A premix, an origomeric prepolymer obtainable from a limited addition polymerization effected with the premix and a thermosetting resin obtainable from such premix or prepolymer as well as fiber reinforced plastics made of such thermosetting resin which are excellent in the heat resistance, impact resistance and flexibility and exhibit a high toughness, wherein said premix comprises, as a first essential component, an amine-terminated amic acid expressed by the formula, ##STR1## in which R.sup.1 stands for a tetravalent aromatic residue having 6 to 20 carbon atoms and R.sup.2 denotes a divalent organic residue having 2 to 20 carbon atoms, said amic acid being produced by reacting a tetracarboxylic dianhydride with a diamine compound, and, as a second essential component, an N,N'-bis maleimide of the formula, ##STR2## wherein R.sup.3 denotes a divalent organic residue having 2 to 20 carbon atoms, the mole ratio of [N,N'-bismaleimide]/[amine-terminated amic acid] being in the range from 1 to 3.

9. 发明授权

US06403670B1 Thermosetting composition containing polyhemiacetal ester resin and powdery thermosetting composition 失效
标题翻译：含有聚缩醛酯树脂和粉末状热固性组合物的热固性组合物
公开(公告)号：US06403670B1
公开(公告)日：2002-06-11
申请号：US09623127
申请日：2000-10-13
申请人： Masahiro Ishidoya , Masayuki Takemoto , Atsushi Sato , Koji Sato , Shun Saito
发明人： Masahiro Ishidoya , Masayuki Takemoto , Atsushi Sato , Koji Sato , Shun Saito
IPC分类号： C08F400
CPC分类号： C09D167/025 , C08G18/683 , C08G18/8077 , C08G2150/20 , C08K5/0025 , C08L63/00 , C08L67/025 , C08L101/02 , Y10S525/934 , C08L2666/02 , C08L2666/28
摘要： The present invention relates to a thermosetting composition which comprises: (A) a polyhemiacetal ester resin having a repeat unit represented by formula (1): wherein R1 and R2 are a bivalent organic group, and Y is an oxygen atom or a sulfur atom, and (B) a compound having in the molecule two or more reactive functional groups which can form a chemical bond with the carboxyl group, and optionally, (C) an acid catalyst. The thermosetting composition gives cured products having excellent chemical properties, physical properties, adhesion, smoothness and weathering resistance at relatively lower temperatures and have excellent storage stability, and can be utilized as solvent cutback type, solventless liquid type of 100% effective component or powder thermosetting compositions.
摘要翻译：本发明涉及一种热固性组合物，其包含：（A）具有由式（1）表示的重复单元的聚缩醛酯树脂：其中R1和R2是二价有机基团，Y是氧原子或硫原子，和（B）在分子中具有两个或更多个与羧基形成化学键的反应性官能团的化合物，和任选的（C）酸催化剂。热固性组合物在相对较低的温度下提供具有优异的化学性质，物理性质，粘合性，光滑性和耐候性的固化产物，并且具有优异的储存稳定性，并且可以用作溶剂切割型，无溶剂型的100％有效成分或粉末热固性组合物。

10. 发明授权

US5132180A Composite paint film coating 失效
标题翻译：复合漆涂膜
公开(公告)号：US5132180A
公开(公告)日：1992-07-21
申请号：US521966
申请日：1990-05-11
申请人： Hiroyuki Kishi , Hitoshi Kimura , Katsuya Yamamoto , Yoshinobu Tamura , Tsuneo Sakauchi , Masahide Nagaoka , Masaya Kawabata , Akitoshi Shirasaka , Shinichi Inoue , Makoto Efumi , Shosaku Yamamoto , Michiaki Wake , Masayuki Takemoto , Naoya Sakai
发明人： Hiroyuki Kishi , Hitoshi Kimura , Katsuya Yamamoto , Yoshinobu Tamura , Tsuneo Sakauchi , Masahide Nagaoka , Masaya Kawabata , Akitoshi Shirasaka , Shinichi Inoue , Makoto Efumi , Shosaku Yamamoto , Michiaki Wake , Masayuki Takemoto , Naoya Sakai
IPC分类号： B32B15/08 , B05D1/04 , B05D7/14 , B05D7/24 , C09D5/44 , C25D13/00
CPC分类号： C09D5/4473 , Y10T428/31678 , Y10T428/31681 , Y10T428/31786
摘要： A composite paint film coating formed on a steel sheet of an automotive vehicle body. The composite paint film coating is comprised of an electrodeposition paint film (I) coated on the steel sheet, and an intermediate paint film (II) coated on the first paint film. The electrodeposition paint film has a minimum melt viscosity not less than 0.2 during hardening. The electrodepositon paint film is formed of cathodic electrodeposition paint composition which includes a cationic thermosetting resin (1), and an already cross-linked particulate resin (2). The particlate resin is an addition-polymer formed between a fist compound (A) having at least two primary amino groups in a molecule, and a second compound (B) having at least two .alpha.,.beta.-ethylenic unsaturated groups. The particulate resin has an average particle size ranging from 0.01 to 1 .mu.m. The weight ratio ((2)/(1)) in solid content between the particulate resin (2) cationic thermosetting resin (1) is within a range from 0.03 to 0.15. The intermediate paint film (II) has hardening starting time ranging from 5 to 20 minutes.

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