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    • 5. 发明授权
    • Method and apparatus for converting sulfur dioxide in gas to sulfur
    • 将气体中的二氧化硫转化为硫的方法和装置
    • US4341753A
    • 1982-07-27
    • US184759
    • 1980-09-08
    • Toshikatsu MoriTeruo KumagaiShimpei MatsudaFumito Nakajima
    • Toshikatsu MoriTeruo KumagaiShimpei MatsudaFumito Nakajima
    • C01B17/04
    • C01B17/0473C01B17/0408Y10S423/05
    • There is provided a method for converting sulfur dioxide in an exhaust gas to sulfur, which comprises the reduction step of reducing sulfur dioxide in an exhaust gas containing water vapor to hydrogen sulfide in the presence of carbon, a part of the exhaust gas is caused to bypass the reduction step and the remainder of the exhaust gas is fed to the reduction step to convert sulfur dioxide in the exhaust gas to hydrogen sulfide; the gas from the reduction step is mixed with the exhaust gas bypassing the reduction step while controlling the amount of the bypassing exhaust gas so that the ratio of hydrogen sulfide to sulfur dioxide in the mixed gas is maintained at 2; the mixed gas is fed to the Claus reaction step; and the Claus reaction step of reacting hydrogen sulfide formed at the reduction step with sulfur dioxide to convert hydrogen sulfide to sulfur.
    • 提供了一种将废气中的二氧化硫转化为硫的方法,其包括在碳存在下将含有水蒸汽的废气中的二氧化硫还原为硫化氢的还原步骤,将一部分废气引起 旁路还原步骤,将剩余的废气送入还原步骤,将废气中的二氧化硫转化为硫化氢; 来自还原步骤的气体与绕过还原步骤的排气混合,同时控制旁路废气的量,使得混合气体中的硫化氢与二氧化硫的比例保持在2; 将混合气体送入Claus反应步骤; 和在还原步骤中形成的硫化氢与二氧化硫反应以将硫化氢转化为硫的Claus反应步骤。
    • 6. 发明授权
    • Process for desulfurizing combustion exhaust gases
    • 燃烧废气脱硫工艺
    • US4328195A
    • 1982-05-04
    • US130388
    • 1980-03-14
    • Toshikatsu MoriTeruo KumagaiShinpei MatsudaTsukasa NishimuraYasuyuki Nishimura
    • Toshikatsu MoriTeruo KumagaiShinpei MatsudaTsukasa NishimuraYasuyuki Nishimura
    • B01D53/50B01D53/68B01D53/77C01F11/46C01B17/00
    • C01F11/464B01D53/501B01D53/68
    • An improved process for desulfurizing combustion exhaust gases of mainly coal containing sulfur oxides, HF and dust containing Al is provided, which process consists of four steps; a first step of contacting the gases with calcium carbonate or hydroxide in the form of slurry to convert the sulfur oxides into CaSO.sub.3 ; a second step of contacting O.sub.2 with the resulting slurry to convert CaSO.sub.3 into CaSO.sub.4 ; a third step of separating CaSO.sub.4 and mother liquor from the resulting slurry; and a fourth step of preparing a slurry of calcium carbonate or hydroxide to be employed in the first step, from the mother liquor, the pHs of the slurry and the mother liquor in the first and fourth steps being adjusted to 5 or higher by adding alkali such as sodium carbonate.According to the present process, it is possible to prevent hindrance of HF and Al contained in dust to the reaction of SO.sub.2 -absorbent (CaCO.sub.3 or Ca[OH].sub.2) with SO.sub.2 gas, and thereby improve percentage desulfurization and also obtain a high quality gypsum.
    • 提供了一种改进的主要含硫硫氧化物,HF和含有Al的粉尘的燃烧废气脱硫方法,该方法由四个步骤组成: 将气体与浆料形式的碳酸钙或氢氧化物接触以将硫氧化物转化为CaSO 3的第一步骤; 使O 2与所得浆料接触以将CaSO 3转化为CaSO 4的第二步骤; 从所得浆料中分离出CaSO 4和母液的第三步骤; 以及在母液中制备第一步中使用的碳酸钙或氢氧化物浆料的第四步骤,通过加入碱将第一步骤和第四步骤中的浆料和母液的pH调节至5以上 如碳酸钠。 根据本方法,可以防止SO 2吸收剂(CaCO 3或Ca [OH] 2)与SO 2气体反应中灰尘中含有的HF和Al的阻碍,从而提高脱硫率并获得高质量 石膏