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    • 3. 发明授权
    • Silver halide photographic materials and process of developing them
    • 卤化银照相材料及其开发工艺
    • US4452882A
    • 1984-06-05
    • US489907
    • 1983-04-29
    • Yoshitaka AkimuraEiichi OkutsuShigenori MoriuchiNaomi SaekiTaiji HashimuraHiroyuki Mifune
    • Yoshitaka AkimuraEiichi OkutsuShigenori MoriuchiNaomi SaekiTaiji HashimuraHiroyuki Mifune
    • G03C5/29G03C1/043G03C1/06G03C1/36G03C5/30
    • G03C1/043Y10S430/15
    • A silver halide photographic light-sensitive material and a developing process used in connection with that material are disclosed. The material is comprised of a support having thereon a silver halide emulsion layer containing a silver halide emulsion in which at least 80 mole % of the whole silver halide is composed of silver chloride, the mean grain size thereof is less than 0.4 .mu.m, and which contains more than 1.times.10.sup.-6 mole of a water-soluble rhodium salt per mole of silver at an optional period before finishing the first ripening in the production step for the silver halide emulsion. The material also contains 1.times.10.sup.-5 to 1.times.10.sup.-2 mole of polyalkylene oxide having a molecular weight of at least 600 or a derivative thereof per mole of silver. The process involves imagewise exposing the material and processing it in a developer containing 0.05 to 0.5 mole/liter of a dihydroxybenzene series developing agent, 0 to 0.05 g/liter of an auxiliary developing agent, at least 0.25 mole/liter of a free sulfite ion, at least 20 mg/liter of 5- or 6-nitroindazole, and an alkali of an amount sufficient for keeping the pH of the developer higher than 10.5. The material and processing are capable of providing good letter image quality in a short developing time.
    • 公开了卤化银照相感光材料和与该材料结合使用的显影方法。 该材料由其上含有卤化银乳剂层的载体组成,其中至少80%(摩尔)的卤化银全部由氯化银组成,其平均粒径小于0.4μm, 其在完成在卤化银乳剂的制备步骤中的第一次熟化之前的任选时间内每摩尔银含有大于1×10 -6摩尔的水溶性铑盐。 该材料还含有1×10-5至1×10-2摩尔的分子量至少为600的聚环氧烷或其每摩尔银的衍生物。 该方法包括成像曝光材料并在包含0.05至0.5摩尔/升二羟基苯系列显影剂,0至0.05克/升辅助显影剂,至少0.25摩尔/升游离亚硫酸根离子 ,至少20mg / l的5-或6-硝基吲唑,以及足以使显影剂的pH保持在10.5以上的量的碱。 材料和加工能够在短时间内提供良好的信函图像质量。