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1. 发明授权

US06482315B1 Gasoline sulfur reduction in fluid catalytic cracking 有权
标题翻译：汽油硫化液流化催化裂化
公开(公告)号：US06482315B1
公开(公告)日：2002-11-19
申请号：US09649627
申请日：2000-08-28
申请人： Terry G. Roberie , Ranjit Kumar , Michael Scott Ziebarth , Wu-Cheng Cheng , Xinjin Zhao , Nazeer Bhore
发明人： Terry G. Roberie , Ranjit Kumar , Michael Scott Ziebarth , Wu-Cheng Cheng , Xinjin Zhao , Nazeer Bhore
IPC分类号： C10G2904
CPC分类号： C10G11/05 , C10G11/02 , C10G11/18 , C10G2300/202 , C10G2300/4093 , C10G2300/70 , C10G2300/80 , C10G2400/02 , C10L1/06
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction additive comprising a non-molecular sieve support containing a high content of vanadium. Preferably, the support is alumina. The sulfur reduction catalyst is used in the form of a separate particle additive in combination with the active catalytic cracking catalyst (normally a faujasite such as zeolite Y) to process hydrocarbon feedstocks in the fluid catalytic cracking (FCC) unit to produce low-sulfur gasoline and other liquid products.
摘要翻译：通过使用包含含有高含量钒的非分子筛载体的硫还原添加剂，催化裂化过程的液体裂解产物，特别是裂化汽油的硫含量降低。优选地，载体是氧化铝。硫还原催化剂以单独的颗粒添加剂的形式与活性催化裂化催化剂（通常为八面沸石如沸石Y）结合使用以处理流化催化裂化（FCC）单元中的烃原料以产生低硫汽油和其他液体产品。

2. 发明授权

US07153413B2 Gasoline sulfur reduction in fluid catalytic cracking 有权
标题翻译：汽油硫化液流化催化裂化
公开(公告)号：US07153413B2
公开(公告)日：2006-12-26
申请号：US09901939
申请日：2001-07-10
申请人： Terry G. Roberie , Ranjit Kumar , Michael S Ziebarth , Wu-Cheng Cheng , Xinjin Zhao , Nazeer Bhore
发明人： Terry G. Roberie , Ranjit Kumar , Michael S Ziebarth , Wu-Cheng Cheng , Xinjin Zhao , Nazeer Bhore
IPC分类号： C10G11/18
CPC分类号： C10G11/05 , C10G11/02
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, is reduced in a catalytic cracking process employing a cracking catalyst containing a high content of vanadium. The cracking process involves introducing at least one vanadium compound into a hydrocarbon-sulfur containing feedstock to be charged to a fluid catalytic cracking reactor operating under steady state conditions and containing an equilibrium fluid cracking catalyst inventory within the reactor. The amount of sulfur in the liquid products, in particular gasoline and LCO fractions, is reduced as a result of the increased vanadium content on the equilibrium catalyst. Advantageously, sulfur reduction is achieved even in the presence of other metal contaminants, such as nickel and iron, on the equilibrium catalyst.
摘要翻译：在使用含钒量高的裂化催化剂的催化裂化过程中，液体裂解产物，特别是裂化汽油的硫含量降低。裂解过程包括将至少一种钒化合物引入含烃 - 硫的原料中，以将其装入在稳态条件下运行并在反应器内含有平衡流体裂解催化剂存量的流化催化裂化反应器。由于在平衡催化剂上的钒含量增加，液体产物中的硫的量，特别是汽油和LCO馏分的量减少。有利的是，即使在平衡催化剂上存在其它金属污染物如镍和铁的情况下也能实现硫还原。

3. 发明授权

US07452839B2 Gasoline sulfur reduction in fluid catalytic cracking 有权
标题翻译：汽油硫化液流化催化裂化
公开(公告)号：US07452839B2
公开(公告)日：2008-11-18
申请号：US11013481
申请日：2004-12-16
申请人： Wu-Cheng Cheng , Terry G. Roberie , Hye Kyung Cho Timken , Scott Kevin Purnell , Xinjin Zhao
发明人： Wu-Cheng Cheng , Terry G. Roberie , Hye Kyung Cho Timken , Scott Kevin Purnell , Xinjin Zhao
IPC分类号： B01J29/06
CPC分类号： C10G11/05 , B01J29/072 , B01J29/076 , B01J29/166 , B01J2229/42
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
摘要翻译：通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属筛子的结构以及提高裂化催化剂的裂解活性的稀土成分。分子筛通常是诸如USY的八面沸石。初级硫还原组分通常是元素周期3的金属，优选为钒。稀土组分优选包括提高催化剂的硫还原活性的铈。硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

4. 发明授权

US06846403B2 Gasoline sulfur reduction in fluid catalytic cracking 有权
标题翻译：汽油硫化液流化催化裂化
公开(公告)号：US06846403B2
公开(公告)日：2005-01-25
申请号：US09221539
申请日：1998-12-28
申请人： Wu-Cheng Cheng , Scott Kevin Purnell , Terry G. Roberie , Hye Kyung Cho Timken , Xinjin Zhao
发明人： Wu-Cheng Cheng , Scott Kevin Purnell , Terry G. Roberie , Hye Kyung Cho Timken , Xinjin Zhao
IPC分类号： B01J29/072 , B01J29/076 , B01J29/16 , C10G11/05 , C10G11/00
CPC分类号： C10G11/05 , B01J29/072 , B01J29/076 , B01J29/166 , B01J2229/42
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
摘要翻译：通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属筛子的结构以及提高裂化催化剂的裂解活性的稀土成分。分子筛通常是诸如USY的八面沸石。初级硫还原组分通常是周期表第4周期的金属，优选为钒。稀土组分优选包括提高催化剂的硫还原活性的铈。硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

5. 发明授权

US06797155B1 Catalytic cracking process using a modified mesoporous aluminophosphate material 失效
标题翻译：使用改性介孔磷酸铝材料的催化裂化工艺
公开(公告)号：US06797155B1
公开(公告)日：2004-09-28
申请号：US09468450
申请日：1999-12-21
申请人： Arthur Warren Chester , Frederick Earl Daugherty , Anthony Shiu lun Fung , Charles Theodore Kresge , Hye Kyung Cho Timken , James Clarke Vartuli , Ranjit Kumar , Terry G. Roberie , Michael S. Ziebarth
发明人： Arthur Warren Chester , Frederick Earl Daugherty , Anthony Shiu lun Fung , Charles Theodore Kresge , Hye Kyung Cho Timken , James Clarke Vartuli , Ranjit Kumar , Terry G. Roberie , Michael S. Ziebarth
IPC分类号： C10G1102
CPC分类号： C10G11/05
摘要： A process for catalytic cracking of a hydrocarbon feedstock comprises contacting the feedstock with a catalyst composition comprising a primary cracking component, such as zeolite Y, and a mesoporous aluminophosphate material which includes a solid aluminophosphate composition modified with at least one element selected from zirconium, cerium, lanthanum, manganese, cobalt, zinc, and vanadium. The mesoporous aluminophosphate material has a specific surface area of at least 100 m2/g, an average pore size less than or equal to 100 Å, and a pore size distribution such that at least 50% of the pores have a pore diameter less than 100 Å.
摘要翻译：用于烃原料的催化裂化的方法包括使原料与包含初级裂化组分如沸石Y的催化剂组合物和介孔磷酸铝材料接触，所述介孔磷酸铝材料包括用至少一种选自锆，铈的元素改性的固体磷酸铝组合物，镧，锰，钴，锌和钒。介孔磷酸铝材料的比表面积为至少100m 2 / g，平均孔径小于或等于100，孔径分布使得至少50％的孔具有孔径小于100埃。

6. 发明授权

US5626828A Zeolite GZS-11 and its dynamic preparation process 失效
标题翻译：沸石GZS-11及其动态制备工艺
公开(公告)号：US5626828A
公开(公告)日：1997-05-06
申请号：US324949
申请日：1994-10-18
申请人： Jianxin Wu , Robert R. Gatte , Terry G. Roberie
发明人： Jianxin Wu , Robert R. Gatte , Terry G. Roberie
IPC分类号： B01J29/04 , B01J29/70 , C01B39/48
CPC分类号： B01J29/04 , B01J29/70 , B01J29/7007 , C01B39/48 , B01J2229/26 , B01J2229/36 , B01J2229/42 , Y10S423/27
摘要： A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :w H.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of +3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of +4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the as-synthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.
摘要翻译：制备具有由下式表示的摩尔组成的合成沸石GZS-11：[x M2 / nO +（1.0 +/- 0.2-x）R 2 / nO]：Y 2 O 3：y XO 2 :WH 2 O其中M是无机阳离子n，R是价数n的有机阳离子，“x”的值小于1.0，Y是+3价元素中的一种或多种，如铝，硼，镓，铁，铬，钒，钼或锰，X是+4价元素中的一种或多种，例如硅，锗或钛，“y”的值在6至25之间，“w”的值取决于4 沸石的水合程度，并且具有基本上如表1所示的合成沸石的X射线衍射图。用于制备SiO 2 / Al 2 O 3的低比例的SiO 2 / Al 2 O 3的方法是通过调节合成通过添加一种或多种含有沸石组分的反应性源的溶液在老化阶段期间的混合物组成。

7. 发明授权

US06916757B2 High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith 有权
标题翻译：高沸石含量和耐磨耗催化剂，其制备方法和催化方法
公开(公告)号：US06916757B2
公开(公告)日：2005-07-12
申请号：US10151560
申请日：2002-05-20
申请人： Michael S. Ziebarth , Terry G. Roberie , Philip S. Deitz
发明人： Michael S. Ziebarth , Terry G. Roberie , Philip S. Deitz
IPC分类号： B01J27/14 , B01J29/40 , B01J37/00 , B01J29/06
CPC分类号： B01J29/40 , B01J27/14 , B01J37/0045 , B01J2229/26 , B01J2229/42
摘要： A catalyst composition suitable for reacting hydrocarbons, e.g., conversion processes such as fluidized catalytic cracking (FCC) of hydrocarbons, comprises attrition resistant particulate having a high level (30-85%) of stabilized zeolites having a constraint index of 1 to 12. The stabilized zeolite is bound by a phosphorous compound, alumina and optional binders wherein the alumina added to make the catalyst is about 10% by weight or less and the molar ratio of phosphorous (P2O5) to total alumina is sufficient to obtain an attrition index of about 20 or less. The composition can be used as a catalyst per se or as additive catalyst to a conventional catalyst and is especially suitable for enhancing yields of light olefins, and particularly ethylene, produced during conversion processes.
摘要翻译：适用于使烃类反应的催化剂组合物，例如转化过程如烃类的流化催化裂化（FCC），包括具有约1到12的约定指数的稳定沸石的高水平（30-85％）的耐磨颗粒。稳定的沸石由磷化合物，氧化铝和任选的粘合剂结合，其中加入的氧化铝制成催化剂的量为约10重量％或更少，磷的摩尔比（P 总氧化铝足以获得约20或更小的磨耗指数。该组合物本身可用作催化剂或作为常规催化剂的添加剂催化剂，特别适用于提高转化过程中产生的轻质烯烃，特别是乙烯的产率。

8. 发明授权

US5582713A Catalytic cracking utilizing a catalyst comprising zeolite GZS-11 失效
标题翻译：使用包含沸石GZS-11的催化剂进行催化裂化
公开(公告)号：US5582713A
公开(公告)日：1996-12-10
申请号：US470156
申请日：1995-06-06
申请人： Jianxin Wu , Robert R. Gatte , Terry G. Roberie
发明人： Jianxin Wu , Robert R. Gatte , Terry G. Roberie
IPC分类号： B01J29/04 , B01J29/70 , C01B39/48 , C10G11/02
CPC分类号： B01J29/04 , B01J29/70 , B01J29/7007 , C01B39/48 , B01J2229/26 , B01J2229/36 , B01J2229/42 , Y10S423/27
摘要： A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :wH.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of+3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of+4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the assynthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.
摘要翻译：制备具有由下式表示的摩尔组成的合成沸石GZS-11：[x M2 / nO +（1.0 +/- 0.2-x）R 2 / nO]：Y 2 O 3：y XO 2 :WH 2 O其中M是无机价态n的阳离子，R是价数n的有机阳离子，“x”的值小于1.0，Y是+ 3价元素中的一种或多种，例如铝，硼，镓，铁，铬，钒，钼或锰，X是+ 4价元素中的一种或多种，例如硅，锗或钛，“y”的值在6至25之间，“w”的值取决于4 沸石的水合程度，并且具有基本上如表1所示的合成沸石的X射线衍射图。制备SiO 2 / Al 2 O 3的低比例的XO2 / Y2O3的方法是通过调节合成混合物组成在通过添加一种或多种含有沸石组分的反应性源的溶液的老化阶段。

9. 发明申请

US20110224068A1 LOW SMALL MESOPOROUS PEAK CRACKING CATALYST AND METHOD OF USING 审中-公开
标题翻译：低小型多孔式破碎催化剂及其使用方法
公开(公告)号：US20110224068A1
公开(公告)日：2011-09-15
申请号：US13029441
申请日：2011-02-17
申请人： Edward T. Habib, JR. , Ruizhong Hu , Terry G. Roberie , Jianxin Jason Wu , William A. Wachter , Colin L. Beswick
发明人： Edward T. Habib, JR. , Ruizhong Hu , Terry G. Roberie , Jianxin Jason Wu , William A. Wachter , Colin L. Beswick
IPC分类号： B01J29/08
CPC分类号： C10G11/18 , B01J21/16 , B01J29/08 , B01J29/084 , B01J35/1023 , B01J35/1042 , B01J37/28 , B01J2229/36 , C10G11/05 , C10G2400/02
摘要： This invention relates to the composition, method of making and use of a fluidized catalytic cracking (“FCC”) catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. FCC catalysts made from this new zeolite exhibit improved rates of heavy oil cracking heavy oil bottoms conversions and gasoline conversions. The fluidized catalytic cracking catalysts herein are particularly useful in fluidized catalytic cracking (“FCC”) processes for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms.
摘要翻译：本发明涉及由新型Y沸石组成的流化催化裂化（“FCC”）催化剂的组合物，制备和使用方法，所述Y沸石在40埃（埃）范围内表现出极低的小介孔峰，氮吸附测量。由这种新沸石制成的FCC催化剂显示出重油裂解重油底部转化率和汽油转化率的改善。本文中的流化催化裂化催化剂特别可用于流化催化裂化（“FCC”）方法，用于转化重烃原料如瓦斯油和真空塔塔底。

10. 发明申请

US20110220549A1 Low Small Mesoporous Peak Cracking Catalyst and Method of Using 有权
标题翻译：低中孔裂解催化剂及其使用方法
公开(公告)号：US20110220549A1
公开(公告)日：2011-09-15
申请号：US13029367
申请日：2011-02-17
申请人： Jianxin Jason Wu , William A. Wachter , Colin L. Beswick , Edward Thomas Habib, JR. , Terry G. Roberie , Ruizhong Hu
发明人： Jianxin Jason Wu , William A. Wachter , Colin L. Beswick , Edward Thomas Habib, JR. , Terry G. Roberie , Ruizhong Hu
IPC分类号： C10G11/02
CPC分类号： C10G11/18 , B01J21/16 , B01J29/08 , B01J29/084 , B01J35/1023 , B01J35/1042 , B01J37/28 , B01J2229/36 , C10G11/05 , C10G2400/02
摘要： This invention relates to the composition, method of making and use of a fluidized catalytic cracking (“FCC”) catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 Å (angstrom) range as determined by nitrogen adsorption measurements. FCC catalysts made from this new zeolite exhibit improved rates of heavy oil cracking heavy oil bottoms conversions and gasoline conversions. The fluidized catalytic cracking catalysts herein are particularly useful in fluidized catalytic cracking (“FCC”) processes for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms.
摘要翻译：本发明涉及由新型Y沸石组成的流化催化裂化（“FCC”）催化剂的组合物，制备和使用方法，所述Y沸石在40埃（埃）范围内表现出极低的小介孔峰，氮吸附测量。由这种新沸石制成的FCC催化剂显示出重油裂解重油底部转化率和汽油转化率的改善。本文中的流化催化裂化催化剂特别可用于流化催化裂化（“FCC”）方法，用于转化重烃原料如瓦斯油和真空塔塔底。

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