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1. 发明授权

US07985877B2 Carboxylic acid compound, use thereof, and process for producing the same 有权
标题翻译：羧酸化合物，其用途及其制备方法
公开(公告)号：US07985877B2
公开(公告)日：2011-07-26
申请号：US12301543
申请日：2007-05-31
申请人： Tatsuya Ohtsuka , Yoshihiro Yamamoto , Yoshichika Kuroki , Atsushi Suzuki , Akinari Sugiyama
发明人： Tatsuya Ohtsuka , Yoshihiro Yamamoto , Yoshichika Kuroki , Atsushi Suzuki , Akinari Sugiyama
IPC分类号： C07C59/135 , C07C41/18 , C07C41/22 , C07C43/12 , C07C51/09 , C07C51/367
CPC分类号： C07C41/18 , C07C41/22 , C07C51/09 , C07C51/367 , C07C67/31 , C07C43/12 , C07C69/708
摘要： The present invention provides a process for producing 1,1,1,3,3,3-hexafluoro-2-methoxypropane, wherein a novel compound, 2-methoxy-2-trifluoromethyl-3,3,3-trifluoropropionic acid or a salt thereof is decarboxylated, or wherein an olefin compound represented by chemical formula (4): CF2═C(CF3)(OCH3) is reacted with a fluorinating agent; and a process for producing 2-methoxy-2-trifluoromethyl-3,3,3-trifluoropropionic acid or a salt thereof by reacting a hydroxycarboxylic ester with a methylating agent and then hydrolyzing the reaction product, or hydrolyzing the hydroxycarboxylic ester and then reacting the resulting product with a methylating agent.In accordance with the invention, 1,1,1,3,3,3-hexafluoro-2-methoxypropane, which is useful as a raw material for, for example, the anesthetic Sevoflurane, can be produced efficiently and at low cost.
摘要翻译：本发明提供一种生产1,1,1,3,3,3-六氟-2-甲氧基丙烷的方法，其中新化合物2-甲氧基-2-三氟甲基-3,3,3-三氟丙酸或其盐或其中由化学式（4）表示的烯烃化合物：CF 2 = C（CF 3）（OCH 3）与氟化剂反应; 以及通过使羟基羧酸酯与甲基化剂反应然后水解反应产物或水解羟基羧酸酯，然后使所述羟基羧酸酯水解，从而使2-甲氧基-2-三氟甲基-3,3,3-三氟丙酸或其盐得到的产物与甲基化剂。根据本发明，作为例如麻醉剂七氟醚的原料可以使用的1,1,1,3,3,3-六氟-2-甲氧基丙烷可以有效且低成本地制造。

2. 发明申请

US20090156861A1 NOVEL CARBOXYLIC ACID COMPOUND, USE THEREOF, AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：新型羧酸化合物，其用途及其生产方法
公开(公告)号：US20090156861A1
公开(公告)日：2009-06-18
申请号：US12301543
申请日：2007-05-31
申请人： Tatsuya Ohtsuka , Yoshihiro Yamamoto , Yoshichika Kuroki , Atsushi Suzuki , Akinari Sugiyama
发明人： Tatsuya Ohtsuka , Yoshihiro Yamamoto , Yoshichika Kuroki , Atsushi Suzuki , Akinari Sugiyama
IPC分类号： C07C59/135 , C07C43/12
CPC分类号： C07C41/18 , C07C41/22 , C07C51/09 , C07C51/367 , C07C67/31 , C07C43/12 , C07C69/708
摘要： The present invention provides a process for producing 1,1,1,3,3,3-hexafluoro-2-methoxypropane, wherein a novel compound, 2-methoxy-2-trifluoromethyl-3,3,3-trifluoropropionic acid or a salt thereof is decarboxylated, or wherein an olefin compound represented by chemical formula (4): CF2═C(CF3)(OCH3) is reacted with a fluorinating agent; and a process for producing 2-methoxy-2-trifluoromethyl-3,3,3-trifluoropropionic acid or a salt thereof by reacting a hydroxycarboxylic ester with a methylating agent and then hydrolyzing the reaction product, or hydrolyzing the hydroxycarboxylic ester and then reacting the resulting product with a methylating agent.In accordance with the invention, 1,1,1,3,3,3-hexafluoro-2-methoxypropane, which is useful as a raw material for, for example, the anesthetic Sevoflurane, can be produced efficiently and at low cost.
摘要翻译：本发明提供一种生产1,1,1,3,3,3-六氟-2-甲氧基丙烷的方法，其中新化合物2-甲氧基-2-三氟甲基-3,3,3-三氟丙酸或其盐或其中由化学式（4）表示的烯烃化合物：CF 2 -C（CF 3）（OCH 3）与氟化剂反应; 以及通过使羟基羧酸酯与甲基化剂反应然后水解反应产物或水解羟基羧酸酯，然后使所述羟基羧酸酯水解，从而使2-甲氧基-2-三氟甲基-3,3,3-三氟丙酸或其盐得到的产物与甲基化剂。根据本发明，作为例如麻醉剂七氟醚的原料可以使用的1,1,1,3,3,3-六氟-2-甲氧基丙烷可以有效且低成本地制造。

3. 发明授权

US07005545B2 Process for producing fluorinated fluorosulfonylalkyl vinyl ether 有权
标题翻译：制备氟化氟磺酰基烷基乙烯基醚的方法
公开(公告)号：US07005545B2
公开(公告)日：2006-02-28
申请号：US10515338
申请日：2003-05-23
申请人： Akinari Sugiyama , Tatsuya Ohtsuka , Kazuyoshi Ichihara , Toshiya Mantani
发明人： Akinari Sugiyama , Tatsuya Ohtsuka , Kazuyoshi Ichihara , Toshiya Mantani
IPC分类号： C07C309/00
CPC分类号： C07C303/22 , C07C309/82
摘要： The present invention provides a process for producing a fluorinated fluorosulfonylalkyl vinyl ether represented by general formula (2): CF2═CFO(CF2CF(CF3)O)nCF2CF2SO2F (2) wherein n is an integer from 0 to 10, comprising fluorinating a perfluorovinylether sulfonate with SF4 and HF, the perfluorovinylether sulfonate being represented by general formula (1): CF2═CFO(CF2CF(CF3)O)nCF2CF2SO3M (1) wherein M is Ma or Mb1/2, provided that Ma is an alkali metal and Mb is an alkaline earth metal; and n is as defined above. According to the process of the invention, the fluorinated fluorosulfonylalkyl vinyl ether can be produced in high yield in an industrially advantageous manner.
摘要翻译：本发明提供一种由通式表示的氟化氟磺酰基烷基乙烯基醚的制备方法

4. 发明申请

US20050177001A1 Process for producing fluorinated fluorosulfonylalkyl vinyl ether 有权
标题翻译：制备氟化氟磺酰基烷基乙烯基醚的方法
公开(公告)号：US20050177001A1
公开(公告)日：2005-08-11
申请号：US10515338
申请日：2003-05-23
申请人： Akinari Sugiyama , Tatsuya Ohtsuka , Kazuyoshi Ichihara , Toshiya Mantani
发明人： Akinari Sugiyama , Tatsuya Ohtsuka , Kazuyoshi Ichihara , Toshiya Mantani
IPC分类号： C07C303/22 , C07C309/82 , C07C39/82
CPC分类号： C07C303/22 , C07C309/82
摘要： The present invention provides a process for producing a fluorinated fluorosulfonylalkyl vinyl ether represented by general formula (2): CF2=CFO(CF2CF(CF3)O)nCF2CF2SO2F (2) wherein n is an integer from 0 to 10, comprising fluorinating a perfluorovinylether sulfonate with SF4 and HF, the perfluorovinylether sulfonate being represented by general formula (1): CF2=CFO(CF2CF(CF3)O)nCF2CF2SO3M (1) wherein M is Ma or Mb1/2, provided that Ma is an alkali metal and Mb is an alkaline earth metal; and n is as defined above. According to the process of the invention, the fluorinated fluorosulfonylalkyl vinyl ether can be produced in high yield in an industrially advantageous manner.
摘要翻译：本发明提供一种制备由通式（2）表示的氟化氟磺酰基烷基乙烯基醚的方法：<？in-line-formula description =“In-line formula”end =“lead”？> CF 2 SUB> = CFO（CF 2 CF（CF 3 O）O）2 CF 2 CF 2 其中n为0至10的整数，包括：（1）（式中，n为0〜10的整数，氟化全氟乙烯基醚磺酸盐与SF 4和HF氟化，全氟乙烯基醚磺酸盐由通式（1）表示：<？in-line-formula description =“In-line Formulas”end =“lead”？ CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 3 （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是 Ma或Mb <1/2>，条件是Ma是碱金属，Mb是碱土金属; 和n如上所定义。根据本发明的方法，氟化氟磺酰基烷基乙烯基醚可以以工业上有利的方式以高产率制备。

5. 发明授权

US08420872B2 Process for preparing fluorine-containing propene by gas-phase fluorination 有权
标题翻译：通过气相氟化制备含氟丙烯的方法
公开(公告)号：US08420872B2
公开(公告)日：2013-04-16
申请号：US13054831
申请日：2009-06-25
申请人： Masatoshi Nose , Akinari Sugiyama , Atsushi Suzuki
发明人： Masatoshi Nose , Akinari Sugiyama , Atsushi Suzuki
IPC分类号： C07C17/00
CPC分类号： C07C17/20 , C07C17/206 , C07C17/21 , C07C17/354 , C07C17/358 , Y02P20/582 , C07C19/08 , C07C21/18 , C07C19/10
摘要： The present invention provides a process for preparing a fluorine-containing propene represented by the chemical formula CF3CF═CX1X2, wherein X1 is a hydrogen atom or chlorine atom, and X2 is a fluorine atom, chlorine atom, or hydrogen atom, by reacting a halogenated propene represented by the chemical formula CCIYZCF═CX1X2, wherein X1 and X2 are the same as above, and Y and Z may be the same or different and individually indicate a fluorine atom or chlorine atom, with anhydrous hydrogen fluoride in a gas phase in the presence of a chromium oxide or a fluorinated chromium oxide as a fluorination catalyst. The process of the present invention provides a fluorine-containing propene represented by the chemical formula CF3CF═CClX, wherein X is Cl, H or F, under relatively mild conditions at a high yield.
摘要翻译：本发明提供由化学式CF 3CF≡CX1 X 2表示的含氟丙烯的制备方法，其中X 1为氢原子或氯原子，X 2为氟原子，氯原子或氢原子，通过使卤代由化学式CCIYZCF≡CX1X2表示的丙烯，其中X1和X2与上述相同，Y和Z可以相同或不同，并且分别表示氟原子或氯原子，在气相中用无水氟化氢作为氟化催化剂存在铬氧化物或氟化铬氧化物。本发明的方法在相对温和的条件下以高产率提供由化学式CF 3CF≡CClX表示的含氟丙烯，其中X为Cl，H或F。

6. 发明申请

US20110124929A1 PROCESS FOR PREPARING FLUORINE-CONTAINING PROPENE BY GAS-PHASE FLUORINATION 有权
标题翻译：通过气相荧光法制备含氟的丙烯的方法
公开(公告)号：US20110124929A1
公开(公告)日：2011-05-26
申请号：US13054831
申请日：2009-06-25
申请人： Masatoshi Nose , Akinari Sugiyama , Atsushi Suzuki
发明人： Masatoshi Nose , Akinari Sugiyama , Atsushi Suzuki
IPC分类号： C07C17/04
CPC分类号： C07C17/20 , C07C17/206 , C07C17/21 , C07C17/354 , C07C17/358 , Y02P20/582 , C07C19/08 , C07C21/18 , C07C19/10
摘要： The present invention provides a process for preparing a fluorine-containing propene represented by the chemical formula CF3CF═CX1X2, wherein X1 is a hydrogen atom or chlorine atom, and X2 is a fluorine atom, chlorine atom, or hydrogen atom, by reacting a halogenated propene represented by the chemical formula CCIYZCF═CX1X2, wherein X1 and X2 are the same as above, and Y and Z may be the same or different and individually indicate a fluorine atom or chlorine atom, with anhydrous hydrogen fluoride in a gas phase in the presence of a chromium oxide or a fluorinated chromium oxide as a fluorination catalyst. The process of the present invention provides a fluorine-containing propene represented by the chemical formula CF3CF═CClX, wherein X is Cl, H or F, under relatively mild conditions at a high yield.
摘要翻译：本发明提供由化学式CF 3CF≡CX1 X 2表示的含氟丙烯的制备方法，其中X 1为氢原子或氯原子，X 2为氟原子，氯原子或氢原子，通过使卤代由化学式CCIYZCF≡CX1X2表示的丙烯，其中X1和X2与上述相同，Y和Z可以相同或不同，并且分别表示氟原子或氯原子，在气相中用无水氟化氢作为氟化催化剂存在铬氧化物或氟化铬氧化物。本发明的方法在相对温和的条件下以高产率提供由化学式CF 3CF≡CClX表示的含氟丙烯，其中X为Cl，H或F。

7. 发明申请

US20100168480A1 METHOD FOR PRODUCING FLUOROALKYL ALCOHOL 审中-公开
标题翻译：生产氟代醇的方法
公开(公告)号：US20100168480A1
公开(公告)日：2010-07-01
申请号：US12451659
申请日：2008-05-23
申请人： Akinari Sugiyama , Atsushi Suzuki , Masahiro Tomita
发明人： Akinari Sugiyama , Atsushi Suzuki , Masahiro Tomita
IPC分类号： C07C31/34
CPC分类号： C07C29/00 , C07C31/38
摘要： The present invention provides a method for producing a fluoroalkyl alcohol represented by general formula (6) wherein Rf1 and Rf2 are the same or different, each represents a CF3(CF2)n group (wherein n is an integer of 0 to 10) or a CH3(CH2)m group (wherein m is an integer of 0 to 10), and at least one of Rf1 and Rf2 represents a CF3(CF2)n group, the method comprising: decarboxylating a compound represented by general formula (1) wherein Rf1 and Rf2 are the same as above; and R1 represents an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted aralkyl group, an alkali metal, or M1/2 (wherein M represents an alkaline earth metal), in the presence of at least one member selected from the group consisting of pyridines, amines, quaternary ammonium salts, and quaternary phosphonium salts.According to the present invention, fluoroalkyl alcohol such as hexafluoroisopropyl alcohol can be easily produced with high selectivity, using an inexpensive starting material.
摘要翻译：本发明提供一种通式（6）表示的氟烷基醇的制造方法，其中Rf1和Rf2相同或不同，分别表示CF3（CF2）n基（其中n为0〜10的整数）或 CH 3（CH 2）m基团（其中m为0〜10的整数），Rf 1和Rf 2中的至少一个为CF 3（CF 2）n基团，该方法包括：将通式（1）表示的化合物脱羧， Rf1和Rf2与上述相同; 并且R 1表示任选取代的烷基，任选取代的芳基，任选取代的芳烷基，碱金属或M 1/2（其中M表示碱土金属），在选自由吡啶，胺，季铵盐和季鏻盐组成的组。根据本发明，使用廉价的原料，可以以高选择性容易地制备氟代烷基醇如六氟异丙醇。

8. 发明申请

US20070185355A1 Method for producing fluorine-containing halide 有权
标题翻译：含氟卤化物的制造方法
公开(公告)号：US20070185355A1
公开(公告)日：2007-08-09
申请号：US10593322
申请日：2005-03-11
申请人： Akinari Sugiyama , Kazuyoshi Ichihara , Noriyuki Shinoki , Toshiya Mantani , Masahiro Kondou
发明人： Akinari Sugiyama , Kazuyoshi Ichihara , Noriyuki Shinoki , Toshiya Mantani , Masahiro Kondou
IPC分类号： C07C19/08
CPC分类号： C07C41/22 , C07C17/093 , C07C19/14 , C07C43/17
摘要： The present invention provides a method for producing a fluorine-containing halide, comprising reacting a fluorine-containing sulfonyl halide or fluorine-containing disulfonyl chloride with a metal halide or metal component in the present or absence of a solvent. In accordance with the present invention, a fluorine-containing bromide, fluorine-containing iodide or fluorine-containing chloride can be readily produced in high yield at low cost, using an industrially advantageous process.
摘要翻译：本发明提供一种含氟卤化物的制造方法，其特征在于，在含或不存在溶剂的情况下，使含氟磺酰卤或含氟二磺酰氯与金属卤化物或金属成分反应。根据本发明，使用工业上有利的方法，可以以低成本容易地以高产率制备含氟溴化物，含氟碘化物或含氟氯化物。

9. 发明申请

US20100197852A1 NOVEL COMPOUND, METHOD FOR PRODUCING THE SAME AND METHOD FOR PRODUCING FLUOROPOLYMER 有权
标题翻译：新颖的化合物，其生产方法和生产氟聚合物的方法
公开(公告)号：US20100197852A1
公开(公告)日：2010-08-05
申请号：US12668168
申请日：2008-07-24
申请人： Nobuhiko Tsuda , Akinari Sugiyama
发明人： Nobuhiko Tsuda , Akinari Sugiyama
IPC分类号： C08L27/12 , C07C53/21 , C07C309/01 , C07C309/02 , C08F214/18
CPC分类号： C07C59/135 , B01F17/0035 , C07C51/42 , C08F2/26 , C08F14/18 , C08F214/18 , C08J3/12 , C08J3/16 , C08J2323/18 , C08F2/00
摘要： The invention provides a compound which is useful in production of a fluoropolymer and easy to be removed from the produced fluoropolymer, a method of producing the compound, and a method of producing a fluoropolymer using the compound. The invention provides a compound which is represented by Rf1—CH2O—CF2—CHF—Rf2—X, wherein Rf1 represents a fluoroalkyl group containing 1 to 5 carbon atoms, Rf2 represents a fluoroalkylene group containing 1 to 3 carbon atoms, X represents —COOM or —SO3M, and M represents one of H, K, Na, and NH4.
摘要翻译：本发明提供一种可用于生产含氟聚合物并易于从生产的含氟聚合物中除去的化合物，该化合物的制备方法和使用该化合物的含氟聚合物的制备方法。本发明提供由Rf1-CH2O-CF2-CHF-Rf2-X表示的化合物，其中Rf1表示含有1至5个碳原子的氟烷基，Rf2表示含有1至3个碳原子的氟代亚烷基，X表示-COOM 或-SO 3 M，M表示H，K，Na和NH 4中的一种。

10. 发明授权

US07692048B2 Method for producing fluorine-containing halide 有权
标题翻译：含氟卤化物的制造方法
公开(公告)号：US07692048B2
公开(公告)日：2010-04-06
申请号：US10593322
申请日：2005-03-11
申请人： Akinari Sugiyama , Kazuyoshi Ichihara , Noriyuki Shinoki , Toshiya Mantani , Masahiro Kondou
发明人： Akinari Sugiyama , Kazuyoshi Ichihara , Noriyuki Shinoki , Toshiya Mantani , Masahiro Kondou
IPC分类号： C07C19/08
CPC分类号： C07C41/22 , C07C17/093 , C07C19/14 , C07C43/17
摘要： The present invention provides a method for producing a fluorine-containing halide, comprising reacting a fluorine-containing sulfonyl halide or fluorine-containing disulfonyl chloride with a metal halide or metal component in the present or absence of a solvent. In accordance with the present invention, a fluorine-containing bromide, fluorine-containing iodide or fluorine-containing chloride can be readily produced in high yield at low cost, using an industrially advantageous process.
摘要翻译：本发明提供一种含氟卤化物的制造方法，其特征在于，在含或不存在溶剂的情况下，使含氟磺酰卤或含氟二磺酰氯与金属卤化物或金属成分反应。根据本发明，使用工业上有利的方法，可以以低成本容易地以高产率制备含氟溴化物，含氟碘化物或含氟氯化物。

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