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    • 5. 发明授权
    • Method for producing barium titanium oxide single-crystal piece using containerless processing
    • 使用无容器加工制造钡钛氧化物单晶片的方法
    • US07544245B2
    • 2009-06-09
    • US11044325
    • 2005-01-28
    • Kentei YonoPaul-Francois ParadisTakehiko IshikawaShinichi Yoda
    • Kentei YonoPaul-Francois ParadisTakehiko IshikawaShinichi Yoda
    • C30B30/00C30B13/00
    • C04B35/4682C04B35/465C04B35/47C04B35/472C04B2235/3208C04B2235/604C04B2235/79C04B2235/94C04B2235/95C30B11/00C30B11/002C30B29/16Y10S117/901
    • Disclosed is a method for producing a barium titanium oxide single crystal piece with a given structure using a containerless solidification process, which comprises the steps of preparing a material made of a barium titanium oxide, controlling the material to be in a levitated state within a levitation furnace, melting the levitated material using a laser, and solidifying the molten material while maintaining the levitated state. In a specific embodiment, a spherical sample having a composition of BaTiO3 and a weight of about 20 mg is subjected to a rapid solidification and melting process (temperature gradient: about 700 K/sec) 3 times while levitating the sample in 4.5 atm of air atmosphere using an electrostatic levitation furnace. Then, the re-molten sample is maintained at a temperature just below the melting point of the sample for a given time, and then rapidly cooled at a cooling rate of 300 K/sec to obtain a transparent blue barium titanium oxide single crystal. The single crystal exhibits innovative dielectric characteristics having a large relative permittivity (100,000 or more at room temperature) and a low dielectric loss. In addition, the single crystal has excellent temperature stability allowing the relative permittivity to be gently reduced in the range of room temperature to 70 K.
    • 公开了一种使用无容器凝固方法制造具有给定结构的钡钛氧化物单晶片的方法,其包括以下步骤:制备由氧化钛钡制成的材料,将材料控制在悬浮状态下处于悬浮状态 使用激光对悬浮物进行熔融,同时固化熔融材料,同时保持悬浮状态。 在具体实施方案中,将具有BaTiO 3组成和重量约20mg的球形样品在快速凝固和熔化过程(温度梯度:约700K /秒)下进行3次,同时使样品在4.5atm空气中悬浮 使用静电悬浮炉。 然后,将再熔融样品保持在正好低于样品熔点的温度一定时间,然后以300K /秒的冷却速度快速冷却,得到透明的蓝色钡钛氧化物单晶。 单晶具有相对介电常数(室温下为100,000或更高)和低介电损耗的创新介电特性。 此外,单晶具有优异的温度稳定性,允许相对介电常数在室温至70K的范围内轻轻降低。
    • 9. 发明申请
    • Method for producing barium titanium oxide single-crystal piece using containerless processing
    • 使用无容器加工制造钡钛氧化物单晶片的方法
    • US20050199180A1
    • 2005-09-15
    • US11044325
    • 2005-01-28
    • Kentei YonoPaul-Francois ParadisTakehiko IshikawaShinichi Yoda
    • Kentei YonoPaul-Francois ParadisTakehiko IshikawaShinichi Yoda
    • C30B29/32C04B35/46C04B35/48C04B35/49C30B1/00C30B30/04C30B30/08
    • C04B35/4682C04B35/465C04B35/47C04B35/472C04B2235/3208C04B2235/604C04B2235/79C04B2235/94C04B2235/95C30B11/00C30B11/002C30B29/16Y10S117/901
    • Disclosed is a method for producing a barium titanium oxide single crystal piece with a given structure using a containerless solidification process, which comprises the steps of preparing a material made of a barium titanium oxide, controlling the material to be in a levitated state within a levitation furnace, melting the levitated material using a laser, and solidifying the molten material while maintaining the levitated state. In a specific embodiment, a spherical sample having a composition of BaTiO3 and a weight of about 20 mg is subjected to a rapid solidification and melting process (temperature gradient: about 700 K/sec) 3 times while levitating the sample in 4.5 atm of air atmosphere using an electrostatic levitation furnace. Then, the re-molten sample is maintained at a temperature just below the melting point of the sample for a given time, and then rapidly cooled at a cooling rate of 300 K/sec to obtain a transparent blue barium titanium oxide single crystal. The single crystal exhibits innovative dielectric characteristics having a large relative permittivity (100,000 or more at room temperature) and a low dielectric loss. In addition, the single crystal has excellent temperature stability allowing the relative permittivity to be gently reduced in the range of room temperature to 70 K.
    • 公开了一种使用无容器凝固方法制造具有给定结构的钡钛氧化物单晶片的方法,其包括以下步骤:制备由氧化钛钡制成的材料,将材料控制在悬浮状态下处于悬浮状态 使用激光对悬浮物进行熔融,同时固化熔融材料,同时保持悬浮状态。 在具体实施方案中,将具有组成为BaTiO 3和重量约20mg的球形样品经受快速凝固和熔化过程(温度梯度:约700K /秒)3次,同时 使用静电悬浮炉将样品悬浮在空气气氛的4.5atm中。 然后,将再熔融样品保持在正好低于样品熔点的温度一定时间,然后以300K /秒的冷却速度快速冷却,得到透明的蓝色钡钛氧化物单晶。 单晶具有相对介电常数(室温下为100,000或更高)和低介电损耗的创新介电特性。 此外,单晶具有优异的温度稳定性,允许相对介电常数在室温至70K的范围内轻轻降低。