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1. 发明授权

US4350829A Process for preparing isobutyric acid 失效
标题翻译：制备异丁酸的方法
公开(公告)号：US4350829A
公开(公告)日：1982-09-21
申请号：US52590
申请日：1979-06-27
申请人： Tatsuo Masuko , Shigeo Fukaya , Nobuyuki Murai , Jun Noma
发明人： Tatsuo Masuko , Shigeo Fukaya , Nobuyuki Murai , Jun Noma
IPC分类号： C07C51/235 , C07C51/295 , C07C53/124
CPC分类号： C07C51/235
摘要： There is disclosed a process for the production of isobutyric acid by liquid-phase oxidation of isobutyraldehyde in the presence of an alkali metal-containing compound, the oxidation being effected while maintaining the molar ratio of oxygen to isobutyraldehyde to be fed at 0.5 or above.
摘要翻译：公开了一种在含碱金属化合物的存在下通过异丁醛的液相氧化生产异丁酸的方法，氧化是在保持氧与异丁醛的摩尔比为0.5以上的条件下进行的。

2. 发明授权

US5393866A Method for the production of polytetramethylene ether glycol 失效
标题翻译：生产聚四亚甲基醚二醇的方法
公开(公告)号：US5393866A
公开(公告)日：1995-02-28
申请号：US149779
申请日：1993-11-10
申请人： Nobuyuki Murai , Masayuki Shirato , Hiroshi Takeo , Hidetoshi Tanaka
发明人： Nobuyuki Murai , Masayuki Shirato , Hiroshi Takeo , Hidetoshi Tanaka
IPC分类号： C08G65/20 , C08G65/26 , C08G65/324 , C08G59/68 , C07C43/02 , C08G65/04
CPC分类号： C08G65/20 , C08G65/2678 , C08G65/2684 , C08G65/324
摘要： A method for the production of polytetramethylene ether glycol wherein polymerization of tetrahydrofuran in the presence of fluorosulfonic acid is followed by hydrolysis of the resulting polymer, characterized by(1) using the fluorosulfonic acid at 0.007-0.3 molar equivalents with respect to the tetrahydrofuran;(2) using in combination therewith fuming sulfuric acid which contains free sulfur trioxide at 0.05-1.0 molar equivalent with respect to the fluorosulfonic acid; and(3) adding said fuming sulfuric acid to the tetrahydrofuran prior to adding the fluorosulfonic acid thereto.According to the method, high quality polytetramethylene ether glycol with a low fluorine content may be obtained at a high yield without lowering the polymerization temperature. For example, PTMG may be obtained with 3 or fewer, and preferably 2 or fewer terminal fluorines per 2,000 termini of the resulting PTMG. As a result, when the resulting PTMG is used as a starting material for elastomers, it is possible to easily obtain a high molecular weight polymer with excellent heat resistance.
摘要翻译：一种生产聚四亚甲基醚二醇的方法，其中在氟磺酸存在下聚合四氢呋喃，然后水解所得聚合物，其特征在于（1）使用相对于四氢呋喃0.007-0.3摩尔当量的氟磺酸; （2）与含有相对于氟磺酸的0.05-1.0摩尔当量的游离三氧化硫的发烟硫酸组合使用; 和（3）在向其中加入氟磺酸之前将所述发烟硫酸加入到四氢呋喃中。根据该方法，可以在不降低聚合温度的情况下以高产率获得低含氟量的高品质聚四亚甲基醚二醇。例如，PTMG可以获得3个以下，优选2个以下的末端荧光，每2 000个终点产生的PTMG。结果，当所得到的PTMG用作弹性体的起始材料时，可以容易地获得具有优异耐热性的高分子量聚合物。

3. 发明授权

US06403842B1 Processes for producing poly(alkylene ether) glycol 有权
标题翻译：制备聚（亚烷基醚）二醇的方法
公开(公告)号：US06403842B1
公开(公告)日：2002-06-11
申请号：US09482641
申请日：2000-01-13
申请人： Mitsuharu Kobayashi , Nobuyuki Murai
发明人： Mitsuharu Kobayashi , Nobuyuki Murai
IPC分类号： C07C4313
CPC分类号： C08G18/4854 , C08G65/20 , C08G65/2615 , C08G65/2657 , C08G65/266 , C08G65/2693
摘要： Disclosed are a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and a carboxylic acid anhydride, wherein the carboxylic acid anhydride has a ketene dimer content of 50 ppm or lower, and a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and acetic anhydride, wherein the acetic anhydride is purified acetic anhydride obtained by treating acetic anhydride by contacting with at least one of a metal oxide and a mixed oxide, and optionally, distilling the acetic anhydride simultaneously with or after the contact treatment.
摘要翻译：公开了一种制备聚（亚烷基醚）二醇的方法，其包括在至少一种催化剂和羧酸酐存在下使环醚聚合，其中羧酸酐的乙烯酮二聚体含量为50ppm或更低，以及一种制备聚（亚烷基醚）二醇的方法，其包括在至少一种催化剂和乙酸酐的存在下使环醚聚合，其中所述乙酸酐是通过用乙酸酐与至少一种金属氧化物和混合氧化物，并且任选地，在接触处理之后或之后蒸馏乙酸酐。

4. 发明授权

US5318617A Writing board ink composition 失效
标题翻译：书写板油墨组成
公开(公告)号：US5318617A
公开(公告)日：1994-06-07
申请号：US38474
申请日：1993-03-29
申请人： Toshiyuki Nagasawa , Nobuyuki Murai , Kazuo Goda
发明人： Toshiyuki Nagasawa , Nobuyuki Murai , Kazuo Goda
IPC分类号： C09D11/16 , C09D11/17
CPC分类号： C09D11/17
摘要： A writing board ink composition comprises a medium formed of a lower alcohol solvent which contains an alcohol-soluble polymer, a scraping (erasing) agent, a surfactant and a diketopyrrolopyrrole pigment having a median Stokes diameter (ultrafine particle size) of not more than 0.2 .mu.m and represented by the following formula ##STR1## R.sup.1 and R.sup.2 independently represent an unsubstituted phenyl or naphthyl group of a non-water-solubilizing substituent substituted phenyl or naphthyl group, and R.sup.3 and R.sup.4 independently represent hydrogen or a non-water-solubilizing substituent. The writing board ink composition remains stable for a long time while in pens even when the resin content (alcohol-soluble polymer) is such that unclear writing and scrapability reduction (loss of scrapability or erasability) can be avoided, since the pigment of ultrafine particle size is fast to lower alcohol solvents.
摘要翻译：书写用油墨组合物包含由含有醇溶性聚合物的低级醇溶剂，刮擦（擦除）剂，表面活性剂和二仲吡咯并吡咯颜料形成的介质，所述颜料的中等斯托克斯直径（超微粒径）不大于0.2 并且由下式表示：其中R 1和R 2独立地表示非水溶性取代基的取代的苯基或萘基的未取代的苯基或萘基，R 3和R 4独立地表示氢或非 - 水溶性取代基。即使当树脂含量（醇溶性聚合物）具有不清楚的书写和可刮除性降低（可刮除性或可擦除性的损失））时，书写用墨水组合物长时间保持稳定，而由于超细颗粒的颜料大小很快降低酒精溶剂。

5. 发明授权

US08360383B2 Seat sliding device 有权
标题翻译：座椅滑动装置
公开(公告)号：US08360383B2
公开(公告)日：2013-01-29
申请号：US12994749
申请日：2009-05-11
申请人： Gakuji Kimura , Yuusuke Satou , Kensuke Miyoshi , Nobuyuki Murai
发明人： Gakuji Kimura , Yuusuke Satou , Kensuke Miyoshi , Nobuyuki Murai
IPC分类号： F16M13/00
CPC分类号： B60N2/0818 , B60N2/0705 , B60N2/0843 , B60N2/0881
摘要： A seat sliding device for preventing accidental operation of the operation member. The seat sliding device includes a biasing member 60 which biases a lock member 50 in response to the operation of an operation lever 70 in an unlocking pivoting direction and which is tiltable around a shaft 62 as the tilting center together with the operation lever 70 in response to the operation of the operation lever 70. A balancer 64 of the biasing member 60 has a shape and mass, etc. adapted so as to bring a position of the center of gravity of the tilting body including the operation lever 70 and the biasing member 60 close to the shaft center of the shaft 62.
摘要翻译：一种用于防止操作构件意外操作的座椅滑动装置。座椅滑动装置包括偏置构件60，该偏置构件60响应于操作杆70在解锁转动方向上的操作而偏压锁定构件50，并且作为倾斜中心与作为响应的操作杆70一起作为倾斜中心可倾斜偏置构件60的平衡器64具有形状和质量等，其适于使得包括操作杆70的倾斜体的重心位置和偏置构件靠近轴62的轴心。

6. 发明授权

US06468342B1 Aqueous pigment dispersion and process for producing the same 有权
标题翻译：水性颜料分散体及其制造方法
公开(公告)号：US06468342B1
公开(公告)日：2002-10-22
申请号：US09762597
申请日：2001-02-09
申请人： Sohko Itoh , Tatsuya Yagyu , Nobuyuki Murai , Makiko Matsui
发明人： Sohko Itoh , Tatsuya Yagyu , Nobuyuki Murai , Makiko Matsui
IPC分类号： C09C1700
CPC分类号： B82Y30/00 , C01P2004/62 , C01P2004/64 , C01P2006/19 , C09C1/565 , C09D11/324 , C09D17/005
摘要： It is provided an aqueous pigment dispersion having improved dispersing stability in which carbon black shows appropriate initial dispersing property and long-term dispersing property to water, and carbon black particles are less susceptible to aggregation. Moreover, it is provided a raw material for ink-jet ink having improved printing density when alkali metal cation is substituted by potassium ion. The present invention is summarized as an aqueous pigment dispersion, which contains surface modified carbon black that is obtained by wet-oxidizing carbon black by using hypohalous acid and/or a salt thereof, and alkali metal cation, characterized in that concentration of the alkali metal cation is not more than 2% by weight.
摘要翻译：提供了一种具有改进的分散稳定性的水性颜料分散体，其中炭黑显示适当的初始分散性和对水的长期分散性，并且炭黑颗粒不易凝集。此外，提供了当碱金属阳离子被钾离子取代时具有改善的印刷密度的喷墨油墨的原料。本发明总结为含有通过使用次卤酸和/或其盐湿法氧化炭黑和碱金属阳离子而得到的表面改性炭黑的水性颜料分散体，其特征在于，碱金属阳离子不超过2重量％。

7. 发明申请

US20110121154A1 SEAT SLIDING DEVICE 有权
标题翻译：座椅滑动装置
公开(公告)号：US20110121154A1
公开(公告)日：2011-05-26
申请号：US12994749
申请日：2009-05-11
申请人： Gakuji Kimura , Yuusuke Satou , Kensuke Miyoshi , Nobuyuki Murai
发明人： Gakuji Kimura , Yuusuke Satou , Kensuke Miyoshi , Nobuyuki Murai
IPC分类号： B60N2/08 , B60N2/07
CPC分类号： B60N2/0818 , B60N2/0705 , B60N2/0843 , B60N2/0881
摘要： A seat sliding device for preventing accidental operation of the operation member. The seat sliding device includes a biasing member 60 which biases a lock member 50 in response to the operation of an operation lever 70 in an unlocking pivoting direction and which is tiltable around a shaft 62 as the tilting center together with the operation lever 70 in response to the operation of the operation lever 70. A balancer 64 of the biasing member 60 has a shape and mass, etc. adapted so as to bring a position of the center of gravity of the tilting body including the operation lever 70 and the biasing member 60 close to the shaft center of the shaft 62.
摘要翻译：一种用于防止操作构件意外操作的座椅滑动装置。座椅滑动装置包括偏置构件60，该偏置构件60响应于操作杆70在解锁转动方向上的操作而偏压锁定构件50，并且作为倾斜中心与作为响应的操作杆70一起作为倾斜中心可倾斜偏置构件60的平衡器64具有形状和质量等，其适于使得包括操作杆70的倾斜体的重心位置和偏置构件靠近轴62的轴心。

8. 发明授权

US5777155A Process for producing unsaturated glycol diester 失效
标题翻译：制备不饱和二醇二酯的方法
公开(公告)号：US5777155A
公开(公告)日：1998-07-07
申请号：US819199
申请日：1997-03-17
申请人： Masato Sato , Hironobu Ohno , Nobuyuki Murai , Hiroshi Iwasaka
发明人： Masato Sato , Hironobu Ohno , Nobuyuki Murai , Hiroshi Iwasaka
IPC分类号： B01J27/057 , C07B61/00 , C07C67/055 , C07C69/16 , C07C67/05 , C07C67/04
CPC分类号： C07C67/055
摘要： A process for producing an unsaturated glycol diester disclosed, which process comprises reacting a conjugated diene with a carboxylic acid and molecular oxygen in the presence of a solid catalyst comprising (1) palladium and (2) tellurium as active components supported on a carrier, wherein a said carrier is a solid carrier in which a proportion of the volume of pores having a pore radius in the range of from 5 to 50 nm is 80% or more relative to the total volume of pores having a pore radius in the range of from 1.8 to 10,000 nm.
摘要翻译：公开了一种制备不饱和二醇二酯的方法，该方法包括在固体催化剂存在下使共轭二烯与羧酸和分子氧反应，所述固体催化剂包含（1）钯和（2）碲作为负载在载体上的活性组分，其中所述载体是固体载体，其中孔半径在5至50nm范围内的孔体积的一部分相对于孔半径在以下范围内的孔的总体积为80％或更大 1.8至10,000nm。

9. 发明授权

US5429721A Process for preparing diacetoxybutene 失效
标题翻译：制备二乙酰氧基丁烯的方法
公开(公告)号：US5429721A
公开(公告)日：1995-07-04
申请号：US245663
申请日：1994-05-18
申请人： Hiroaki Kandori , Nobuyuki Murai
发明人： Hiroaki Kandori , Nobuyuki Murai
IPC分类号： B01J23/44 , C07B61/00 , C07C67/055 , C07C67/54 , C07C69/16 , B01D3/10 , C07C69/02
CPC分类号： C07C67/54 , C07C67/055
摘要： A process for preparing diacetoxybutene, including:reacting butadiene, acetic acid and oxygen in the presence of a palladium-based catalyst;feeding continuously the resulting reaction product into a first distillation tower;feeding continuously a withdrawn bottoms withdrawn from the first distillation tower into a second distillation tower;withdrawing bottoms containing high boiling point materials from the bottom of the second distillation tower, so that the content of the high boiling point materials in the bottoms of the second distillation tower is not more than 20 wt %;feeding continuously the withdrawn bottoms into a thin-film evaporator whose internal pressure is kept lower than the bottom pressure of the second distillation tower to carry out evaporation treatment; andrecycling the evaporated materials mainly containing diacetoxybutene into the second distillation tower.
摘要翻译：一种制备二乙酰氧基丁烯的方法，包括：在钯基催化剂存在下使丁二烯，乙酸和氧反应; 将所得反应产物连续进料到第一蒸馏塔中; 将从第一蒸馏塔排出的回收塔底馏分连续进料到第二蒸馏塔中; 从第二蒸馏塔的底部排出含有高沸点物质的塔底物，使得第二蒸馏塔底部的高沸点物质的含量不大于20wt％; 将取出的底部物料连续进入薄膜蒸发器，其内部压力保持低于第二蒸馏塔的底部压力以进行蒸发处理; 并将主要含有二乙酰氧基丁烯的蒸发材料回收到第二蒸馏塔中。

10. 发明授权

US5177254A Method for producing an unsaturated glycol diester 失效
标题翻译：生产不饱和甘油油的方法
公开(公告)号：US5177254A
公开(公告)日：1993-01-05
申请号：US152339
申请日：1988-02-04
申请人： Junzo Haji , Ichiro Yokotake , Takahiro Yamaguchi , Masato Sato , Nobuyuki Murai
发明人： Junzo Haji , Ichiro Yokotake , Takahiro Yamaguchi , Masato Sato , Nobuyuki Murai
IPC分类号： B01J27/02 , B01J27/049 , C07B61/00 , C07C67/04 , C07C67/055 , C07C69/16 , C07C69/593
CPC分类号： C07C67/055
摘要： A method for producing an unsaturated glycol diester by reacting molecular oxygen, a carboxylic acid and a conjugated diene in the presence of a solid catalyst containing palladium and tellurium supported on a carrier, wherein an active carbon with the total pore volume of pores having radii of from 18 to 100,000 .ANG. being at least 0.45 cc/g and with the volume of pores having radii of at least 3,000 .ANG. constituting at least 50% of the total pore volume, is used as the carrier for the solid catalyst.

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