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1. 发明授权

US5629136A Photosensitive lithographic printing plate requiring no fountain solution 失效
标题翻译：不需要润版液的感光平版印刷版
公开(公告)号：US5629136A
公开(公告)日：1997-05-13
申请号：US568372
申请日：1995-12-06
申请人： Tatsuji Higashi , Koji Sonokawa , Tsumoru Hirano
发明人： Tatsuji Higashi , Koji Sonokawa , Tsumoru Hirano
IPC分类号： G03F7/00 , G03F7/075 , G03F7/11
CPC分类号： G03F7/0752
摘要： A presensitized plate for use in making a lithographic printing plate requiring no fountain solution excellent in scratch resistance and press life is disclosed, which comprises support and, formed thereon in order from support, a photosensitive layer and a silicone rubber layer, wherein the silicone rubber layer is a crosslinked and cured product obtained by addition reaction of (a) polysiloxane having alkenyl groups with (b) hydrogen polysiloxane having .tbd.Si--H groups so that the number of .tbd.Si--H groups in (b) is from 11 to 30 based on the number of alkenyl groups in (a), wherein polysiloxane (a) has at least two alkenyl groups directly bonded to silicon atoms per molecule, average repeating number x of --[Si(R.sup.1)(R.sup.2)--O].sub.x -- group of 100 .ltoreq.x.ltoreq.600 (wherein R.sup.1 and R.sup.2 each represents a alkyl group, aryl group, aralkyl group, alkenyl group, polydimethylsiloxane group or halogenated hydrocarbon group, provided that 70% or more of R.sup.1 and R.sup.2 are methyl groups), and alkyl groups or alkenyl groups directly bonded to the terminal silicon atoms, and wherein the hydrogen polysiloxane (b) is formula (I):R.sup.3 --Si(R.sup.4).sub.2 --O--[SiH(R.sup.4)--O].sub.y --[Si(R.sup.4).sub.2 --O].sub.z --Si(R.sup.4).sub.2 --R.sup.3 (I)wherein R.sup.3 represents a hydrogen atom or a methyl group; R.sup.4 represents an alkyl group, an aryl group, or an aralkyl group, provided that 70% or more of R.sup.4 is a methyl group; y is from 4 to 100, and z is from 0 to 100.
摘要翻译：公开了一种用于制造不需要耐刮擦性和冲压寿命优异的润版液的平版印刷版的预敏化板，其包括载体，并且从载体上依次形成感光层和硅橡胶层，其中硅橡胶层是通过（a）具有烯基的聚硅氧烷与（b）具有3个Si-H基团的氢聚硅氧烷的加成反应得到的交联固化物，使得（b）中的3BOND Si-H基团的数量为11〜30 基于（a）中的烯基数，其中聚硅氧烷（a）具有至少两个每分子直接与硅原子键合的烯基， - [Si（R 1）（R 2）-O] x - 基团，其中R 1和R 2各自表示烷基，芳基，芳烷基，烯基，聚二甲基硅氧烷基或卤代烃基，其中R 1和R 2的70％或更多为甲基基团）和烷基或醇（b）为式（I）：R3-Si（R4）2-O- [SiH（R4）-O] y- [Si（R4）2） -O] z-Si（R 4）2 -R 3（I）其中R 3表示氢原子或甲基; R4表示烷基，芳基或芳烷基，条件是R4的70％以上为甲基。 y为4〜100，z为0〜100。

2. 发明授权

US06660453B2 Waterless planographic printing plate precursor and production method thereof 失效
标题翻译：无水平版印刷版前体及其制备方法
公开(公告)号：US06660453B2
公开(公告)日：2003-12-09
申请号：US09747964
申请日：2000-12-27
申请人： Tsumoru Hirano , Koji Sonokawa
发明人： Tsumoru Hirano , Koji Sonokawa
IPC分类号： G03F7004
CPC分类号： B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/02 , B41C2210/12 , B41C2210/16 , B41C2210/24 , B41C2210/266 , Y10S430/145 , Y10S430/146
摘要： A waterless planographic printing plate precursor which has a support member, a light-to-heat conversion layer for converting laser light to heat, and a silicone rubber layer. The light-to-heat conversion layer is contains at least one kind of polyurethane having at least one carboxyl group, and at least one light-to-heat conversion substance.
摘要翻译：一种无水平版印刷版原版，其具有支撑构件，用于将激光转换成热的光 - 热转换层和硅橡胶层。光热转换层包含至少一种具有至少一个羧基的聚氨酯和至少一种光热转换物质。

3. 发明授权

US5334486A Photopolymerizable composition and dry PS plate 失效
标题翻译：光聚合组合物和干PS板
公开(公告)号：US5334486A
公开(公告)日：1994-08-02
申请号：US811671
申请日：1991-12-23
申请人： Yukio Abe , Tatsuji Higashi , Tsumoru Hirano , Syunichi Kondo
发明人： Yukio Abe , Tatsuji Higashi , Tsumoru Hirano , Syunichi Kondo
IPC分类号： G03F7/038 , G03F7/027
CPC分类号： G03F7/0388
摘要： A photopolymerizable composition comprising: (a) a compound obtained by reacting one mole of a polyamine represented by the following general formula (I) with at least 2 moles of a compound having a group capable of reacting with the polyamine and a polymerizable ethylenically unsaturated group: ##STR1## wherein n is an integer of not less than 1 and (b) a photopolymerization initiator.A dry PS plate comprises a substrate provided thereon with, in order, a light-sensitive resin layer and a silicone rubber layer wherein the light-sensitive resin layer comprises the photopolymerizable composition and a polymeric compound having film-forming ability.The photopolymerizable composition and the dry PS plate have very high sensitivity.
摘要翻译：一种可光聚合组合物，其包含：（a）通过使1摩尔由下列通式（I）表示的多胺与至少2摩尔具有可与多胺反应的基团的化合物和可聚合烯属不饱和基团：其中n是不小于1的整数，（b）光聚合引发剂。干PS板包括依次设置有感光树脂层和硅橡胶层的基板，其中光敏树脂层包含可光聚合组合物和具有成膜能力的聚合物。可光聚合组合物和干PS板具有非常高的灵敏度。

4. 发明授权

US5888696A Planographic original plate requiring no fountain solution 失效
标题翻译：普通原版不需要润版液
公开(公告)号：US5888696A
公开(公告)日：1999-03-30
申请号：US812550
申请日：1997-03-07
申请人： Tsumoru Hirano , Toshifumi Inno , Koji Sonokawa
发明人： Tsumoru Hirano , Toshifumi Inno , Koji Sonokawa
IPC分类号： G03F7/075 , B41C1/055 , B41C1/10 , B41N1/00 , B41N1/14 , G03F7/00 , G03F7/11
CPC分类号： B41C1/1033 , B41N1/003 , B41C2210/16 , Y10S430/146
摘要： A planographic original plate requiring no fountain solution, in which a layer allowing adhesion thereof with a silicone rubber layer to decrease through transforming a laser beam into heat and the silicone rubber layer of an addition type containing 10 to 20% by weight of organohydrogenpolysiloxane based on solid content are laminated to a support in this order, thereby providing a planographic original plate requiring no fountain solution which is capable of heat mode recording due to a laser beam and is excellent in image reproducibility and resistance to scratching.
摘要翻译：不需要润版液的平版印刷版，其中通过将激光束转换成热量使其与硅橡胶层的粘合性降低的层和基于以下的基于10〜20重量％的有机氢聚硅氧烷的添加型硅橡胶层固体含量依次层压到载体上，从而提供不需要能够通过激光束进行热模式记录的润版液的平版印刷版，并且图像再现性和耐划伤性优异。

5. 发明授权

US06849386B2 Method for preparing master plate useful for making lithographic printing plate without need of dampening water 失效
标题翻译：制备用于制作平版印刷版而不需要润版水的主板的方法
公开(公告)号：US06849386B2
公开(公告)日：2005-02-01
申请号：US10413575
申请日：2003-04-15
申请人： Tsumoru Hirano , Koji Sonokawa
发明人： Tsumoru Hirano , Koji Sonokawa
IPC分类号： G03F7/004 , B41C1/10 , B41N1/00 , B41N1/14 , G03F7/00 , G03F7/075 , G03F7/11
CPC分类号： B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/08 , B41C2210/16 , B41C2210/24 , B41N1/003
摘要： An object of the present invention is to provide a method for manufacturing such a dry lithographic printing master plate that has eliminated uneven plate performance and more specifically that provides a stable adhesiveness between a heat-sensitive layer and a silicone rubber layer as well as a high aging stability of a coating solution. Provided is a method for preparing a master plate useful for making a dry lithographic printing plate comprising at least a heat-sensitive layer and a silicone rubber layer which are stacked in this order on a substrate, said method comprising the steps of: (1) dissolving a diorgano-polysiloxane and a curing catalyst in a solvent; (2) dissolving a cross-linking agent in a solvent; (3) mixing the solution obtained in the step (1) with the solution obtained in the step (2); and (4) applying the mixture obtained in the step (3) over the heat-sensitive layer to thereby form the silicone rubber layer.
摘要翻译：本发明的目的是提供一种制造这种干式平版印刷母板的方法，其消除了不平坦的板性能，更具体地说，在热敏层和硅橡胶层之间提供了稳定的粘附性以及高的涂层溶液的老化稳定性。本发明提供一种制备用于制备干性平版印刷版的母版的方法，所述干版印刷版至少包括在基片上依次堆叠的热敏层和硅橡胶层，所述方法包括以下步骤：（1）将二有机聚硅氧烷和固化催化剂溶解在溶剂中; （2）将交联剂溶解在溶剂中; （3）将步骤（1）中获得的溶液与步骤（2）中获得的溶液混合; 和（4）将在步骤（3）中获得的混合物涂覆在热敏层上，从而形成硅橡胶层。

6. 发明授权

US4946770A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US4946770A
公开(公告)日：1990-08-07
申请号：US84771
申请日：1987-08-13
申请人： Osamu Takahashi , Tsumoru Hirano , Seiki Sakanoue
发明人： Osamu Takahashi , Tsumoru Hirano , Seiki Sakanoue
IPC分类号： G03C7/34 , G03C7/388 , G03C7/392
CPC分类号： G03C7/3882 , G03C7/346
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer containing a dispersion, said dispersion comprising oleophilic fine particles containing (a) at least one oil-soluble cyan coupler represented by formula (I) (described herein) capable of forming substantially non-diffusible cyan dye upon coupling with an oxidation product of an aromatic primary amine developing agent, and (b) a water-insoluble, organic solvent-soluble homopolymer or copolymer comprising not more than about 20% by weight of a repeating unit having an acid radical in the main chain or a side chain thereof, wherein the dispersion does not contain high-boiling point organic solvents. The photographic material provides color images excellent in preservability, particularly resistance to dark discoloration and light discoloration in good balance.
摘要翻译：一种卤化银彩色照相材料，其包括其上具有至少一个含有分散体的卤化银乳剂层的载体，所述分散体包含含有（a）由式（I）（本文所述）表示的至少一种油溶性青色成色剂的亲油性细颗粒，能够在与芳族伯胺显影剂的氧化产物偶联时形成基本上不扩散的青色染料，和（b）水不溶性的有机溶剂可溶的均聚物或共聚物，其包含不超过约20重量％在主链或侧链具有酸基的重复单元，其中分散体不含有高沸点有机溶剂。照相材料提供了保存性优异的彩色图像，特别是抵抗黑暗变色和轻微变色的良好平衡。

7. 发明授权

US4668613A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4668613A
公开(公告)日：1987-05-26
申请号：US724866
申请日：1985-04-19
申请人： Morio Yagihara , Tsumoru Hirano , Tatsuya Yamamoto , Kei Sakanoue
发明人： Morio Yagihara , Tsumoru Hirano , Tatsuya Yamamoto , Kei Sakanoue
IPC分类号： G03C7/26 , C08F2/00 , C08F2/50 , C08F20/00 , C08F20/52 , G03C7/32 , G03C7/327
CPC分类号： G03C7/3275
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a polymer coupler which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is polymerized using a polymerization initiator represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a straight chain or branched chain alkyl group having from 1 to 5 carbon atoms; an R.sub.2 represents a straight chain or branched chain alkyl group having from 1 to 20 carbon atoms.The polymer coupler according to the present invention has a good stability to humidity and heat during storage of the silver halide color photographic light-sensitive material containing thereof and provides decreased formation of fog in non-image areas of color photographs obtained by means of color development processing of the silver halide color photographic light-sensitive material.
摘要翻译：一种卤化银彩色照相感光材料，其包含其上具有含有聚合物偶联剂的卤化银乳剂层的载体，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料，并使用聚合由下列通式（I）表示的引发剂：其中R 1表示具有1至5个碳原子的直链或支链烷基; R 2表示具有1至20个碳原子的直链或支链烷基。根据本发明的聚合物成色剂在含有卤化银彩色摄影感光材料的储存期间对湿度和热量具有良好的稳定性，并且在通过显色获得的彩色照片的非图像区域中减少了雾的形成处理卤化银彩色照相感光材料。

8. 发明授权

US4511647A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4511647A
公开(公告)日：1985-04-16
申请号：US549947
申请日：1983-11-09
申请人： Tsumoru Hirano , Morio Yagihara , Makoto Umemoto
发明人： Tsumoru Hirano , Morio Yagihara , Makoto Umemoto
IPC分类号： G03C7/327 , G03C7/34 , G03C7/16 , G03C7/26
CPC分类号： G03C7/34 , G03C7/3275
摘要： A silver halide color photographic light-sensitive material is disclosed. Their material is comprised of a support having thereon a silver halide emulsion layer containing a cyan color image forming polymer coupler latex. This latex is comprised of a recurring unit of a cyan coupler monomer capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent represented by the general formula (I) and a recurring unit of an ethylenically unsaturated monomer containing an acid component represented by the general formula (II) and a recurring unit of methyl acrylate. ##STR1## The cyan color image forming polymer coupler latex has excellent color forming properties and photographic material containing the coupler latex provides a cyan image having good fastness to heat and the combination of heat and humidity. A method for forming a color image utilizing the disclosed photographic material containing the novel couple of latex is also disclosed.
摘要翻译：公开了一种卤化银彩色照相感光材料。它们的材料由其上具有含有青色成像聚合物成色剂胶乳的卤化银乳剂层的载体组成。该胶乳由能够与通式（I）表示的芳族伯胺显影剂的氧化产物偶联的能够形成染料的青色成色剂单体的重复单元和含有通式（I）的烯键式不饱和单体的重复单元组成，由通式（II）表示的酸成分和丙烯酸甲酯的重复单元。（II）青色成像聚合物成色胶乳具有优异的成色性能，并且含有成色剂胶乳的照相材料提供具有良好耐热牢度和热和湿度组合的青色图像。还公开了利用所公开的含有胶乳新组合的照相材料形成彩色图像的方法。

9. 发明授权

US4409320A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4409320A
公开(公告)日：1983-10-11
申请号：US377271
申请日：1982-05-10
申请人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi , Takashi Ozawa
发明人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi , Takashi Ozawa
IPC分类号： G03C7/38 , C07D231/52 , C08F20/00 , C08F20/34 , C08F20/52 , C08F20/58 , C08F20/60 , C09B26/02 , G03C7/327 , G03C7/00 , G03C1/40
CPC分类号： G03C7/327 , C07D231/52 , C08F20/60
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by the following general formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; and X represents a halogen atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a cyano group or an alkoxycarbonyl group and which is present at the 4-position or 5-position of the phenyl group. The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having an improved sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译：一种卤化银彩色照相感光材料，其包括其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料，是具有衍生自由下列通式（I）表示的单体的重复单元的聚合物或共聚物其中R表示氢原子，含有1至4个碳原子的低级烷基或氯原子 ; X表示卤素原子，酰氨基，氨基甲酰基，亚磺酰氨基，氨磺酰基，氰基或烷氧基羰基，其存在于苯基的4-位或5-位上。品红色成像聚合物成色剂胶乳具有良好的成色性能，能够以高产率形成染料并且不形成不期望的污渍和雾，并且含有品红色图像形成的卤化银彩色照相感光材料聚合物成色剂胶乳具有良好的膜强度和降低的层厚度，并提供稳定的品红色图像，其具有改善的清晰度和对光，热和湿度的良好牢度。还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。

10. 发明授权

US4367282A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4367282A
公开(公告)日：1983-01-04
申请号：US328151
申请日：1981-12-07
申请人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
发明人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
IPC分类号： G03C7/38 , C07D231/52 , C07D521/00 , C08F20/36 , C08F20/60 , C09B26/02 , G03C7/327 , G03C7/00 , G03C1/40
CPC分类号： C07D231/12 , C07D231/52 , C07D233/56 , C07D249/08 , C08F20/36 , C08F20/60 , G03C7/3275
摘要： A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a 2-equivalent magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --NH--, --NHCONH-- or --NHCOO--; Y represents --CONH-- or --COO--; A represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain or an unsubstituted or substituted phenylene group; Ar represents an unsubstituted or substituted phenyl group; Za, Zb, Zc and Zd can each represent a methine group, a substituted methine group or -N.dbd.; m represents 0 or 1; and n represents 0 or 1.The 2-equivalent magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs and provides a stable magenta image having a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译：描述了一种卤化银彩色照相感光材料，其包括其上具有含有2-当量的品红色成像聚合物成色剂胶乳的卤化银乳剂层的载体，其能够在与芳族原料的氧化产物偶联时形成染料胺显影剂，其是具有衍生自由式（I）表示的单体的重复单元的聚合物或共聚物其中R表示氢原子，含有1至4个碳原子的低级烷基或氯原子 X表示-CONH-，-NH-，-NHCONH-或-NHCOO-; Y表示-CONH-或-COO-; A表示未取代或取代的亚烷基，其可以是直链或支链或未取代或取代的亚苯基; Ar表示未取代或取代的苯基; Za，Zb，Zc和Zd各自表示次甲基，取代的次甲基或-N =; m表示0或1; 并且n表示0或1. 2-等价的品红色成像聚合物成色胶乳具有良好的成色性能，能够以高产率形成染料，并且不形成不期望的污渍和雾，并提供稳定的品红色图像，其具有耐光，耐热，耐湿性好。还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。

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