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1. 发明申请

US20090286928A1 CARBON NANOTUBE GRAFTED WITH LOW-MOLECULAR WEIGHT POLYANILINE AND DISPERSION THEREOF 审中-公开
标题翻译：碳纳米管用低分子量聚苯胺和其分散体
公开(公告)号：US20090286928A1
公开(公告)日：2009-11-19
申请号：US12270687
申请日：2008-11-13
申请人： Tatsuhiro TAKAHASHI , Noriyuki Kuramoto , Koichiro Yonetake , Osamu Haba , Hiroshi Awano , Hiroki Arai , Teruya Goto , Yushi Yamaguchi , Naoya Nishimura , Masahiro Hida , Masaaki Ozawa , Mitsunobu Matsumura
发明人： Tatsuhiro TAKAHASHI , Noriyuki Kuramoto , Koichiro Yonetake , Osamu Haba , Hiroshi Awano , Hiroki Arai , Teruya Goto , Yushi Yamaguchi , Naoya Nishimura , Masahiro Hida , Masaaki Ozawa , Mitsunobu Matsumura
IPC分类号： C08L77/06 , C08G69/26
CPC分类号： C08G73/0266 , B82Y30/00 , B82Y40/00 , C08K7/24
摘要： Chemically modified carbon nanotubes composed of carbon nanotubes (such as multiwall carbon nanotubes) having carboxyl groups on the surface thereof and polymeric aniline (such as 3- to 300-meric aniline) bonding thereto through the amide linkage. The chemically modified carbon nanotubes exhibit good affinity with organic solvents and readily disperse into organic solvents.
摘要翻译：由其表面具有羧基的碳纳米管（例如多壁碳纳米管）和通过酰胺键与其结合的聚合苯胺（例如3-至300-聚对苯胺）构成的化学改性的碳纳米管。化学改性的碳纳米管与有机溶剂呈现良好的亲和性，易分散于有机溶剂中。

2. 发明申请

US20130309485A1 HEAT-CONDUCTIVE FILM AND PRODUCTION METHOD THEREFOR 审中-公开
标题翻译：导热膜及其生产方法
公开(公告)号：US20130309485A1
公开(公告)日：2013-11-21
申请号：US13982107
申请日：2012-01-18
申请人： Yoshinari Takayama , Kenichi Tagawa , Daisuke Kitagawa , Tatsuhiro Takahashi , Koichiro Yonetake , Hiroshi Awano , Takumi Shoji , Mitsuteru Tada
发明人： Yoshinari Takayama , Kenichi Tagawa , Daisuke Kitagawa , Tatsuhiro Takahashi , Koichiro Yonetake , Hiroshi Awano , Takumi Shoji , Mitsuteru Tada
IPC分类号： B32B5/16
CPC分类号： B32B5/16 , C01B21/064 , C01P2002/72 , C01P2004/03 , C01P2004/20 , C08J5/18 , C08J2379/08 , C08K3/22 , C08K3/38 , C08K9/02 , C09D179/08 , Y10T428/25 , C08L79/08
摘要： A thermally conductive film (10) includes a matrix (12) made of a resin and flaky filler particles (14) dispersed in the matrix (12). The flaky filler particles (14) each has a flaky filler body (16) made of boron nitride and a γ-ferrite coating (18) on the filler body (16), and are oriented in a through-thickness direction of the thermally conductive film (10). The resin is, for example, polyimide.
摘要翻译：导热膜（10）包括由树脂制成的基体（12）和分散在基质（12）中的片状填料颗粒（14）。片状填料颗粒（14）各自具有由氮化硼制成的片状填料体（16）和填料体（16）上的γ铁氧体涂层（18），并且在导热的贯穿厚度方向电影（10）。树脂是例如聚酰亚胺。

3. 发明授权

US08084121B2 Fine carbon fiber with linearity and resin composite material using the same 有权
标题翻译：细碳纤维与线性和树脂复合材料使用相同
公开(公告)号：US08084121B2
公开(公告)日：2011-12-27
申请号：US10555637
申请日：2004-05-07
申请人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
发明人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
IPC分类号： B32B18/00 , B32B27/04 , D01F9/12
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： The fine carbon fiber obtained by pulverizing vapor grown fine carbon fiber, each fiber including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) is 0.345 nm or less, and the ratio of the peak height (Id) of the band (e.g. 1,341 to 1,349 cm−1) in a Raman scattering spectrum to that of the peak height (Ig) of the band (e.g. 1,570 to 1,578 cm−1) (Id/Ig) is 0.1 to 2, a bending angle of 30° or less with respect to the axis; a composite material comprising the fine carbon fiber and a resin serving as a matrix, wherein the fine carbon fiber is oriented in one direction through, application of an external force; and a production method and use thereof. The linear fine carbon fiber of the present invention exhibits excellent dispersibility in a matrix and is readily oriented by application of an external force, and therefore, enables to produce a composite material, wherein merely the carbon fiber is or both the fine carbon fiber and the matrix resin are oriented in one direction.
摘要翻译：通过粉碎气相生长的细碳纤维而获得的细碳纤维，每个纤维包括沿其轴线延伸的中空空间，外径为1至1000nm，纵横比为5至1,000，BET比表面积为 2〜2000m 2 / g，其中平均层间距离（d002）为0.345nm以下，拉曼散射光谱带的峰高（Id）（例如1,341〜1349cm -1）的比例与的带的高度（Ig）（例如1,570-1,578cm-1）（Id / Ig）为0.1〜2，相对于轴的弯曲角为30°以下。包含细碳纤维和用作基质的树脂的复合材料，其中细碳纤维沿一个方向取向，施加外力; 及其制造方法及其用途。本发明的线状细碳纤维在基体中表现出优异的分散性，并且通过施加外力容易取向，因此能够生产复合材料，其中仅碳纤维为细碳纤维或基质树脂在一个方向上取向。

4. 发明授权

US08372511B2 Fine carbon fiber with linearity and resin composite material using the same 有权
标题翻译：细碳纤维与线性和树脂复合材料使用相同
公开(公告)号：US08372511B2
公开(公告)日：2013-02-12
申请号：US13312719
申请日：2011-12-06
申请人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
发明人： Koichiro Yonetake , Tatsuhiro Takahashi , Ryuji Yamamoto , Toshio Morita
IPC分类号： B32B18/00 , B32B27/04
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： A fine carbon fiber having linearity, each fiber filament of the carbon fiber having a bending angle of 30° or less with respect to the longitudinal direction of the fiber filament, and including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) of the carbon fiber at a (002) plane is 0.345 nm or less as measured by means of X-ray diffractometry, and the ratio of the peak height (Id) of the band at 1,341 to 1,349 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak height (Ig) of the band at 1,570 to 1,578 cm−1 in the spectrum (Id/Ig) is 0.1 to 2. The fiber exhibits excellent dispersibility in a matrix.
摘要翻译：具有线性的细碳纤维，碳纤维的纤维长丝相对于纤维长丝的长度方向具有30°以下的弯曲角度，并且包括沿其轴线延伸的中空空间，并且具有外径 1〜1000nm，长宽比为5〜1000，BET比表面积为2〜2000m 2 / g，其中，（002）面上的碳纤维的平均层间距离（d002）为0.345nm以下如通过X射线衍射法测定的，并且在碳纤维的拉曼散射光谱中，在1,341〜1349cm -1处的条带的峰高（Id）与峰高（Ig）的峰高光谱（Id / Ig）中的1570至1,578cm -1的谱带为0.1至2.该纤维在基质中表现出优异的分散性。

5. 发明申请

US20060286361A1 Fine carbon fiber with linearity and resin composite material using the same 有权
标题翻译：细碳纤维与线性和树脂复合材料使用相同
公开(公告)号：US20060286361A1
公开(公告)日：2006-12-21
申请号：US10555637
申请日：2004-05-07
申请人： Koichiro Yonetake
发明人： Koichiro Yonetake
IPC分类号： D04H13/00 , B32B15/14
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： The fine carbon fiber obtained by pulverizing vapor grown fine carbon fiber, each fiber including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) is 0.345 nm or less, and the ratio of the peak height (Id) of the band (e.g. 1,341 to 1,349 cm−1) in a Raman scattering spectrum to that of the peak height (Ig) of the band (e.g. 1,570 to 1,578 cm−) (Id/Ig) is 0.1 to 2, a bending angle of 30° or less with respect to the axis; a composite material comprising the fine carbon fiber and a resin serving as a matrix, wherein the fine carbon fiber is oriented in one direction through, application of an external force; and a production method and use thereof. The linear fine carbon fiber of the present invention exhibits excellent dispersibility in a matrix and is readily oriented by application of an external force, and therefore, enables to produce a composite material, wherein merely the carbon fiber is or both the fine carbon fiber and the matrix resin are oriented in one direction.
摘要翻译：通过粉碎气相生长的细碳纤维而获得的细碳纤维，每个纤维包括沿其轴线延伸的中空空间，外径为1至1000nm，纵横比为5至1,000，BET比表面积为 2〜2000μm2 / g，其中平均层间距离（d 002 002）为0.345nm以下，带的峰高（Id）（例如，1,570至1,578cm -1）（Id（1））的拉曼散射光谱（例如1,341至1,349cm -1） / Ig）为0.1〜2，相对于轴为30°以下的弯曲角度; 包含细碳纤维和用作基质的树脂的复合材料，其中细碳纤维沿一个方向取向，施加外力; 及其制造方法及其用途。本发明的线状细碳纤维在基质中表现出优异的分散性，并且通过施加外力容易取向，因此能够生产复合材料，其中仅碳纤维为细碳纤维或基质树脂在一个方向上取向。

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