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1. 发明授权

US06303537B1 Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication 失效
标题翻译：乙酸乙烯酯催化剂，包括金属钯和金，并使用超声处理制备
公开(公告)号：US06303537B1
公开(公告)日：2001-10-16
申请号：US09441603
申请日：1999-11-17
申请人： Tao Wang , Jerry A. Broussard , H. Robert Gerberich
发明人： Tao Wang , Jerry A. Broussard , H. Robert Gerberich
IPC分类号： B01J2358
CPC分类号： B01J37/343 , B01J23/44 , B01J23/52 , B01J23/58 , B01J37/0203 , B01J37/0205 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A catalyst effective for the production of vinyl acetate by reaction of ethylene, oxygen and acetic acid, comprising a porous support on the porous surfaces of which is deposited catalytically effective amounts of metallic palladium and gold, and prepared by steps comprising impregnating the support with one or more aqueous solutions of water-soluble compounds of the metals, fixing the metals on the support as water-insoluble compounds in one or more fixing steps by reaction with an appropriate alkaline compound, and reducing the water-insoluble compounds of the catalytically active metals to their free metallic form in one or more reducing steps, at least one of the said reducing steps being carried out in an aqueous medium containing a reducing agent dissolved therein or through which a gaseous reducing agent is bubbled, and in which the support containing the fixed water-insoluble metal compounds is immersed, while sonicating, i.e., applying ultrasound waves to, such aqueous medium.
摘要翻译：通过乙烯，氧气和乙酸的反应生产乙酸乙烯酯有效的催化剂，包括多孔表面上的多孔载体沉积有催化有效量的金属钯和金，并通过以下步骤制备，包括用一种浸渍载体或更多的水溶性金属化合物的水溶液，通过与适当的碱性化合物反应在一个或多个固定步骤中将金属固定在载体上作为水不溶性化合物，并还原催化活性金属的水不溶性化合物在一个或多个还原步骤中以至少一种所述还原步骤在含有还原剂溶解在其中的还原剂的水性介质中进行，或通过该还原剂鼓泡气体还原剂，其中含有固定的不溶于水的金属化合物被浸没，同时超声处理，即对这种水性介质施加超声波。

2. 发明授权

US06486093B2 Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate 有权
标题翻译：乙酸乙烯酯催化剂，包含金属钯和金，由金属钴制成
公开(公告)号：US06486093B2
公开(公告)日：2002-11-26
申请号：US09933214
申请日：2001-08-20
申请人： Tao Wang , Jerry A. Broussard
发明人： Tao Wang , Jerry A. Broussard
IPC分类号： B01J2358
CPC分类号： B01J23/52 , B01J35/008 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A catalyst for the production of vinyl acetate by reaction of ethylene, oxygen and acetic acid comprising a porous support on the porous surfaces of which is deposited catalytically effective amounts of metallic palladium and gold, said catalyst having been prepared by steps comprising impregnating a porous support, the porous surfaces of which contain a catalytically effective amount of a prereduced metallic palladium, with a solution of potassium aurate, and reducing the potassium aurate to a catalytically effective amount of metallic gold. Alternate embodiments are also disclosed.
摘要翻译：一种用于通过乙烯，氧和乙酸的反应生产乙酸乙烯酯的催化剂，其包含多孔载体的多孔表面被沉积有催化有效量的金属钯和金，所述催化剂通过以下步骤制备，所述步骤包括浸渍多孔载体，其多孔表面含有催化有效量的预还原的金属钯，与钴酸钾的溶液一起，并将醇酸钾还原成催化有效量的金属金。还公开了替代实施例。

3. 发明授权

US06350900B1 Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate 失效
公开(公告)号：US06350900B1
公开(公告)日：2002-02-26
申请号：US09088978
申请日：1998-06-02
申请人： Tao Wang , Jerry A. Broussard
发明人： Tao Wang , Jerry A. Broussard
IPC分类号： C07C6705
CPC分类号： B01J23/52 , B01J35/008 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A catalyst for the production of vinyl acetate by reaction of ethylene, oxygen and acetic acid comprising a porous support on the porous surfaces of which is deposited catalytically effective amounts of metallic palladium and gold, said catalyst having been prepared by steps comprising impregnating a porous support, the porous surfaces of which contain a catalytically effective amount of a prereduced metallic palladium, with a solution of potassium aurate, and reducing the potassium aurate to a catalytically effective amount of metallic gold. Alternate embodiments are also disclosed.

4. 发明授权

US5700753A Heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production 失效
标题翻译：用于乙酸乙烯酯生产的非均相双金属钯 - 金催化剂
公开(公告)号：US5700753A
公开(公告)日：1997-12-23
申请号：US655571
申请日：1996-05-24
申请人： Tao Wang , Jerry A. Broussard
发明人： Tao Wang , Jerry A. Broussard
IPC分类号： B01J31/30 , B01J23/52 , B01J23/58 , B01J23/66 , B01J37/02 , C07B61/00 , C07C67/055 , C07C69/15 , B01J23/44
CPC分类号： B01J37/0207 , B01J23/52 , B01J23/58 , B01J23/66 , B01J37/0205 , C07C67/055
摘要： This invention provides a heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production from ethylene, acetic acid and oxygen. An invention catalyst is prepared by forming a first shell dispersion coating of colloidal palladium on the catalyst support surface, and super-imposing a second shell dispersion coating of colloidal gold metal on the catalyst support surface. An organometallic gold compound is employed to apply the gold dispersion on the catalyst support surface. The organometallic gold compound does not require a fixing procedure, which normally is the cause of low gold metal retention. A preferred invention palladium-gold catalyst has a high gold metal retention, and exhibits durability and long term selectivity in vinyl acetate production.
摘要翻译：本发明提供了用于从乙烯，乙酸和氧气生产乙酸乙烯酯的异质双金属钯 - 金催化剂。通过在催化剂载体表面上形成胶态钯的第一壳分散涂层，并在催化剂载体表面上超强度胶体金属金属的第二壳分散涂层来制备发明催化剂。使用有机金属金化合物将金分散体施加到催化剂载体表面上。有机金属金化合物不需要固定程序，这通常是金金属保留金低的原因。优选的本发明钯 - 金催化剂具有高金金属保留性，并且在乙酸乙烯酯生产中表现出耐久性和长期选择性。

5. 发明授权

US06667418B2 Oxidation treatment of a recycle stream in production of acetic acid by methanol carbonylation 失效
标题翻译：通过甲醇羰基化生产乙酸的循环流的氧化处理
公开(公告)号：US06667418B2
公开(公告)日：2003-12-23
申请号：US10124200
申请日：2002-04-16
申请人： Jerry A. Broussard , Hung-Cheun Cheung , Stephen Andrew Houliston , Michael E. Huckman , Peggy McKarns Macatangay , Madan Singh , Michael L. Karnilaw , G. Paull Torrence
发明人： Jerry A. Broussard , Hung-Cheun Cheung , Stephen Andrew Houliston , Michael E. Huckman , Peggy McKarns Macatangay , Madan Singh , Michael L. Karnilaw , G. Paull Torrence
IPC分类号： C07C5112
CPC分类号： C07C51/487 , C07C51/12 , C07C53/08
摘要： A method and system is provided for producing acetic acid by the catalytic carbonylation of methanol with carbon monoxide to obtain a reaction product stream comprising acetic acid and a minor amount of acetaldehyde. The acetaldehyde content in the reaction product stream is reduced by oxidation to convert at least a portion of the acetaldehyde in the stream to acetic acid or further to CO2 and H2O. The oxidized stream may then be directed to the purification section, the reaction section, or both whereby the deleterious effects of acetaldehyde are reduced. Advantage of the present invention over conventional processes is the reduced need to dispose of acetaldehyde as waste and improved overall system efficiency in the production of acetic acid.
摘要翻译：提供了通过甲醇与一氧化碳的催化羰基化生产乙酸的方法和系统，以获得包含乙酸和少量乙醛的反应产物流。通过氧化还原反应产物流中的乙醛含量，将至少一部分乙醛转化为乙酸或进一步转化为CO 2和H 2 O. 然后将氧化物流引导至纯化部分，反应部分或二者，由此降低乙醛的有害作用。本发明优于常规方法的优点是减少了将乙醛作为废物处理的需要，并提高了乙酸生产中的整体系统效率。

6. 发明授权

US5081285A Production of ethyl 3-ethoxypropanoate by acid catalyzed addition of ethanol to ethyl acrylate 失效
标题翻译：通过酸催化将乙醇加入到丙烯酸乙酯中制备3-乙氧基丙酸乙酯
公开(公告)号：US5081285A
公开(公告)日：1992-01-14
申请号：US659790
申请日：1991-02-21
申请人： Jerry D. Unruh , Jerry A. Broussard
发明人： Jerry D. Unruh , Jerry A. Broussard
IPC分类号： C07C67/31
CPC分类号： C07C67/31
摘要： This invention pertains to the addition of an alkyl alcohol to an alkyl acrylate to form alkyl 3-alkoxy propanoate catalyzed by a strong acid catalyst. The process has sepcific application in the addition of ethanol to ethyl acrylate to form ethyl 3-ethoxy propanoate.
摘要翻译：本发明涉及向丙烯酸烷基酯中加入烷基醇以形成由强酸催化剂催化的3-烷氧基丙酸烷基酯。该方法在将乙醇加入到丙烯酸乙酯中以形成3-乙氧基丙酸乙酯有独特的应用。

7. 发明授权

US4863971A Synthesis gas conversion with perovskite catalysts 失效
标题翻译：用钙钛矿催化剂合成气转化
公开(公告)号：US4863971A
公开(公告)日：1989-09-05
申请号：US028257
申请日：1987-03-20
申请人： Jerry A. Broussard , Leslie E. Wade
发明人： Jerry A. Broussard , Leslie E. Wade
IPC分类号： B01J23/00 , C07C1/04 , C07C27/06
CPC分类号： C07C1/044 , B01J23/00 , C07C1/0435 , C07C27/06 , C07C2521/06 , C07C2523/02 , C07C2523/10 , C07C2523/34 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/83
摘要： A process for synthesis gas conversion utilizing perovskite catalysts is disclosed herein. The perovskites utilized in the process have a carbon selectivity of about eight mol percent or more for oxygenated compounds containing one to six carbon atoms. The process comprises reacting synthesis gas in the presence of a perovskite catalyst in the temperature range of about 200.degree. C. to about 400.degree. C.
摘要翻译：本文公开了一种利用钙钛矿催化剂的合成气转化方法。在该方法中使用的钙钛矿对于含有1至6个碳原子的含氧化合物具有约8mol％或更多的碳选择性。该方法包括在约200℃至约400℃的温度范围内使合成气在钙钛矿催化剂存在下反应。

8. 发明授权

US06274531B1 Vinyl acetate catalyst comprising metallic palladium and gold, and cupric acetate 有权
标题翻译：包含金属钯和金的乙酸乙烯酯催化剂和乙酸铜
公开(公告)号：US06274531B1
公开(公告)日：2001-08-14
申请号：US09338739
申请日：1999-06-23
申请人： Ioan Nicolau , Jerry A. Broussard , Philip M. Colling
发明人： Ioan Nicolau , Jerry A. Broussard , Philip M. Colling
IPC分类号： B01J2112
CPC分类号： B01J23/8926 , B01J23/52 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A catalyst for the production of vinyl acetate by reaction of ethylene, oxygen and acetic acid comprising a porous support on the porous surfaces of which is deposited catalytically effective amounts of metallic palladium and gold, and cupric acetate. Use of this catalyst results in a reaction having a relatively low selectivity to carbon dioxide.
摘要翻译：通过乙烯，氧和乙酸的反应生产乙酸乙烯酯的催化剂，其包含多孔载体的多孔表面是沉积有催化有效量的金属钯和金和乙酸铜。使用该催化剂导致对二氧化碳具有较低选择性的反应。

9. 发明授权

US5948724A Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate 失效
标题翻译：包含金属钯和金和乙酸铜的乙酸乙烯酯催化剂
公开(公告)号：US5948724A
公开(公告)日：1999-09-07
申请号：US959897
申请日：1997-10-29
申请人： Ioan Nicolau , Jerry A. Broussard , Philip M. Colling
发明人： Ioan Nicolau , Jerry A. Broussard , Philip M. Colling
IPC分类号： B01J23/52 , B01J23/89 , B01J37/02 , C07C67/055 , C07C69/15 , B01J23/72 , B01J23/44
CPC分类号： B01J23/8926 , B01J23/52 , C07C67/055
摘要： A catalyst for the production of vinyl acetate by reaction of ethylene, oxygen and acetic acid comprising a porous support on the porous surfaces of which is deposited catalytically effective amounts of metallic palladium and gold, and cupric acetate. Use of this catalyst results in a reaction having a relatively low selectivity to carbon dioxide.
摘要翻译：通过乙烯，氧和乙酸的反应生产乙酸乙烯酯的催化剂，其包含多孔载体的多孔表面是沉积有催化有效量的金属钯和金和乙酸铜。使用该催化剂导致对二氧化碳具有较低选择性的反应。

10. 发明授权

US5210337A Formaldehyde resistant catalyst for hydrogenation and hydrogenolysis of aldehydes, acetals, and esters 失效
标题翻译：用于氢化和氢解醛，缩醛和酯的甲醛耐受催化剂
公开(公告)号：US5210337A
公开(公告)日：1993-05-11
申请号：US500103
申请日：1990-03-28
申请人： Jerry A. Broussard
发明人： Jerry A. Broussard
IPC分类号： B01J23/36 , C07C29/141 , C07C29/149
CPC分类号： C07C29/149 , B01J23/36 , C07C29/141 , Y02P20/52
摘要： Rhenium has been found to be formaldehyde resistant catalyst and is thus useful in the catalytic hydrogenation of carbonyls, acetals and esters to alcohols when the reaction medium contains formaldehyde as a reactant or impurity. Also, rhenium is a useful catalyst in the hydrogenolysis of acylic acetals to alcohols.
摘要翻译：已经发现铼是耐甲醛的催化剂，因此当反应介质含有甲醛作为反应物或杂质时，可用于羰基，缩醛和酯与醇的催化氢化。此外，铼是在酰基缩醛对醇的氢解中的有用的催化剂。

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