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1. 发明授权

US5985489A Carbon for a lithium secondary battery, lithium secondary battery, and manufacturing methods therefor 失效
标题翻译：锂二次电池用碳，锂二次电池及其制造方法
公开(公告)号：US5985489A
公开(公告)日：1999-11-16
申请号：US776609
申请日：1997-02-20
申请人： Takushi Ohsaki , Ryuichi Yazaki , Hiroshi Taira , Takashi Inui , Mitsuo Kigure , Akihiro Nakamura
发明人： Takushi Ohsaki , Ryuichi Yazaki , Hiroshi Taira , Takashi Inui , Mitsuo Kigure , Akihiro Nakamura
IPC分类号： H01M4/133 , H01M4/58 , H01M4/587 , H01M4/62 , H01M4/60
CPC分类号： H01M4/587 , H01M4/133 , H01M4/623 , Y02P70/54
摘要： A superior lithium secondary battery having high total discharge capacity, high effective discharge capacity, high total discharge efficiency, and high effective discharge rate can be obtained by using, as a carbon electrode for a lithium secondary battery, a carbon for a lithium secondary battery obtained by successively conducting a halogenation treatment, a dehalogenation treatment, and a pore adjustment treatment on a dry-distilled charcoal, or by successively conducting a crushing treatment, a molding treatment, and a carbonization treatment on a dry-distilled charcoal.
摘要翻译： PCT No.PCT / JP96 / 01684第 371日期1997年2月20日 102（e）1997年2月20日PCT PCT 1996年6月19日PCT公布。出版物WO97 / 01192 日期1997年1月9日通过使用作为锂二次电池的碳电极，可以获得具有高总放电容量，高有效放电容量，高总放电效率和高有效放电率的优良锂二次电池，通过在干馏炭上连续进行卤化处理，脱卤处理和孔调整处理，或者通过对干馏炭进行连续进行破碎处理，成形处理和碳化处理而获得的锂二次电池。

2. 发明授权

US5948329A Manufacturing method for carbon material for electrical double layer capacitor 失效
标题翻译：双电层电容器碳材料的制造方法
公开(公告)号：US5948329A
公开(公告)日：1999-09-07
申请号：US750845
申请日：1996-12-24
申请人： Takushi Ohsaki , Akira Wakaizumi , Mitsuo Kigure , Akihiro Nakamura , Shinichi Marumo , Toshiya Miyagawa , Tadao Adachi
发明人： Takushi Ohsaki , Akira Wakaizumi , Mitsuo Kigure , Akihiro Nakamura , Shinichi Marumo , Toshiya Miyagawa , Tadao Adachi
IPC分类号： H01G9/00 , H01G11/22 , H01G11/34 , H01G11/38 , H01G11/44 , H01G11/58 , H01G11/86 , H01G9/155
CPC分类号： H01G9/155 , Y02E60/13
摘要： It is possible to obtain at high yield a carbonaceous material suitable for carbon electrodes of electrical double layer capacitors and having superior capacitance by means of a method comprising a halogenation treatment step wherein a halogenated dry-distilled charcoal is obtained by bringing a dry-distilled charcoal into contact with a halogen gas; and by a dehalogenation treatment step wherein a part or all of the above-mentioned halogen in said halogenated dry-distilled charcoal is eliminated. In addition, it is possible to obtain carbonaceous material for electrical double layer capacitors, which has a large capacitance at rapid discharge and excellent shape, by means of conducting a molding treatment step in which a molded article is made by crushing a dry-distilled charcoal and adding a binding agent; and a carbonization treatment step in which the above-mentioned molded article is heated in an inert gas atmosphere before conducting the halogenation treatment.
摘要翻译： PCT No.PCT / JP96 / 01151 Sec。 371日期：1996年12月24日 102（e）1996年12月24日PCT PCT 1996年4月27日PCT公布。出版物WO96 / 34402 日期：1996年10月31日可以通过包括卤化处理步骤的方法以高产率获得适用于双电层电容器的碳电极的碳质材料并具有优异的电容，其中通过带来卤化干馏炭与卤素气体接触的干馏炭; 并通过脱卤处理步骤，其中除去所述卤代干馏炭中的上述卤素的一部分或全部。此外，可以通过进行成型制品通过粉碎干馏炭来制造成型制品的方法，可以获得快速放电时具有大电容和优异形状的双电层电容器用碳质材料并加入粘合剂; 以及在进行卤化处理之前将上述成型体在惰性气体气氛中加热的碳化处理工序。

3. 发明授权

US5603867A Method of production for active carbon electrode for use as electrical double layer condenser and active carbon electrode obtained thereby 失效
标题翻译：用作电双层冷凝器的活性炭电极的生产方法和由此获得的活性炭电极
公开(公告)号：US5603867A
公开(公告)日：1997-02-18
申请号：US523622
申请日：1995-09-05
申请人： Takushi Ohsaki , Akira Wakaizumi , Mitsuo Kigure , Akihiro Nakamura , Shinichi Marumo , Toshiya Miyagawa
发明人： Takushi Ohsaki , Akira Wakaizumi , Mitsuo Kigure , Akihiro Nakamura , Shinichi Marumo , Toshiya Miyagawa
IPC分类号： C01B32/336 , H01B1/04 , H01G9/00 , H01G9/155 , H01M4/00 , C01B31/08 , C01B31/10 , C01B31/12
CPC分类号： H01G9/155 , C01B31/10 , H01B1/04 , H01M4/00 , Y02E60/13
摘要： It is the objective of the present invention to provide an active carbon electrode which is of sufficient mechanical strength to be formed into a large plate, may be suitably used as an electrical double layer condenser capable of a large current discharge, and which can realize a high capacitance. The method of production for such an active carbon electrode comprises the steps of a) producing a carbon base material by carrying out a first activation treatment to a carbon material obtained by carbonization of a carbon compound; b) producing a formed body by adding a binder to the carbon base material; c) carbonizing the formed body; and d) producing an active carbon electrode by carrying out a second activation treatment to the carbonized formed body.
摘要翻译：本发明的目的是提供一种具有足够的机械强度以形成大板的活性炭电极，可以适合用作能够实现大电流放电的双电层电容器，高电容。这种活性碳电极的制造方法包括以下步骤：a）通过对通过碳化合物碳化获得的碳材料进行第一活化处理来制造碳基材料; b）通过向碳基材料中添加粘合剂来生产成形体; c）将成形体碳化; 和d）通过对碳化成形体进行第二活化处理来生产活性碳电极。

4. 发明授权

US5658692A Carbon negative electrode materials and lithium secondary cells containing the same 失效
标题翻译：碳负极材料和含有它的锂二次电池
公开(公告)号：US5658692A
公开(公告)日：1997-08-19
申请号：US514504
申请日：1995-08-11
申请人： Takushi Ohsaki , Ryuichi Yazaki , Hiroshi Taira , Akira Wakaizumi
发明人： Takushi Ohsaki , Ryuichi Yazaki , Hiroshi Taira , Akira Wakaizumi
IPC分类号： C04B41/50 , H01M4/58 , H01M4/60
CPC分类号： C04B41/009 , C04B41/5001 , H01M4/587 , C04B2111/00853
摘要： Disclosed is a carbon negative electrode material containing microparticles of hard carbon. The pores in the carbon microparticles have an inlet diameter such that an organic solvent in an electrolyte of a lithium secondary cell is substantially impermeable and that lithium ions are permeable. Use of such carbon negative electrode material as a negative electrode enables to provide a lithium secondary cell with excellent cell capacity, in which charge capacity and discharge capacity are improved and irreversible capacity is minimized.
摘要翻译：公开了含有硬碳微粒的碳负极材料。碳微粒中的孔具有入口直径，使得锂二次电池的电解质中的有机溶剂基本上是不可渗透的，并且锂离子是可渗透的。使用这种碳负极材料作为负极能够提供具有优异的电池容量的锂二次电池，其中充电容量和放电容量得到改善，不可逆容量最小化。

5. 发明授权

US06475461B1 Porous carbonaceous material, manufacturing method therefor and use thereof 失效
标题翻译：多孔碳质材料及其制造方法及其用途
公开(公告)号：US06475461B1
公开(公告)日：2002-11-05
申请号：US08737806
申请日：1996-11-27
申请人： Takushi Ohsaki , Akira Wakaizumi , Takashi Inui , Akihiro Nakamura , Katsuyoshi Yanagita , Masayoshi Hayashida
发明人： Takushi Ohsaki , Akira Wakaizumi , Takashi Inui , Akihiro Nakamura , Katsuyoshi Yanagita , Masayoshi Hayashida
IPC分类号： C01B3110
CPC分类号： H01G9/155 , B01J20/20 , B01J20/30 , B01J21/18 , B01J35/10 , C01B32/336 , C04B38/0022 , H01G11/34 , H01M4/96 , Y02C10/08 , Y02E60/13
摘要： A halogen treatment is conducted comprising: a halogenation step wherein a halogenation heat treatment for preparing a halogenated carbonized charcoal is conducted in which the carbonized charcoal is brought into contact with halogen; and a dehalogenation step wherein a dehalogenation treatment is conducted in which a part of or all halogen atoms in the halogenated carbonized charcoal are eliminated. A porous carbonaceous material is obtained at a high yield, and the amounts of nitrogen, oxygen, carbon dioxide, and methane adsorbed by this porous carbonaceous material are large. When this porous carbonaceous material is used as an electrical double layer capacitor carbon, the electrostatic capacity is increased compared to conventional carbonaceous materials. Consequently, a carbonaceous material is obtained which has micopores and/or sub-micropores which are suitable for the adsorption of small molecules such as nitrogen, and for storage of electrochemical energy.
摘要翻译：进行卤素处理，包括：卤化步骤，其中进行用于制备卤化碳化炭的卤化热处理，其中碳化炭与卤素接触; 和脱卤步骤，其中进行脱卤处理，其中卤代碳化炭中的一部分或全部卤素原子被除去。以高产率获得多孔碳质材料，并且由该多孔碳质材料吸附的氮，氧，二氧化碳和甲烷的量大。当这种多孔碳质材料用作电双层电容器碳时，与常规碳质材料相比，静电容量增加。因此，得到具有适于吸附小分子如氮气的微孔和/或亚微孔以及用于储存电化学能的碳质材料。

6. 发明授权

US5972834A Carbon adsorbent, manufacturing method therefor, gas separation method and device therefor 失效
标题翻译：碳吸附剂及其制造方法，气体分离方法及其装置
公开(公告)号：US5972834A
公开(公告)日：1999-10-26
申请号：US750847
申请日：1996-12-24
申请人： Takushi Ohsaki , Takashi Inui , Katsuyoshi Yanagita , Masayoshi Hayashida , Nobuyasu Tomita , Fusao Nakamura , Satoshi Sawaguchi , Akira Wakaizumi , Hiroyuki Miyake
发明人： Takushi Ohsaki , Takashi Inui , Katsuyoshi Yanagita , Masayoshi Hayashida , Nobuyasu Tomita , Fusao Nakamura , Satoshi Sawaguchi , Akira Wakaizumi , Hiroyuki Miyake
IPC分类号： B01D53/02 , B01J20/20 , C01B3/56 , C01B21/04 , B01J20/02
CPC分类号： C01B3/56 , B01D53/02 , B01J20/20 , C01B21/0461 , B01D2253/102 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , Y02C10/08 , Y02P20/152
摘要： It is possible to increase the amount of nitrogen generated per unit of adsorbent, raise the nitrogen yield, and reduce the manufacturing cost for nitrogen by using, as an adsorbent for the separation of nitrogen, molecular sieving carbon obtained by successively conducting a halogenation treatment, a dehalogenation treatment, and a pore adjustment treatment on a carbonized charcoal. By using activated carbon obtained by successively conducting a halogenation treatment, a dehalogenation treatment, and an activation treatment on a carbonized charcoal, as an adsorbent for carbon dioxide and methane, it is possible to improve the amount adsorbed.
摘要翻译： PCT No.PCT / JP96 / 01152 Sec。 371日期：1996年12月24日 102（e）日期1996年12月24日PCT PCT 1996年4月26日PCT公布。公开号WO96 / 33801 日期1996年10月31日可以通过使用通过连续地获得的氮分离筛分碳的吸附剂，增加单位吸附剂产生的氮的量，提高氮产率，并降低氮的制造成本对碳化炭进行卤化处理，脱卤处理和孔调整处理。通过使用通过对作为二氧化碳和甲烷的吸附剂的碳化炭进行卤化处理，脱卤处理和活化处理而获得的活性炭，可以提高吸附量。

7. 发明授权

US4458022A Process for manufacturing molecular sieving carbon 失效
标题翻译：制造分子筛碳的方法
公开(公告)号：US4458022A
公开(公告)日：1984-07-03
申请号：US495488
申请日：1983-05-17
申请人： Takushi Ohsaki , Susumu Abe
发明人： Takushi Ohsaki , Susumu Abe
IPC分类号： B01J20/20 , C01B31/08 , C01B37/00 , B01J21/20 , B01J21/18
CPC分类号： C01B31/085
摘要： A process for manufacturing molecular sieving carbon is disclosed, wherein pelletized charcoal made of coconut shell charcoal powder and coal tar is washed with dilute mineral acid solution, then a specified amount of coal tar is added, penetrated therein, followed by heat treatment under a particular range of temperature, and cooling in inert gas.
摘要翻译：公开了制造分子筛碳的方法，其中由椰壳炭粉和煤焦油制成的造粒炭用稀无机酸溶液洗涤，然后加入指定量的煤焦油，渗入其中，然后在特定的条件下进行热处理温度范围和惰性气体中的冷却。

8. 发明授权

US4742040A Process for manufacturing a carbon molecular sieve 失效
标题翻译：制造碳分子筛的方法
公开(公告)号：US4742040A
公开(公告)日：1988-05-03
申请号：US8327
申请日：1987-01-29
申请人： Takushi Ohsaki , Susumu Abe
发明人： Takushi Ohsaki , Susumu Abe
IPC分类号： B01J20/20 , C01B31/08 , C01B37/00
CPC分类号： B01J20/20
摘要： A process for manufacturing a carbon molecular sieve having both increased gas adsorption capacity and selectivity, which entails:(a) adding coal tar, coal tar pitch, or a combination thereof to powdered coconut shell charcoal as a binder;(b) pelletizing the mixture and carbonizing the same at about 600.degree.-900.degree.;(c) immersing the pellets in mineral acid solution, thereby sustantially removing soluble ingredients containing alkaline metal compounds therefrom;(d) drying the immersed pellets;(e) adding to the dried pellets a fraction of cresote which is distilled at a temperature of 140.degree. to 260.degree. C., in an amount sufficient to increase both said gas adsorption capacity and selectivity;(f) heating the pellets to about 600.degree.-900.degree. C., for about 10-60 minutes; and(g) cooling the pellets in an inert gas.
摘要翻译：一种制造具有增加的气体吸附能力和选择性的碳分子筛的方法，其包括：（a）将煤焦油，煤焦油沥青或其组合添加到作为粘合剂的粉末状椰子炭炭上; （b）将混合物造粒并在约600-900℃下对其进行碳化; （c）将颗粒浸入无机酸溶液中，由此维持从其中含有碱金属化合物的可溶性成分; （d）干燥浸渍的颗粒; （e）向干燥的颗粒中加入一部分在140℃至260℃的温度下蒸馏的氯氰菊酯，其量足以增加所述气体吸附能力和选择性; （f）将丸粒加热至约600-900℃约10-60分钟; 和（g）在惰性气体中冷却丸粒。

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