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    • 1. 发明授权
    • Fuel system having excellent gasoline barrier property
    • 燃油系统具有优异的汽油阻隔性能
    • US08092879B2
    • 2012-01-10
    • US10684511
    • 2003-10-15
    • Takeshi NomuraTakeshi Koyama
    • Takeshi NomuraTakeshi Koyama
    • B32B1/08B32B23/00
    • F16L11/04B60K15/03177C08G18/3206C08G18/329C08G18/7642C08G2390/40C08J7/047C08J2475/00C09D175/04F16L2011/047Y10T428/13Y10T428/1303Y10T428/1352Y10T428/1359Y10T428/139Y10T428/1393
    • Provided is a fuel system comprising a fuel vessel, molded parts for a fuel and/or a tube for a fuel in which bodies are constituted from at least one of a thermoplastic resin and a synthetic rubber, wherein a coating layer is formed on the surfaces in at least one side of the insides and the outsides of the fuel vessel body, the molded part bodies for a fuel and/or the tube body for a fuel or at least one of connected parts in these bodies; the above coating layer is formed by curing a polyurethane resin composition comprising an active hydrogen-containing compound (A) and an organic polyisocyanate compound (B); and the above coating layer has a gasoline permeability coefficient of 2 g·mm/m2·day or less at 23° C. and a relative humidity of 60% RH. The above coating layer is excellent in a permeation-preventing performance against an automobile fuel (gasoline barrier property), an adhesion property between fuel vessel body and molding parts or tube, a heat resistance and an impact resistance, a flexibility, a bending resistance, etc., then a fuel vessel, molded parts for a fuel and a tube for a fuel which have excellent performances are obtained.
    • 提供了一种燃料系统,其包括燃料容器,用于燃料的模制部件和/或用于燃料的管,其中主体由热塑性树脂和合成橡胶中的至少一种构成,其中在所述表面上形成涂层 在燃料容器本体的内部和外部的至少一侧,用于燃料的模制零件体和/或用于燃料的管体或这些主体中的至少一个连接部分; 通过固化含有活性氢化合物(A)和有机多异氰酸酯化合物(B)的聚氨酯树脂组合物形成上述涂层; 上述涂层在23℃,相对湿度为60%RH的汽油透过系数为2g·mm / m 2·天以下。 上述涂层在汽车燃料的防渗透性(汽油阻隔性),燃料容器主体和成型部件或管之间的粘合性,耐热性和耐冲击性,挠性,耐弯曲性, 然后获得燃料容器,用于燃料的模制零件和具有优异性能的燃料管。
    • 2. 发明申请
    • Gas-barriering coated film
    • 防气涂层膜
    • US20070003768A1
    • 2007-01-04
    • US11455244
    • 2006-06-19
    • Takeshi NomuraTakeshi Koyama
    • Takeshi NomuraTakeshi Koyama
    • B32B27/40
    • C08G18/7642C08G18/3206C08G18/5024Y10T428/31551Y10T428/31562Y10T428/31565Y10T428/31576Y10T428/31587Y10T428/31598
    • Provided is a gas-barriering coated film obtained by coating a gas barriering layer on at least one face of a flexible film or an inorganic-deposited polymer film, wherein the above gas-barriering layer is a polyurethane resin-cured material formed from a composition comprising an active hydrogen-containing compound (A) and an organic polyisocyanate compound (B), and 20% by weight or more of a skeletal structure represented by Formula (1) is contained in the above resin-cured material. The gas-barriering coated film of the present invention is excellent in various performances such as a layer-to-layer adhesive property, a gas barriering property at a high humidity, a bending resistance and a retort treating resistance in addition to a high gas barriering property, and therefore it is applied to various uses including packing materials for food and medicines to which a high gas barriering property is required.
    • 提供一种通过在柔性膜或无机沉积聚合物膜的至少一个表面上涂覆阻气层而获得的气体阻挡涂布膜,其中上述阻气层是由组合物形成的聚氨酯树脂固化材料 包含含活性氢的化合物(A)和有机多异氰酸酯化合物(B),并且在上述树脂固化材料中含有20重量%以上由式(1)表示的骨架结构。 本发明的阻气性涂膜除了高阻气性以外还具有各种性能,例如层间粘合性,高湿度下的阻气性,耐弯曲性和蒸煮处理电阻 属性,因此适用于需要高气体阻塞性的食品,药品的包装材料等各种用途。
    • 3. 发明授权
    • Pneumatic tire
    • 气动轮胎
    • US07240708B2
    • 2007-07-10
    • US10749409
    • 2004-01-02
    • Takeshi NomuraTakeshi Koyama
    • Takeshi NomuraTakeshi Koyama
    • B60C5/14
    • B60C5/14B60C1/0008C08G18/329C08G18/7642C08G18/8019C08G18/8029C08G2380/00C09D175/12Y10S152/16Y10T428/31551
    • A pneumatic tire comprising a skin layer which is formed by curing a polyurethane resin composition comprising a compound having active hydrogen atoms and an organic polyisocyanate compound, has an oxygen permeation coefficient at 23° C. under a relative humidity of 60% of 2.0 ml·mm/m2·day·MPa or smaller and comprises 20% by weight or more of a skeleton structure represented by formula (1) is provided. Since the tire has the skin layer formed with the polyurethane resin composition and having an excellent barrier property to gases, the weight of the tire can be decreased, durability can be improved and quiet driving can be achieved while the internal pressure is retained even when the gas filling the tire is the air, and the tire is more economical than tires filled with nitrogen gas. Unlike other tires using other materials having the barrier property to gases to decrease the weight, no adhesives are necessary for disposing the skin layer. Thus, the process can be simplified and the cost can be reduced in the production
    • 包含通过固化包含具有活性氢原子的化合物的聚氨酯树脂组合物和有机多异氰酸酯化合物形成的表皮层的充气轮胎在相对湿度为60%的2.0ml的条件下具有23℃的透氧系数。 mm / m 2·day.MPa以下,由式(1)表示的骨架结构体含有20重量%以上。 由于轮胎具有由聚氨酯树脂组合物形成并具有优异的气体隔离性的表皮层,所以即使在内部压力保持时也能够减轻轮胎的重量,提高耐久性,并能够保持静音, 填充轮胎的气体是空气,轮胎比装有氮气的轮胎更经济。 与使用具有气体阻隔性的其他材料以减轻重量的其它轮胎不同,不需要粘合剂来设置表皮层。 因此,可以简化该过程,并且可以在生产中降低成本
    • 4. 发明授权
    • Gas-barriering coated film
    • 防气涂层膜
    • US07534493B2
    • 2009-05-19
    • US11455244
    • 2006-06-19
    • Takeshi NomuraTakeshi Koyama
    • Takeshi NomuraTakeshi Koyama
    • B32B27/40
    • C08G18/7642C08G18/3206C08G18/5024Y10T428/31551Y10T428/31562Y10T428/31565Y10T428/31576Y10T428/31587Y10T428/31598
    • Provided is a gas-barriering coated film obtained by coating a gas barriering layer on at least one face of a flexible film or an inorganic-deposited polymer film, wherein the above gas-barriering layer is a polyurethane resin-cured material formed from a composition comprising an active hydrogen-containing compound (A) and an organic polyisocyanate compound (B), and 20% by weight or more of a skeletal structure represented by Formula (1) is contained in the above resin-cured material. The gas-barriering coated film of the present invention is excellent in various performances such as a layer-to-layer adhesive property, a gas barriering property at a high humidity, a bending resistance and a retort treating resistance in addition to a high gas barriering property, and therefore it is applied to various uses including packing materials for food and medicines to which a high gas barriering property is required.
    • 提供一种通过在柔性膜或无机沉积聚合物膜的至少一个表面上涂覆阻气层而获得的气体阻挡涂布膜,其中上述阻气层是由组合物形成的聚氨酯树脂固化材料 包含含活性氢的化合物(A)和有机多异氰酸酯化合物(B),并且在上述树脂固化材料中含有20重量%以上由式(1)表示的骨架结构。 本发明的阻气性涂膜除了高阻气性以外还具有各种性能,例如层间粘合性,高湿度下的阻气性,耐弯曲性和蒸煮处理电阻 属性,因此适用于需要高气体阻塞性的食品,药品的包装材料等各种用途。
    • 5. 发明申请
    • Polyisocyanate compound, process for producing the compound, polyaddition composition and powder coating material
    • 多异氰酸酯化合物,化合物的制造方法,加聚组合物和粉末涂料
    • US20060128926A1
    • 2006-06-15
    • US11347267
    • 2006-02-06
    • Takeshi KoyamaTakeshi Nomura
    • Takeshi KoyamaTakeshi Nomura
    • C08G18/00
    • C08G18/798C08G18/0895C08G18/2825C08G18/3212C08G18/4213C08G18/757C08G2150/20Y10T428/31547
    • A polyisocyanate compound obtained by highly converting a bis(isocyanatomethyl)cyclohexane into a uretidione compound, a process for producing the compound, a polyisocyanate polyaddition composition obtained by polyaddition of the compound, a compound having at least two hydroxyl groups and a compound having one hydroxyl group, and a powder coating material using the composition as the curing agent. The powder coating material is advantageous for safety and health due to the absence of dissociation of blocking agents and for economy due to a content of latent NCO greater than conventional uretidione-based powder coating materials. When a curing agent obtained from the polyisocyanate compound is used in combination with a polyester polyol having 30% or greater of hydroxyl group bonded to secondary carbon atom in the entire hydroxyl group, the curing temperature is lowered and the coating film exhibits excellent gloss like solvent-based coating materials, smoothness of the surface, weatherability and mechanical properties.
    • 通过将双(异氰酸甲酯基)环己烷高度转化成脲基二膦化合物得到的多异氰酸酯化合物,该化合物的制造方法,通过化合物的加成得到的多异氰酸酯加聚组合物,具有至少2个羟基的化合物和具有1个羟基的化合物 和使用该组合物作为固化剂的粉末涂料。 粉末涂料由于不存在封端剂的解离和经济性而有利于安全性和健康性,因为潜在的NCO含量比常规的基于脲基二酮的粉末涂料的含量要大。 当从多异氰酸酯化合物获得的固化剂与在整个羟基中与仲碳原子键合的羟基的含量为30%以上的聚酯多元醇组合使用时,固化温度降低,涂膜表现出优异的光泽,如溶剂 基涂料,表面光滑度,耐候性和机械性能。
    • 8. 发明授权
    • Polyisocyanate prepolymer
    • 多异氰酸酯预聚物
    • US06262296B1
    • 2001-07-17
    • US09549545
    • 2000-04-14
    • Takeshi NomuraTakeshi KoyamaYutaka Kono
    • Takeshi NomuraTakeshi KoyamaYutaka Kono
    • C07C27124
    • C08G18/757C08G18/12C08G18/6674C08G2190/00C08G18/307
    • A polyisocyanate prepolymer with isocyanate group on terminal obtainable by reaction of (A) polyoxyalkylenepolyol, (B) polyhydric alcohol having a molecular weight of 90 to 250 and the number of hydroxyl group of 2 to 3 with branched alkyl group and/or cyclohexane ring and (C) organic polyisocyanate composed of bis(isocyanatemethyl)cyclohexane, wherein NCO group content in the polyisocyanate prepolymer is 8% by weight or above and urethane group content in the polyisocyanate prepolymer is 8% by weight or above and sum total of NCO group content and urethane group content is 16 to 30% by weight and a concentration of unreacted (C) organic polyisocyanate remained in the polyisocyanate prepolymer is 1% by weight or below.
    • 具有异氰酸酯基的多异氰酸酯预聚物末端可以通过(A)聚氧亚烷基多元醇,(B)分子量为90〜250的多元醇和2〜3的羟基数与支链烷基和/或环己烷环反应而得到, (C)由双异氰酸酯甲基环己烷组成的有机多异氰酸酯,其中多异氰酸酯预聚物中的NCO基含量为8重量%以上,多异氰酸酯预聚物中的氨基甲酸酯基含量为8重量%以上,NCO基含量的总和 氨基甲酸酯基含量为16〜30重量%,多异氰酸酯预聚物中残留的未反应(C)有机多异氰酸酯的浓度为1重量%以下。