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    • 1. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5858635A
    • 1999-01-12
    • US803373
    • 1997-02-20
    • Takeshi NakamineMasuji MotokiToshio KawagishiNaoto Matsuda
    • Takeshi NakamineMasuji MotokiToshio KawagishiNaoto Matsuda
    • G03C7/38G03C1/08G03C7/26G03C7/32
    • G03C7/3835
    • A silver halide color photographic material is described, containing a 1H-pyrazolo�5,1-c!-1,2,4-triazole magenta coupler represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.4 each represent a substituent; R.sub.2 and R.sub.3 each represent a hydrogen atom, an alkyl group, an aryl group, a hydroxyl group or an alkyl group substituted with at least one hydroxyl group; R.sub.9 represents a hydrogen atom, an alkyl group, an aryl group, an acyl group or a sulfonyl group; L represents --SO.sub.2 --, --CO--, --SO.sub.2 NR.sub.10 --, --CONR.sub.10 -- or --COO--; R.sub.10 represents a hydrogen atom, an alkyl group or an aryl group; A.sub.1, A.sub.2, and A.sub.3 each represent --O--, --NR.sub.5 --, --NR.sub.5 CO--, --CONR.sub.5 --, --NR.sub.5 SO.sub.2 --, --SO.sub.2 NR.sub.5 --, --COO--, --OCO--, --NR.sub.5 CONR.sub.5 --, --OCONR.sub.5 -- or --NHCOO--; R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group or an alkyl group substituted with at least one hydroxyl group; B.sub.1, B.sub.2, and B.sub.3 each represent an alkyl group, an alkylene group, an aryl group, an arylene group, an alkyl group substituted with at least one hydroxyl group or an alkylene group substituted with at least one hydroxyl group; s represents 0 or an integer of 1 to 3; X represents a hydrogen atom or a group releasable on coupling with an oxidized aromatic primary amine developing agent; k represents 0 or an integer of 1 to 3; u, m, n, t, and p each represent 0 or 1, provided that m-n+t-p=0; q represents 1; r represents 1 or 2; and at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, B.sub.1, B.sub.2, and B.sub.3 has a hydroxyl group, provided that the hydroxyl group is not the one directly bonded to an aryl group.
    • 描述了含有由式(I)代表的1H-吡唑并[5,1-c] -1,2,4-三唑品红成色剂取代基的卤化银彩色照相材料; R2和R3各自表示氢原子,烷基,芳基,羟基或被至少一个羟基取代的烷基; R9表示氢原子,烷基,芳基,酰基或磺酰基; L表示-SO 2 - , - CO - , - SO 2 NR 10 - , - CONR 10 - 或-COO-; R 10表示氢原子,烷基或芳基; A1,A2和A3各自表示-O-,-NR5-,-NR5CO-,-CONR5-,-NR5SO2-,-SO2NR5-,-COO-,-OCO-,-NR5CONR5-,-OCONR5-或-NHCOO - ; R5表示氢原子,烷基,芳基或被至少一个羟基取代的烷基; B1,B2和B3各自表示烷基,亚烷基,芳基,亚芳基,被至少一个羟基取代的烷基或被至少一个羟基取代的亚烷基; s表示0或1〜3的整数, X表示氢原子或与氧化芳族伯胺显影剂偶联可释放的基团; k表示0或1〜3的整数, u,m,n,t和p各自表示0或1,条件是m-n + t-p = 0; q表示1; r表示1或2; R 1,R 2,R 3,R 4,R 5,B 1,B 2和B 3中的至少一个具有羟基,条件是羟基不是直接与芳基键合的羟基。
    • 3. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5605788A
    • 1997-02-25
    • US556141
    • 1995-11-09
    • Toshio KawagishiTakeshi NakamineMasuji Motoki
    • Toshio KawagishiTakeshi NakamineMasuji Motoki
    • G03C7/00C07D487/04G03C7/38
    • C07D487/04G03C7/3835
    • A silver halide color photographic material containing a pyrazolotriazole coupler represented by the following formula (I) or (II): ##STR1## wherein R.sub.1 represents a hydrogen atom, a halogen atom, or a substituent; X represents a hydrogen atom, a halogen atom, or a group capable of being splitted off by the reaction with an oxidation product of a developing agent; L.sub.1 represents an (n+1)-valent linking group; L.sub.2 represents a group represented by the following formula (III); and n represents 1 or 2, and when n is 2, two L.sub.2 's may be the same or different;--[(A.sub.1).sub.a (B.sub.1).sub.b (A.sub.2).sub.c (B.sub.2).sub.d (A.sub.3).sub.e (B.sub.3).sub.f (A.sub.4).sub.g (B.sub.4).sub.h ](III)wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represents --O--, --S--, --NR.sub.2 --, --N(R.sub.2)CO--, --CON(R.sub.2)--, --N(R.sub.2)SO.sub.2 --, --SO.sub.2 N(R.sub.2)--, --CO.sub.2 --, --OCO--, --N(R.sub.2)CON(R.sub.3)--, --OCON(R.sub.2)-- or --N(R.sub.2)CO.sub.2 --; R.sub.2 and R.sub.3 each represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkanesulfonyl group or an arenesulfonyl group; B.sub.1, B.sub.2 and B.sub.3 each represents an alkylene group or an arylene group; B.sub.4 represents an alkyl group or an aryl group; a, b, c, d, e, f and g each represents 0 or 1, and h represents 1, provided that a-b=0, c-d=0 and e-f=0; and at least one group represented by R.sub.2, R.sub.3, B.sub.1, B.sub.2, B.sub.3 and B.sub.4 in the substituents represented by L.sub.2 has a group represented by the following formula (IV):--A--NH--R.sub.4 (IV)wherein A represents --CO-- or --SO.sub.2 --; and R.sub.4 represents a hydrogen atom or an alkyl group.
    • 含有由下式(I)或(II)表示的吡唑并三唑成色剂的卤化银彩色照相材料:其中R 1表示氢原子,卤素原子或取代基; X表示氢原子,卤素原子或能够通过与显影剂的氧化产物反应而分裂的基团; L1表示(n + 1)价连接基团; L2表示由下式(III)表示的基团。 - (A1)a(B1)b(A2)c(B2)d(A3)e(B3)f(A4)其中n为1或2,当n为2时,两个L2可以相同或不同; )g(B4)h](III)其中A1,A2,A3和A4各自表示-O - , - S - , - NR2-,-N(R2)CO-,-CON(R2) - , - N( R2)SO2-,-SO2N(R2) - ,-COO2-,-OCO-,-N(R2)CON(R3) - , - OCON(R2) - 或-N(R2)CO2-; R2和R3各自表示氢原子,烷基,芳基,酰基,链烷磺酰基或芳烃磺酰基; B1,B2和B3各自表示亚烷基或亚芳基; B4表示烷基或芳基; a,b,c,d,e,f和g各自表示0或1,h表示1,条件是a-b = 0,c-d = 0,e-f = 0; 在由L2表示的取代基中的R2,R3,B1,B2,B3和B4表示的至少一个基团具有下式(IV)表示的基团:-A-NH-R4(IV)其中A表示-CO - 或-SO 2 - ; R4表示氢原子或烷基。
    • 9. 发明授权
    • Hair dye composition and dyeing method
    • 染发组合物和染色方法
    • US07056355B2
    • 2006-06-06
    • US10661609
    • 2003-09-15
    • Dominic PrattToshio Kawagishi
    • Dominic PrattToshio Kawagishi
    • A61K7/13
    • A61K8/494A61K8/40A61K2800/43A61Q5/10
    • The present invention is directed to a hair dyeing composition containing a dissociative azo dye of the following general formula (1) A-N═N—B  (1) wherein “A” represents a phenyl or naphthyl group which may be substitued; “B” represents an atomic group containing a dissociative proton, with the proviso “A” and “B” are free of sulfo, carboxyl and quaternary ammonium groups. Additionally, the present invention describes a method of dyeing human or animal hair by using such a dye and the use of this direct azo dye for dyeing human or animal hair. The use of this direct azo dye can impart the hair with an extremely vivid color and has less color fading over time.
    • 本发明涉及含有以下通式(1)的解离偶氮染料的染发组合物:<?in-line-formula description =“In-line Formulas”end =“lead”?> ANNB(1) “in-line-formula description =”In-line Formulas“end =”tail“?>其中”A“表示可被取代的苯基或萘基; “B”表示含有解离质子的原子团,条件是“A”和“B”不含磺基,羧基和季铵基团。 此外,本发明描述了使用这种染料染色人或动物毛发的方法,以及使用该直接偶氮染料染色人或动物毛发的方法。 这种直接偶氮染料的使用可以使头发具有非常鲜艳的颜色,并且随着时间的推移具有较少的褪色。