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    • 4. 发明申请
    • POSITIVE RESIST COMPOSITION AND METHOD OF FORMING RESIST PATTERN
    • 正电阻组合物和形成电阻图案的方法
    • US20090269701A1
    • 2009-10-29
    • US12427547
    • 2009-04-21
    • Makiko IrieTakeshi Iwai
    • Makiko IrieTakeshi Iwai
    • G03F7/004G03F7/20
    • G03F7/0397
    • A positive resist composition including a resin component (A) which exhibits increased solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the resin component (A) including a structural unit (a0) represented by general formula (a0) (wherein R represents a hydrogen atom, a lower alkyl group of 1 to 5 carbon atoms or a halogenated lower alkyl group of 1 to 5 carbon atoms; Q represents a divalent linking group containing a nitrogen atom or an oxygen atom; R6 represents a lower alkyl group of 1 to 5 carbon atoms or an alkoxy group of 1 to 5 carbon atoms; p represents an integer of 1 to 3; and q represents an integer of 0 to 2) and a structural unit (a1) derived from an acrylate ester containing an acid dissociable, dissolution inhibiting group exclusive of groups that exhibit aromaticity.
    • 一种正型抗蚀剂组合物,包括在酸作用下在碱性显影液中显示出增加的溶解性的树脂组分(A)和暴露时产生酸的酸产生剂组分(B),所述树脂组分(A)包括结构单元 a0)(其中R表示氢原子,1〜5个碳原子的低级烷基或1〜5个碳原子的卤代低级烷基); Q表示含有氮原子的二价连接基团 或氧原子; R 6表示碳原子数1〜5的低级烷基或碳原子数1〜5的烷氧基,p表示1〜3的整数,q表示0〜2的整数),结构式 单元(a1)衍生自含有酸解离的溶解抑制基团的丙烯酸酯,不包括具有芳香性的基团。
    • 6. 发明申请
    • Oxime sulfonates and the use thereof as latent acids
    • 肟磺酸盐及其作为潜酸的用途
    • US20100167178A1
    • 2010-07-01
    • US12308279
    • 2007-06-15
    • Hitoshi YamatoToshikage AsakuraYuichi NishimaeTakeshi IwaiMakiko IrieKazuhiko Nakayama
    • Hitoshi YamatoToshikage AsakuraYuichi NishimaeTakeshi IwaiMakiko IrieKazuhiko Nakayama
    • C07C69/52C08F24/00C08F228/02G03C1/04C08F2/46G03F5/00G03F7/00
    • G03F7/0045C07C309/00C07C2603/18C08F20/36G03F7/0046G03F7/0397
    • Compounds of the formula (I), (II) or (III), wherein R1 is for example C1-C18alkylsulfonyl, C1-C10haloalkylsulfonyl, camphorylsulfonyl, phenyl-C1-C3alkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthrylsulfonyl, phenanthrylsulfonyl or heteroarylsulfonyl, R′1 is for example phenylenedisulfonyl, R2 is for example CN, C1-C10haloalkyl or C1-C10haloalkyl which is substituted by (IV); Ar1 is for example phenyl optionally substituted by a group of formula (IV); Ar′1 is for example phenylene which optionally is substituted by a group of formula (IV); A1, A2 and A3 independently of each other are for example hydrogen, halogen, CN, or C1-C18alkyl; D2 is for example a direct bond, O, (CO)O, (CO)S, SO2, OSO2 or C1-C18alkylene; or A3 and D2 together form C3-C30cycloalkenyl; or A2 and D2 together with the carbon of the ethylenically unsaturated double bond to which they are attached form C3-C30cycloalkyl; D3 and D4 for example independently of each other are a direct bond, O, S, C1-C18alkylene or C3-C30cycloalkylene provided that at least one of the radicals R2, Ar1 or Ar′1 comprises a group of the formula (IV); are suitable as photolatent acid donors and for the preparation of corresponding polymers to be employed in chemically amplified photoresists.
    • 式(I),(II)或(III)的化合物,其中R 1是例如C 1 -C 18烷基磺酰基,C 1 -C 10卤代烷基磺酰基,樟脑磺酰基,苯基-C 1 -C 3烷基磺酰基,苯基磺酰基,萘基磺酰基,蒽基磺酰基,菲基磺酰基或杂芳基磺酰基,R'1 是例如亚苯基二磺酰基,R 2是例如CN,被C 1 -C 10卤代烷基或被(IV)取代的C 1 -C 10卤代烷基; Ar 1是例如任选被式(Ⅳ)基团取代的苯基; Ar 1是例如任选被式(IV)的基团取代的亚苯基; A1,A2和A3彼此独立地是例如氢,卤素,CN或C 1 -C 18烷基; D2例如是直接键合O,(CO)O,(CO)S,SO 2,OSO 2或C 1 -C 18亚烷基; 或A3和D2一起形成C 3 -C 30环烯基; 或A2和D2与它们所连接的烯属不饱和双键的碳一起形成C 3 -C 30环烷基; D3和D4彼此独立地是直接键合O,S,C 1 -C 18亚烷基或C 3 -C 30环烷基,条件是基团R 2,Ar 1或Ar'1中的至少一个包含式(Ⅳ)基团。 适合作为光潜酸供体,并用于制备用于化学放大光致抗蚀剂的相应聚合物。
    • 10. 发明授权
    • Positive resist composition and method of forming resist pattern
    • 正型抗蚀剂组合物和形成抗蚀剂图案的方法
    • US08263307B2
    • 2012-09-11
    • US12427547
    • 2009-04-21
    • Makiko IrieTakeshi Iwai
    • Makiko IrieTakeshi Iwai
    • G03F7/00G03F7/004
    • G03F7/0397
    • A positive resist composition including a resin component (A) which exhibits increased solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the resin component (A) including a structural unit (a0) represented by general formula (a0) (wherein R represents a hydrogen atom, a lower alkyl group of 1 to 5 carbon atoms or a halogenated lower alkyl group of 1 to 5 carbon atoms; Q represents a divalent linking group containing a nitrogen atom or an oxygen atom; R6 represents a lower alkyl group of 1 to 5 carbon atoms or an alkoxy group of 1 to 5 carbon atoms; p represents an integer of 1 to 3; and q represents an integer of 0 to 2) and a structural unit (a1) derived from an acrylate ester containing an acid dissociable, dissolution inhibiting group exclusive of groups that exhibit aromaticity.
    • 一种正型抗蚀剂组合物,包括在酸作用下在碱性显影液中显示出增加的溶解性的树脂组分(A)和暴露时产生酸的酸产生剂组分(B),所述树脂组分(A)包括结构单元 a0)(其中R表示氢原子,1〜5个碳原子的低级烷基或1〜5个碳原子的卤代低级烷基); Q表示含有氮原子的二价连接基团 或氧原子; R 6表示碳原子数1〜5的低级烷基或碳原子数1〜5的烷氧基,p表示1〜3的整数,q表示0〜2的整数),结构式 单元(a1)衍生自含有酸解离的溶解抑制基团的丙烯酸酯,不包括具有芳香性的基团。