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1. 发明授权

US5559186A Thermoplastic resin compositions comprising blends of polyphenylene ether and polystyrene copolymer resins 失效
标题翻译：包括聚苯醚和聚苯乙烯共聚物树脂的共混物的热塑性树脂组合物
公开(公告)号：US5559186A
公开(公告)日：1996-09-24
申请号：US413158
申请日：1995-03-29
申请人： Takeshi Fujii , Yasuro Suzuki , Hayato Kihara , Takashi Anbo
发明人： Takeshi Fujii , Yasuro Suzuki , Hayato Kihara , Takashi Anbo
IPC分类号： C08L25/04 , C08L51/04 , C08L71/00 , C08L71/12 , C08L25/08
CPC分类号： C08L71/123 , Y10S525/905
摘要： A thermoplastic resin composition having excellent appearance and moldability contains:(A) 1 to 99% by weight of a polyphenylene ether resin,(B) 99 to 1% by weight of a polystyrene resin prepared by copolymerization of: (i) a styrene compound, 100 to 500 ppm by weight of a compound containing 2-6 vinyl groups, and if necessary, a compound capable of copolymerizing with the styrene compound, or (ii) a polystyrene resin obtained by copolymerization of a styrene compound, 100 to 500 ppm by weight of a compound containing 2-6 vinyl groups, a first rubber, and if necessary, a compound capable of copolymerizing with said styrene compound, or a mixture of (i) and (ii). Component (C) is a second rubber which can be present in amounts of about 0 to 100 parts by weight relative to (A) and (B).
摘要翻译：具有优异的外观和成型性的热塑性树脂组合物含有：（A）1〜99重量％的聚苯醚树脂，（B）99〜1重量％的聚苯乙烯树脂，其通过以下方法共聚制备：（i）苯乙烯化合物，100〜500重量ppm的含有2-6个乙烯基的化合物，如果需要，可以与苯乙烯化合物共聚的化合物，或（ii）通过苯乙烯化合物共聚得到的聚苯乙烯树脂100〜500ppm 的含有2-6个乙烯基的化合物，第一橡胶，如果需要，可以与所述苯乙烯化合物共聚的化合物或（i）和（ii）的混合物。组分（C）是相对于（A）和（B）可以以约0至100重量份的量存在的第二橡胶。

2. 发明授权

US06660806B1 Rubber-modified styrenic resin composition and molded article thereof 失效
标题翻译：橡胶改性苯乙烯树脂组合物及其成型品
公开(公告)号：US06660806B1
公开(公告)日：2003-12-09
申请号：US09458959
申请日：1999-12-10
申请人： Shuji Yoshimi , Hayato Kihara , Takahiro Ishii
发明人： Shuji Yoshimi , Hayato Kihara , Takahiro Ishii
IPC分类号： C08F27901
CPC分类号： C08L51/04 , C08L23/08 , C08L83/04 , C08L2666/04 , C08L2666/02
摘要： A rubber-modified styrenic resin composition comprising (A) 100 wt. parts of a rubber-modified styrenic resin which contains 10 to 35 wt. % of soft component particles having an average particle size of 0.1 to 0.5 &mgr;m, where said soft component particles have a single occlusion structure comprising a core part which consists of a single continuous phase of a styrenic resin and a shell part which comprises a rubber polymer and occludes said core part, and (B) 0.1 to 10 wt. parts of a polymer having a solubility parameter (SP) of 8.45 to 8.70 and having no aromatic vinyl compound unit therein. This composition has excellent plane impact strength and gloss properties, as well as moldability and other physical properties, and satisfies properties required for exterior materials, wrapping materials and molded foam articles.
摘要翻译：橡胶改性苯乙烯树脂组合物，其包含（A）100重量％橡胶改性苯乙烯树脂的一部分，其含有10〜35重量％％的平均粒径为0.1〜0.5μm的软组分颗粒，其中所述软组分颗粒具有包含由单一连续相的苯乙烯树脂组成的核心部分和包含橡胶聚合物的壳部分的单一闭塞结构并封闭所述核心部分，（B）0.1〜10wt。部分溶解度参数（SP）为8.45〜8.70的聚合物，其中没有芳族乙烯基化合物单元。该组合物具有优异的平面冲击强度和光泽性能，以及成型性等物理性能，并且满足外部材料，包装材料和模塑泡沫制品所需的性能。

3. 发明授权

US5783646A Process for producing styrene base polymer 失效
标题翻译：制备苯乙烯基聚合物的方法
公开(公告)号：US5783646A
公开(公告)日：1998-07-21
申请号：US899641
申请日：1997-07-24
申请人： Hayato Kihara , Masayuki Fujita
发明人： Hayato Kihara , Masayuki Fujita
IPC分类号： C08F2/02 , C08F2/38 , C08F12/08 , C08F2/00
CPC分类号： C08F2/38 , C08F12/08
摘要： A styrene base polymer superior and well-balanced in mechanical strength and fluidity and also superior in heat resistance is industrially advantageously produced by a radical polymerization process comprising; (a) subjecting styrene or a styrene compound and a radical scavenger to thermal polymerization, (1) a concentration of the radical scavenger to styrene or the styrene compound being from 3.0.times.10.sup.-3 to 5.0.times.10.sup.-2 mol %, and (2) a polymerization temperature ranging from 100.degree. C. to 140.degree. C., provided that the concentration of the radical scavenger (C) and the polymerization temperature (T) satisfy the following formula, 100C +0.088T.ltoreq.13.8, and (b) continuing the polymerization to a polymerization conversion of from 40 to 85%.
摘要翻译：在机械强度和流动性方面优异且平衡良好且耐热性优异的苯乙烯基聚合物在工业上有利地通过自由基聚合方法制备，所述方法包括：（a）使苯乙烯或苯乙烯化合物和自由基清除剂进行热聚合，（1）自由基清除剂对苯乙烯或苯乙烯化合物的浓度为3.0×10 -3至5.0×10 -2摩尔％，和（2）聚合温度范围为100℃至140℃，条件是自由基清除剂（C）和聚合温度（T）的浓度满足下式：100℃+0.088T≤13.8，和（b ）继续聚合至40至85％的聚合转化率。

4. 发明授权

US06417307B1 Shrink film 失效
标题翻译：收缩膜
公开(公告)号：US06417307B1
公开(公告)日：2002-07-09
申请号：US09514303
申请日：2000-02-28
申请人： Nobuo Oi , Hayato Kihara , Tatsuya Miyatake
发明人： Nobuo Oi , Hayato Kihara , Tatsuya Miyatake
IPC分类号： C08F21206
CPC分类号： C08J5/18 , C08F4/65908 , C08F4/65912 , C08F210/02 , C08F212/08 , C08J2323/08 , C08J2325/04 , C08F4/6592 , C08F2500/03 , C08F2500/17 , C08F2500/26
摘要： A shrink film comprising a non-crystalline copolymer of ethylene with an alkenyl aromatic hydrocarbon, and having a transparency, a low temperature shrinking property, a high shrinkage ratio and a small natural shrinkage.
摘要翻译：一种包含乙烯与烯基芳烃的非结晶共聚物，具有透明性，低温收缩性，高收缩率和小的自然收缩率的收缩膜。

5. 发明授权

US5854366A Styrene base random copolymer and process for producing the same 失效
标题翻译：苯乙烯基无规共聚物及其制备方法
公开(公告)号：US5854366A
公开(公告)日：1998-12-29
申请号：US744143
申请日：1996-11-12
申请人： Satoshi Nakagawa , Shuji Yoshimi , Hayato Kihara
发明人： Satoshi Nakagawa , Shuji Yoshimi , Hayato Kihara
IPC分类号： C08F2/00 , C08F2/02 , C08F6/06 , C08F6/10 , C08F212/00 , C08F212/06 , C08F212/08 , C08F212/36
CPC分类号： C08F212/08
摘要： A styrene base random copolymer having a weight average molecular weight of 200,000 to 1,000,000, a monovinylbenzene unit and a divinylbenzene unit in an amount of 50 to 500 ppm by weight based on the weight of the monovinylbenzene unit, the divinylbenzene unit consisting of p-divinylbenzene unit and m-divinylbenzene unit, wherein the weight ratio between the p-divinylbenzene unit and the m-divinylbenzene unit is in the range of 100:0 to 75:25, which is superior in impact strength, melt tension, heat resistance and fluidity, and which is capable of being molded within a short molding cycle, is industrially advantageously produced by a continuous bulk polymerization without troubles such as undesirable deposits of polymeric gel material on reactor walls.
摘要翻译：基于单乙烯基苯单元的重量，重均分子量为200,000至1,000,000的苯乙烯基无规共聚物，单乙烯基苯单元和二乙烯基苯单元的量为50至500重量ppm，二乙烯基苯单元由对二乙烯基苯单元和间二乙烯基苯单元，其中对二乙烯基苯单元和间二乙烯基苯单元之间的重量比在100:0至75:25的范围内，其冲击强度，熔体张力，耐热性和流动性优异，并且其能够在短的成型周期内模制，在工业上有利地通过连续本体聚合制备，而没有诸如聚合物凝胶材料在反应器壁上的不希望的沉积物的麻烦。

6. 发明授权

US5726215A Styrene resin composition and shaped article thereof 失效
标题翻译：苯乙烯树脂组合物及其成型制品
公开(公告)号：US5726215A
公开(公告)日：1998-03-10
申请号：US555098
申请日：1995-11-08
申请人： Shuji Yoshimi , Hayato Kihara , Takahiro Ishii
发明人： Shuji Yoshimi , Hayato Kihara , Takahiro Ishii
IPC分类号： C08J5/18 , C08L23/02 , C08L23/08 , C08L25/04 , C08L53/00
CPC分类号： C08L23/02 , C08J5/18 , C08L25/04 , C08L53/00 , C08J2325/08 , C08L2207/066 , C08L23/06 , C08L23/08 , C08L23/0869 , C08L23/10
摘要： A styrene resin composition is disclosed which constitutes 45 to 92% by weight of a styrene resin (A), 5 to 45% by weight of an olefin resin other than an ethylene-unsaturated carboxylic acid ester copolymer(B), and 3 to 25% by weight of an ethylene-unsaturated carboxylic acid ester copolymer (C). The styrene resin composition of the present invention may be used to make a variety of shaped articles which exhibit excellent mechanical properties, such as an impact strength, elongation at break and resistance against chemicals such as Freon and oil.
摘要翻译：公开了一种苯乙烯树脂组合物，其占苯乙烯树脂（A）45-92重量％，除乙烯 - 不饱和羧酸酯共聚物（B）以外的5〜45重量％的烯烃树脂，3〜25重量份重量％的乙烯 - 不饱和羧酸酯共聚物（C）。本发明的苯乙烯树脂组合物可以用于制造各种成形制品，其具有优异的机械性能，例如冲击强度，断裂伸长率和耐氟化物和油等化学品。

7. 发明授权

US5489652A Injection-molded articles 失效
标题翻译：注塑制品
公开(公告)号：US5489652A
公开(公告)日：1996-02-06
申请号：US464387
申请日：1995-06-05
申请人： Takahiro Ishii , Hayato Kihara , Shuji Yoshimi , Hiroshi Miyagi
发明人： Takahiro Ishii , Hayato Kihara , Shuji Yoshimi , Hiroshi Miyagi
IPC分类号： C08L25/04 , C08F279/00 , C08F279/02 , C08L9/00 , C08L25/06 , C08L51/00 , C08L51/04 , C08F287/00
CPC分类号： C08F279/02 , C08L25/06 , C08L2205/14 , C08L9/00
摘要： Disclosed are a rubber-modified polystyrene resin composition which comprises a polystyrene resin serving as a matrix and soft component particles as dispersed therein, the composition fulfilling the following requirements (a) to (d):(a) the polystyrene resin as the matrix satisfies the following requirements:150,000.ltoreq.Mw.ltoreq.500,000wherein Mw is the weight average molecular weight, and2.ltoreq.Bn(Mz).ltoreq.20wherein Bn(Mz) is the branch count or the number of branching points in the Z-average molecular weight (Mz),(b) the soft component particles in the composition have an average particle diameter (Dp) of 0.1 to 10 .mu.m,(c) the soft component particles in the composition have a swelling index in the range of 3 to 30, and(d) the proportion of the soft component particles in the composition is in the range of 5 to 30% by weight, as well as an injection-molded article formed from the composition.
摘要翻译：公开了一种橡胶改性的聚苯乙烯树脂组合物，其包含用作基质的聚苯乙烯树脂和分散在其中的软组分颗粒，该组合物满足以下要求（a）至（d）：（a）作为基质的聚苯乙烯树脂满足以下要求：150,000

8. 发明授权

US5489629A Rubber-modified polystyrene resin compositions 失效
标题翻译：橡胶改性聚苯乙烯树脂组合物
公开(公告)号：US5489629A
公开(公告)日：1996-02-06
申请号：US291462
申请日：1994-08-17
申请人： Takahiro Ishii , Hayato Kihara , Shuji Yoshimi , Hiroshi Miyagi
发明人： Takahiro Ishii , Hayato Kihara , Shuji Yoshimi , Hiroshi Miyagi
IPC分类号： C08L25/04 , C08F279/00 , C08F279/02 , C08L9/00 , C08L25/06 , C08L51/00 , C08L51/04 , C08F287/00
CPC分类号： C08F279/02 , C08L25/06 , C08L2205/14 , C08L9/00
摘要： Disclosed are a rubber-modified polystyrene resin composition which comprises a polystyrene resin serving as a matrix and soft component particles as dispersed therein, the composition fulfilling the following requirements (a) to (d):(a) the polystyrene resin as the matrix satisfies the following requirements:150,000.ltoreq.Mw.ltoreq.500,000wherein Mw is the weight average molecular weight, and2.ltoreq.Bn(Mz).ltoreq.20wherein Bn(Mz) is the branch count or the number of branching points in the Z-average molecular weight (Mz),(b) the soft component particles in the composition have an average particle diameter (Dp) of 0.1 to 10 .mu.m,(c) the soft component particles in the composition have a swelling index in the range of 3 to 30, and(d) the proportion of the soft component particles in the composition is in the range of 5 to 30% by weight, as well as an injection-molded article formed from the composition.
摘要翻译：公开了一种橡胶改性的聚苯乙烯树脂组合物，其包含用作基质的聚苯乙烯树脂和分散在其中的软组分颗粒，该组合物满足以下要求（a）至（d）：（a）作为基质的聚苯乙烯树脂满足以下要求：150,000

9. 发明授权

US5936036A Rubber-modified styrenic resin composition and molded article thereof 失效
标题翻译：橡胶改性苯乙烯树脂组合物及其成型品
公开(公告)号：US5936036A
公开(公告)日：1999-08-10
申请号：US941575
申请日：1997-09-30
申请人： Hayato Kihara , Takahiro Ishii , Kenji Atarashi
发明人： Hayato Kihara , Takahiro Ishii , Kenji Atarashi
IPC分类号： B29C39/02 , B29C45/00 , B29C47/00 , B29K96/02 , C08L51/04 , C08L23/08
CPC分类号： C08L51/04
摘要： There is provided a rubber-modified styrenic resin composition comprising a rubber-modified styrenic resin containing soft component particles of a salami structure and a polymer having a predetermined solubility parameter, which is much more improved in both of plane impact resistance and Izod impact resistance, while retaining a high level of other properties such as rigidity, gloss and moldability.
摘要翻译：提供一种橡胶改性苯乙烯树脂组合物，其包含含有萨拉米香结构的软组分颗粒的橡胶改性苯乙烯树脂和具有预定溶解度参数的聚合物，其在平面抗冲击性和艾佐德冲击强度两方面都得到更大的改善，同时保持高水平的其他性能，如刚性，光泽和成型性。

10. 发明授权

US5665833A Method for controlling a polymerization rate of styrene resins 失效
标题翻译：苯乙烯树脂聚合速度控制方法
公开(公告)号：US5665833A
公开(公告)日：1997-09-09
申请号：US683197
申请日：1996-07-18
申请人： Hiroto Mukaiyama , Hayato Kihara
发明人： Hiroto Mukaiyama , Hayato Kihara
IPC分类号： C08F4/32 , C08F12/08
CPC分类号： C08F12/08
摘要： The method for controlling a polymerization rate, in a continuous radical polymerization of mainly styrene monomer using a complete mixing type reactor, without substantially changing an average molecular weight of a polymer formed, comprising the steps of: (a) keeping a polymerization temperature substantially constant at t(.degree.C.), (b) setting a feeding rate of the styrene monomer to A times larger rate than that in a polymerization conducted in the absence of a radical polymerization initiator, and (c) controlling an amount of the radical polymerization initiator added in the range of from (0.1/n).times.10.sup.-3 to (2.0/n).times.10.sup.-3 mol per 1 liter of the monomer, n being a number of radical generating functional groups present in one molecule of the radical polymerization initiator, such that a polymer concentration x satisfy the mathematical expression: x.gtoreq.0.3t+6.multidot.(A-1)+12 and that x be kept substantially constant, wherein A represents a ratio of a polymerization rate after being controlled to a rate of polymerization conducted in the absent of the radical polymerization initiator. The method can easily and as desired control the polymerization rate using any desired radical polymerization initiator.
摘要翻译：在主要使用完全混合型反应器的苯乙烯单体的连续自由基聚合中基本上不改变形成的聚合物的平均分子量的方法来控制聚合速率的方法，包括以下步骤：（a）保持聚合温度基本上恒定在t（℃）下，（b）将苯乙烯单体的进料速率设定为不存在自由基聚合引发剂时所进行的聚合反应的A倍，和（c）控制自由基聚合的量引发剂以每1升单体为（0.1 / n）×10-3至（2.0 / n）×10-3mol的范围内添加，n为存在于自由基聚合引发剂的一个分子中的自由基产生官能团数，使得聚合物浓度x满足数学表达式：x> / = 0.3t + 6x（A-1）+12，并且x保持基本上恒定，其中A表示控制后的聚合速率与在没有自由基聚合引发剂的情况下进行的聚合速率。该方法可以容易且按需要使用任何所需的自由基聚合引发剂控制聚合速率。

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