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    • 9. 发明授权
    • Electrode and battery using the same
    • 电极和电池使用相同
    • US07229713B2
    • 2007-06-12
    • US10486049
    • 2003-06-18
    • Takeru YamamotoGentaro KanoHiroyuki Akashi
    • Takeru YamamotoGentaro KanoHiroyuki Akashi
    • H01M4/02H01M10/40
    • H01M4/02H01M4/13H01M10/052H01M10/0587H01M2004/021H01M2004/028
    • Provided are an electrode and a battery having superior charge-discharge cycle characteristics and capable of obtaining a higher energy density. The battery comprises a spirally wound electrode body (20) including a cathode (21) and an anode (22) spirally wound with a separator (23) in between. During charge, lithium metal is precipitated on the anode (22), so the capacity of the anode (22) is represented by the sum of a capacity component by insertion and extraction of lithium and a capacity component by precipitation and dissolution of the lithium metal. The anode (22) includes a mixture layer (22b) having a powdered anode active material, and the mixture layer (22b) has liquid absorption properties that when 1 μdm3 of propylene carbonate is dropped on the mixture layer (22b) at 23° C., a contact angle that the mixture layer (22b) forms with a propylene carbonate drop becomes 10 degrees within 100 seconds. Thereby, the mixture layer (22b) is impregnated with an electrolyte solution quickly and uniformly, so lithium metal is uniformly precipitated on the whole mixture layer (22b).
    • 提供了具有优异的充放电循环特性并且能够获得更高能量密度的电极和电池。 电池包括螺旋卷绕的电极体(20),其包括阴极(21)和在其间螺旋地缠绕有隔板(23)的阳极(22)。 在充电期间,锂金属在阳极(22)上沉淀,因此阳极(22)的容量由锂的插入和提取的容量分量和通过锂金属的沉淀和溶解的容量分量之和表示 。 阳极(22)包括具有粉末状阳极活性物质的混合物层(22b),并且混合物层(22b)具有液体吸收性质,当将碳酸丙烯酯的1% 混合层(22b)在23℃下,混合层(22b)与碳酸丙烯酯滴形成的接触角在100秒内变为10度。 由此,混合层(22b)迅速且均匀地浸渍电解质溶液,使锂金属在整个混合层(22b)上均匀地沉淀。
    • 10. 发明授权
    • Battery
    • 电池
    • US07682752B2
    • 2010-03-23
    • US11470686
    • 2006-09-07
    • Tomoyuki NakamuraTakahiro EndoHiroyuki Akashi
    • Tomoyuki NakamuraTakahiro EndoHiroyuki Akashi
    • H01M6/18
    • H01M10/0565H01M2/16H01M4/66H01M6/10H01M10/0436H01M2300/0082
    • A battery in which the relative positions of a cathode, an anode and a separator are maintained with high precision is provided. A cathode and an anode face each other with a polymer electrolyte including a polymer and a separator in between. In each of the cathode and the anode, an active material layer is disposed on a current collector. Exposed regions where the active material layers are not disposed on the current collectors and the separator are adhered to each other with the polymer electrolyte in between. Thereby, even under a high-temperature environment, the heat shrinkage of the separator can be prevented, and heat generation due to the generation of a short-circuit current can be prevented.
    • 提供了以高精度保持阴极,阳极和隔膜的相对位置的电池。 阴极和阳极在其间具有包括聚合物和隔膜的聚合物电解质彼此面对。 在阴极和阳极的每个中,活性物质层设置在集电体上。 活性物质层未设置在集电体上的曝光区域和隔板之间的聚合物电解质彼此粘合。 由此,即使在高温环境下也能够防止隔板的热收缩,能够防止由于短路电流的产生而发热。