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1. 发明授权

US06307117B1 Method for producing ethylene and propylene 有权
标题翻译：生产乙烯和丙烯的方法
公开(公告)号：US06307117B1
公开(公告)日：2001-10-23
申请号：US09508043
申请日：2000-03-03
申请人： Takashi Tsunoda , Mitsuhiro Sekiguchi
发明人： Takashi Tsunoda , Mitsuhiro Sekiguchi
IPC分类号： C07C406
CPC分类号： C07C4/06 , B01J29/061 , B01J29/40 , B01J29/44 , C07C2529/04 , C07C2529/40 , C10G2400/20 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： Disclosed is a method for producing ethylene and propylene from a hydrocarbon feedstock by catalytic conversion, which comprises contacting, in a reactor, a hydrocarbon feedstock comprising 20% by weight or more, based on the weight of the hydrocarbon feedstock, of at least one C4-C12 olefin with a zeolite-containing catalyst, wherein the zeolite in the zeolite-containing catalyst satisfies the following requirements: (1) the zeolite is an intermediate pore size zeolite having a pore size of from 5 to 6.5 Å, (2) the zeolite contains substantially no proton, (3) the zeolite contains at least one metal selected from the group consisting of metals belonging to Group IB of the Periodic Table, and (4) the zeolite has an SiO2/Al2O3 molar ratio of from 200 to 5,000, to effect a catalytic conversion reaction of the hydrocarbon feedstock, thereby obtaining a reaction mixture containing ethylene and propylene; and separating the ethylene and propylene from the reaction mixture. In the method of the present invention, the zeolite-containing catalyst has high resistance to deactivation and, thus, ethylene and propylene can be stably produced in high yield for a prolonged period of time.
摘要翻译：公开了一种通过催化转化从烃原料生产乙烯和丙烯的方法，其包括在反应器中使基于烃原料重量的20重量％或更多的烃原料与至少一个C 4 -C 12烯烃与含沸石的催化剂，其中，含沸石的催化剂中的沸石满足以下要求：（1）沸石是孔径为5〜6.5的中等孔径的沸石，（2）沸石基本上不含质子，（3）沸石含有选自元素周期表第IB族金属中的至少一种金属，（4）沸石的SiO 2 / Al 2 O 3摩尔比为200-5,000 ，进行烃原料的催化转化反应，得到含有乙烯和丙烯的反应混合物; 并从反应混合物中分离乙烯和丙烯。在本发明的方法中，含沸石的催化剂具有高的失活性，因此可以长期稳定地高产率地制备乙烯和丙烯。

2. 发明授权

US07754934B2 Process for producing ethylene and propylene 有权
标题翻译：生产乙烯和丙烯的方法
公开(公告)号：US07754934B2
公开(公告)日：2010-07-13
申请号：US11631644
申请日：2005-07-15
申请人： Takashi Tsunoda , Mitsuhiro Sekiguchi
发明人： Takashi Tsunoda , Mitsuhiro Sekiguchi
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , Y02P20/582 , C07C11/06 , C07C11/04
摘要： A process for efficiently and stably producing ethylene and propylene which comprises bringing a hydrocarbon feedstock comprising at least one C4-12 olefin into contact with a zeolite-containing catalyst to obtain a reaction mixture containing ethylene and propylene, separating the reaction mixture into a fraction comprising ingredients ranging from hydrogen to C3 hydrocarbons and a fraction comprising C4 and higher hydrocarbons, and recycling the C4 and higher hydrocarbons as they are to a reactor.
摘要翻译：一种有效和稳定地生产乙烯和丙烯的方法，其包括使包含至少一种C 4-12烯烃的烃原料与含沸石的催化剂接触以获得含有乙烯和丙烯的反应混合物，将反应混合物分离成包含成分范围从氢气到C3碳氢化合物和包含C4和更高级烃的馏分，并将C4和更高级烃原样循环到反应器中。

3. 发明授权

US06894163B2 Process for preparation of epsilon-caprolactam 失效
标题翻译： ε-己内酰胺的制备方法
公开(公告)号：US06894163B2
公开(公告)日：2005-05-17
申请号：US10466888
申请日：2002-02-14
申请人： Takashi Tsunoda , Kenji Akagishi , Mitsuhiro Sekiguchi
发明人： Takashi Tsunoda , Kenji Akagishi , Mitsuhiro Sekiguchi
IPC分类号： B01J21/16 , B01J29/035 , B01J29/40 , C07D201/04
CPC分类号： C07D201/04 , B01J21/16 , B01J29/035 , B01J29/40 , Y02P20/52 , Y02P20/584
摘要： ε-Caprolactam is produced by contacting cyclohexanone oxime with a solid acid catalyst in the gaseous phase to effect a rearrangement reaction of the cyclohexanone oxime. The solid acid catalyst is produced by calcining a dried catalyst precursor that can be a zeolite, a crystalline clay mineral and at least one substance selected from an inorganic oxide and a compound which forms the inorganic oxide by calcination. The inorganic oxide includes at least one element selected Groups 4, 13 and 14 of the Periodic Table, and the inorganic oxide excludes oxides contained in a crystalline form in the zeolite and the crystalline clay mineral. Alternately, the rearrangement reaction occurs in the presence of a polyhydric alcohol compound R1—O—R2—OH (where R1 represents C1-C5 alkyl or phenyl, and R2 represents C2-C5 alkylene).
摘要翻译：通过使环己酮肟与气相中的固体酸催化剂接触来制备ε-己内酰胺，以实现环己酮肟的重排反应。固体酸催化剂通过煅烧可以是沸石的干燥催化剂前体，结晶粘土矿物和选自无机氧化物的至少一种物质和通过煅烧形成无机氧化物的化合物来制备。无机氧化物包括选自元素周期表第4,13和14族中的至少一种元素，无机氧化物排除沸石和结晶粘土矿物中结晶形式的氧化物。或者，重排反应发生在多元醇化合物R 1 -OR 2 -OH的存在下（其中R 1表示C

4. 发明申请

US20070265482A1 Process for Producing Ethylene and Propylene 有权
标题翻译：生产乙烯和丙烯的方法
公开(公告)号：US20070265482A1
公开(公告)日：2007-11-15
申请号：US11631644
申请日：2005-07-15
申请人： Takashi Tsunoda , Mitsuhiro Sekiguchi
发明人： Takashi Tsunoda , Mitsuhiro Sekiguchi
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , Y02P20/582 , C07C11/06 , C07C11/04
摘要： A process for efficiently and stably producing ethylene and propylene which comprises bringing a hydrocarbon feedstock comprising at least one C4-12 olefin into contact with a zeolite-containing catalyst to obtain a reaction mixture containing ethylene and propylene, separating the reaction mixture into a fraction comprising ingredients ranging from hydrogen to C3 hydrocarbons and a fraction comprising C4 and higher hydrocarbons, and recycling the C4 and higher hydrocarbons as they are to a reactor.
摘要翻译：一种有效和稳定地生产乙烯和丙烯的方法，其包括使包含至少一种C 4-12烯烃的烃原料与含沸石的催化剂接触以获得含有乙烯和丙烯的反应混合物，将反应混合物分离成包含成分范围从氢至C 3 O 3烃的馏分和包含C 4+和更高级烃的馏分，并将C 4 - SUB和高级碳氢化合物。

5. 发明授权

US5968342A Zeolite catalyst and method of converting hydrocarbons using the same 失效
标题翻译：沸石催化剂和使用其的碳氢化合物的转化方法
公开(公告)号：US5968342A
公开(公告)日：1999-10-19
申请号：US809830
申请日：1997-03-21
申请人： Takashi Tsunoda , Mitsuhiro Sekiguchi , Tokitaka Kaneshima
发明人： Takashi Tsunoda , Mitsuhiro Sekiguchi , Tokitaka Kaneshima
IPC分类号： B01J29/064 , B01J29/068 , B01J29/44 , B01J29/46 , C07B61/00 , C07C4/06 , C07C5/393 , C07C5/41 , C07C11/02 , C07C15/02 , C10G11/02 , C10G11/05 , C10G35/095 , C10G47/20 , B01J29/40
CPC分类号： B01J29/44 , B01J29/068 , C07C4/06 , C07C5/415 , C10G11/05 , C10G11/18 , C07C2529/40 , C10G2400/20 , C10G2400/30
摘要： The present invention provides a catalyst to convert hydrocarbons, which comprises a zeolite containing substantially no proton and having an intermediate pore diameter, a molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 of at least 20 and one or more metals belonging to Group Ib of the Periodic Table. Further, the present invention provides a method to catalytically convert hydrocarbons by using the above catalyst. By means of the present invention, there can be provided a stable catalyst for conversion of hydrocarbons, which is capable of obtaining olefins containing ethylene as a main component and monocyclic aromatic hydrocarbons with good balance and a high yield, and which is hardly deteriorated by steam having a high temperature.
摘要翻译： PCT No.PCT / JP95 / 02040 Sec。 371日期1997年3月21日 102（e）1997年3月21日PCT PCT 1995年10月5日PCT公布。 WO96 / 13331 PCT出版物日期：1996年5月9日本发明提供了一种转化烃的催化剂，其包含基本上不含质子且具有中等孔径，SiO 2与Al 2 O 3的摩尔比为至少20的沸石和属于Ib族的Ib族的一种或多种金属周期表。此外，本发明提供了通过使用上述催化剂催化转化烃的方法。通过本发明，可以提供一种用于转化烃的稳定催化剂，其能够获得含有乙烯作为主要成分的烯烃和具有良好平衡和高产率的单环芳烃，并且几乎不被蒸汽劣化具有高温。

6. 发明申请

US20110172477A1 PROCESS AND APPARATUS FOR PRODUCING OLEFIN 有权
标题翻译：生产烯烃的方法和装置
公开(公告)号：US20110172477A1
公开(公告)日：2011-07-14
申请号：US13119150
申请日：2009-09-01
申请人： Mitsuhiro Sekiguchi , Takashi Tsunoda
发明人： Mitsuhiro Sekiguchi , Takashi Tsunoda
IPC分类号： C07C15/02 , B01J8/00 , C07C4/02
CPC分类号： C10G11/20 , B01J29/40 , B01J29/44 , B01J29/46 , B01J35/1052 , B01J37/0018 , B01J37/0045 , B01J37/04 , B01J37/30 , B01J2229/42 , C10G9/36 , C10G11/05 , C10G11/18 , C10G11/187 , C10G31/06 , C10G70/00 , C10G2300/1081 , C10G2300/807 , C10G2400/02 , C10G2400/20 , C10G2400/22
摘要： The present invention provides a process for producing olefin having 3 or more carbon atoms from ethane stably in a simpler process. The present invention provides a method for producing olefin having a step of obtaining a cold fraction by cooling an ethane-cracked gas, which is obtained by thermal cracking of ethane in the presence of steam, to 600° C. or less; and a step of obtaining a catalytic cracking gas containing olefin having 3 or more carbon atoms by bringing the cold fraction into contact with a catalyst containing a medium pore diameter zeolite.
摘要翻译：本发明提供一种在更简单的工艺中稳定地从乙烷中生产具有3个或更多个碳原子的烯烃的方法。本发明提供一种生产烯烃的方法，其具有通过将蒸汽存在下乙烷热裂解而得到的乙烷裂解气体冷却至600℃以下而得到冷馏分的工序; 以及通过使冷馏分与含有中等孔径沸石的催化剂接触来获得含有3个以上碳原子的烯烃的催化裂化气体的工序。

7. 发明授权

US09309470B2 Process and apparatus for producing olefin 有权
标题翻译：烯烃生产方法和设备
公开(公告)号：US09309470B2
公开(公告)日：2016-04-12
申请号：US13119150
申请日：2009-09-01
申请人： Mitsuhiro Sekiguchi , Takashi Tsunoda
发明人： Mitsuhiro Sekiguchi , Takashi Tsunoda
IPC分类号： C07C4/02 , C07C4/06 , C10G11/20 , B01J29/40 , B01J37/00 , B01J37/30 , C10G9/36 , C10G11/05 , C10G11/18 , C10G31/06 , C10G70/00 , B01J29/44 , B01J29/46 , B01J35/10 , B01J37/04
CPC分类号： C10G11/20 , B01J29/40 , B01J29/44 , B01J29/46 , B01J35/1052 , B01J37/0018 , B01J37/0045 , B01J37/04 , B01J37/30 , B01J2229/42 , C10G9/36 , C10G11/05 , C10G11/18 , C10G11/187 , C10G31/06 , C10G70/00 , C10G2300/1081 , C10G2300/807 , C10G2400/02 , C10G2400/20 , C10G2400/22
摘要： The present invention provides a process for producing olefin having 3 or more carbon atoms from ethane stably in a simpler process. The present invention provides a method for producing olefin having a step of obtaining a cold fraction by cooling an ethane-cracked gas, which is obtained by thermal cracking of ethane in the presence of steam, to 600° C. or less; and a step of obtaining a catalytic cracking gas containing olefin having 3 or more carbon atoms by bringing the cold fraction into contact with a catalyst containing a medium pore diameter zeolite.
摘要翻译：本发明提供一种在更简单的工艺中稳定地从乙烷中生产具有3个或更多个碳原子的烯烃的方法。本发明提供一种生产烯烃的方法，其具有通过将蒸汽存在下乙烷热裂解而得到的乙烷裂解气体冷却至600℃以下而得到冷馏分的工序; 以及通过使冷馏分与含有中等孔径沸石的催化剂接触来获得含有3个以上碳原子的烯烃的催化裂化气体的工序。

8. 发明申请

US20070161824A1 Method for producing alcohol and/or ketone 审中-公开
标题翻译：生产醇和/或酮的方法
公开(公告)号：US20070161824A1
公开(公告)日：2007-07-12
申请号：US10588785
申请日：2005-02-08
申请人： Takashi Tsunoda , Kenji Akagishi , Atsushi Watanabe
发明人： Takashi Tsunoda , Kenji Akagishi , Atsushi Watanabe
IPC分类号： C07C29/04 , C07C45/34
CPC分类号： C07C29/04 , B01J23/002 , B01J23/14 , B01J23/28 , B01J35/08 , B01J2523/00 , C07C45/28 , C07C49/08 , C07C49/10 , C07C49/403 , B01J2523/41 , B01J2523/43 , B01J2523/68 , C07C31/12
摘要： A method for producing an alcohol and/or a ketone, wherein a raw material containing at least one alkene is reacted in the presence of steam under the contact with an oxide catalyst in a gas phase, to produce an alcohol and/or a ketone corresponding to said alkene(s), which comprises satisfying the following requirements: (a) the above oxide catalyst contains the oxide(s) of molybdenum and/or tin, (b) the above reaction is carried out under a condition wherein molecular oxygen is not fed and by the use of a system wherein said catalyst is circulated between a fluid bed reactor and a regenerator, and (c) a stripper is provided on the way from the regenerator to the reactor.
摘要翻译：一种制备醇和/或酮的方法，其中含有至少一种烯烃的原料在与氧化物催化剂的气相接触的蒸汽存在下反应，生成相应的醇和/或酮所述烯烃包括满足以下要求：（a）上述氧化物催化剂含有钼和/或锡的氧化物，（b）上述反应在分子氧为不进料和使用其中所述催化剂在流化床反应器和再生器之间循环的系统，和（c）在从再生器到反应器的路上提供汽提塔。

9. 发明授权

US07113224B2 Receiving apparatus 有权
公开(公告)号：US07113224B2
公开(公告)日：2006-09-26
申请号：US10401578
申请日：2003-03-31
申请人： Kenji Inoue , Takashi Tsunoda
发明人： Kenji Inoue , Takashi Tsunoda
IPC分类号： H04N5/45
CPC分类号： H04N5/45 , H04N5/60 , H04N21/4263 , H04N21/4316 , H04N21/4341 , H04N21/4394 , H04N21/4622 , H04N21/485 , H04N21/84
摘要： A television broadcast receiving apparatus which displays one of television programs received by two tuners on a main picture screen and displays the other on a child picture screen, where one of audios of a program of the main picture screen and a program of the child picture screen is selected and outputted, and the state of an audio signal to be outputted is switched according to the audio state of the program of the child picture screen.

10. 发明申请

US20060164435A1 Display device, display control method thereof, and storage medium 失效
标题翻译：显示装置，显示控制方法和存储介质
公开(公告)号：US20060164435A1
公开(公告)日：2006-07-27
申请号：US11388984
申请日：2006-03-27
申请人： Takashi Tsunoda
发明人： Takashi Tsunoda
IPC分类号： G09G5/00
CPC分类号： G09G5/14 , G09G5/10 , G09G2320/0626 , G09G2320/0686 , G09G2340/0464
摘要： Four windows A, B, C, and D are displayed on the display screen. Of the four windows displayed on the display screen, an active window which is currently being accessed is A, and other windows, i.e., windows B, C, and D are inactive windows. The inactive windows are displayed at a lower luminance than the active window.
摘要翻译：四个窗口A，B，C和D都显示在显示屏上。在显示屏幕上显示的四个窗口中，当前正在访问的活动窗口为A，其他窗口，即窗口B，C和D为非活动窗口。非活动窗口以比活动窗口更低的亮度显示。

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