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    • 10. 发明授权
    • Metal coordination compound, luminescence device and display apparatus
    • 金属配位化合物,发光装置及显示装置
    • US06733905B2
    • 2004-05-11
    • US09995610
    • 2001-11-29
    • Takao TakiguchiShinjiro OkadaAkira TsuboyamaKoji NoguchiTakashi MoriyamaJun KamataniManabu Furugori
    • Takao TakiguchiShinjiro OkadaAkira TsuboyamaKoji NoguchiTakashi MoriyamaJun KamataniManabu Furugori
    • H05B3314
    • H01L51/0084C07F15/0033C07F15/006C07F15/0073C07F15/0086C09K11/06H01L51/0059H01L51/0062H01L51/0085H01L51/0087H01L51/5012Y10S428/917
    • A metal coordination compound suitable as an organic material for a luminescent device is represented by the following formula (1): wherein M denotes Ir, Pt, Rh or Pd; n is 2 or 3; Y denotes an alkylene group having 2-6 carbon atoms capable of including one or at least two non-neighboring methylene groups which can be replaced with —O—, —S—, —C(O)—, —C(O)—O— or —O—C(O)— and capable of including a hydrogen atom which can be replaced with a linear or branched alkyl group which has 1-10 carbon atoms and is capable of including a hydrogen atom which can be replaced with fluorine atom; and CyN denotes a cyclic group containing a nitrogen atom connected to M and capable of having a substituent selected from the group consisting of a halogen atom; a nitro group; a phenyl group; a trialkylsilyl group having 1-8 carbon atoms; and a linear or branched alkyl group having 1-20 carbon atoms capable of including one or at least two non-neighboring methylene groups which can be replaced with —O—, —S—, —C(O)—, —C(O)—O—, —O—C(O)—, —CH═CH— or —C≡C— and capable of including a hydrogen atom which can be replaced with a fluorine atom.
    • 适合作为发光装置的有机材料的金属配位化合物由下式(1)表示:其中M表示Ir,Pt,Rh或Pd; n为2或3; Y表示具有2-6个碳原子的亚烷基,能够包含一个或至少两个不相邻的亚甲基,可以被-O - , - S-,-C(O) - , - C(O) - O-或-OC(O) - 并且能够包括可被具有1-10个碳原子并且能够包含可被氟原子替代的氢原子的直链或支链烷基取代的氢原子; CyN表示含有与M连接的能够具有选自卤素原子的取代基的氮原子的环状基团, 硝基; 苯基; 具有1-8个碳原子的三烷基甲硅烷基; 和具有1-20个碳原子的直链或支链烷基,能够包含一个或至少两个不相邻的亚甲基,可以被-O - , - S - , - C(O) - , - C )-O-,-OC(O) - , - CH = CH-或-C = C-,并且能够包含可被氟原子替代的氢原子。