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    • 1. 发明授权
    • Treating solution for metal surface treatment and a method for surface treatment
    • 金属表面处理处理方法及表面处理方法
    • US07531051B2
    • 2009-05-12
    • US10480841
    • 2002-06-12
    • Takaomi NakayamaHiroyuki SatoTetsuo OotsukiTadashi MatsushitaEisaku OkadaFumiya YoshidaKatsuhiro Shiota
    • Takaomi NakayamaHiroyuki SatoTetsuo OotsukiTadashi MatsushitaEisaku OkadaFumiya YoshidaKatsuhiro Shiota
    • C23C22/06C23C22/50C23C22/53
    • C25D3/02C23C22/34C23C22/44C25D3/54C25D5/34
    • The present invention is the method for surface treatment of a metal material containing iron and/or zinc, containing component (A) and component (B); where (A) is a compound containing at least one metal element selected from the group consisting of Ti, Zr, Hf and Si, (B) is a compound containing fluorine as a supplying source of HF, wherein the ratio K=A/B between the total mole weight A of metal elements of Ti, Zr, Hf and Si in the compound of component (A) and the mole weight B which when the total fluorine atoms in the fluorine-containing compound of component (B) is converted to HF is within the range of 0.06≦K≦0.18, and the concentration of component (A) indicated by the total mole concentration of metal elements of Ti, Zr, Hf and Si is within the region of 0.05 to 100 m mol/L. To the treating solution for surface treatment, at least one compound containing at least one metal element selected from the group consisting of Ag, Al, Cu, Fe, Mn, Mg, Ni, Co and Zn can be blended. It is possible to form a surface-treated film which is superior in corrosion resistance after being coated on the surface of a metal containing iron or zinc from a solution which does not contain a harmful component to the environment.
    • 本发明是含有组分(A)和组分(B)的含铁和/或锌的金属材料的表面处理方法。 其中(A)是含有选自Ti,Zr,Hf和Si中的至少一种金属元素的化合物,(B)是含氟作为HF的供给源的化合物,其中K = A / B 在组分(A)的化合物中Ti,Zr,Hf和Si的金属元素的总摩尔量A与摩尔重量B之间,当组分(B)的含氟化合物中的总氟原子转化为 HF在0.06 <= K <= 0.18的范围内,Ti,Zr,Hf和Si的金属元素的总摩尔浓度所表示的成分(A)的浓度为0.05〜100μmol/ L. 对于用于表面处理的处理溶液,可以混合至少一种含有选自Ag,Al,Cu,Fe,Mn,Mg,Ni,Co和Zn中的至少一种金属元素的化合物。 可以在不含有有害成分的溶液与环境中涂布含铁或锌的金属的表面后,形成耐腐蚀性优异的表面处理膜。