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1. 发明申请

US20120248027A1 COMPOSITE SEMIPERMEABLE MEMBRANE AND METHOD FOR PRODUCING SAME 有权
标题翻译：复合可切割膜及其制造方法
公开(公告)号：US20120248027A1
公开(公告)日：2012-10-04
申请号：US13508704
申请日：2010-12-16
申请人： Takao Sasaki , Tomoko Mitsuhata , Kentaro Takagi , Katsufumi Oto
发明人： Takao Sasaki , Tomoko Mitsuhata , Kentaro Takagi , Katsufumi Oto
IPC分类号： B01D71/56 , B01D69/10 , C08L77/00
CPC分类号： B01D71/56 , B01D65/003 , B01D69/12 , B01D2323/12 , B01D2325/30 , C02F1/44 , C08J7/047 , C08J2477/00
摘要： A composite semipermeable membrane comprising a porous support membrane on which a separating functional polyamide layer resulting from the polycondensation reaction of polyfunctional aromatic amines with polyfunctional acid halides is formed, wherein the separating functional polyamide layer has carboxy groups, amino groups, phenolic hydroxyl groups, and azo groups, wherein XA, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a feed water contact surface of the separating functional polyamide layer (an A surface), is in the range 0.5 or less, and XB, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a permeate-side surface of the separating functional polyamide layer (a B surface), i.e., the opposite side to the A surface, is in the range of 0.5 to 1. The present invention provides a composite semipermeable membrane that achieves a balance between high solute removal properties and a high permeate flow rate and has high organic-solvent resistance, and a method for producing same.
摘要翻译：一种复合半透膜，包括多孔支撑膜，其上形成由多官能芳族胺与多官能酰卤的缩聚反应产生的分离功能聚酰胺层，其中分离官能聚酰胺层具有羧基，氨基，酚羟基和偶氮基团，其中XA，原料水接触表面（氨基的摩尔当量/（偶氮基团的摩尔当量+酚羟基的摩尔当量+氨基的摩尔当量））的比例的分离功能性聚酰胺层（A表面）的范围为0.5以下，XB为氨基（氨基的摩尔当量/（偶氮基的摩尔当量+酚的摩尔当量）羟基+氨基摩尔当量））在分离功能聚酰胺层（B面）的渗透侧表面上，即相反的在一侧的A表面，在0.5〜1的范围内。本发明提供一种复合半透膜，其在高溶质除去性和高渗透流量之间达到平衡，并且具有高的有机溶剂耐性，用于生产。

2. 发明授权

US08631946B2 Composite semipermeable membrane and method for producing same 有权
标题翻译：复合半透膜及其制造方法
公开(公告)号：US08631946B2
公开(公告)日：2014-01-21
申请号：US13508704
申请日：2010-12-16
申请人： Takao Sasaki , Tomoko Mitsuhata , Kentaro Takagi , Katsufumi Oto
发明人： Takao Sasaki , Tomoko Mitsuhata , Kentaro Takagi , Katsufumi Oto
IPC分类号： B01D39/00 , B01D39/14 , B01D29/00 , B01D29/46
CPC分类号： B01D71/56 , B01D65/003 , B01D69/12 , B01D2323/12 , B01D2325/30 , C02F1/44 , C08J7/047 , C08J2477/00
摘要： A composite semipermeable membrane comprising a porous support membrane on which a separating functional polyamide layer resulting from the polycondensation reaction of polyfunctional aromatic amines with polyfunctional acid halides is formed, wherein the separating functional polyamide layer has carboxy groups, amino groups, phenolic hydroxyl groups, and azo groups, wherein XA, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a feed water contact surface of the separating functional polyamide layer (an A surface), is in the range 0.5 or less, and XB, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a permeate-side surface of the separating functional polyamide layer (a B surface), i.e., the opposite side to the A surface, is in the range of 0.5 to 1. The present invention provides a composite semipermeable membrane that achieves a balance between high solute removal properties and a high permeate flow rate and has high organic-solvent resistance, and a method for producing same.
摘要翻译：一种复合半透膜，包括多孔支撑膜，其上形成由多官能芳族胺与多官能酰卤的缩聚反应产生的分离功能聚酰胺层，其中分离官能聚酰胺层具有羧基，氨基，酚羟基和偶氮基团，其中XA，原料水接触表面（氨基的摩尔当量/（偶氮基团的摩尔当量+酚羟基的摩尔当量+氨基的摩尔当量））的比例的分离功能性聚酰胺层（A表面）的范围为0.5以下，XB为氨基（氨基的摩尔当量/（偶氮基的摩尔当量+酚的摩尔当量）羟基+氨基摩尔当量））在分离功能聚酰胺层（B面）的渗透侧表面上，即相反的在一侧的A表面，在0.5〜1的范围内。本发明提供一种复合半透膜，其在高溶质除去性和高渗透流量之间达到平衡，并且具有高的有机溶剂耐性，用于生产。

3. 发明申请

US20130213880A1 SEPARATION MEMBRANE, SEPARATION MEMBRANE ELEMENT AND SEPARATION MEMBRANE PRODUCTION METHOD 审中-公开
标题翻译：分离膜，分离膜元件和分离膜生产方法
公开(公告)号：US20130213880A1
公开(公告)日：2013-08-22
申请号：US13881443
申请日：2011-10-21
申请人： Hiroho Hirozawa , Masakazu Koiwa , Kentaro Takagi , Yutaro Suzuki , Katsufumi Oto , Masahiro Fimura
发明人： Hiroho Hirozawa , Masakazu Koiwa , Kentaro Takagi , Yutaro Suzuki , Katsufumi Oto , Masahiro Fimura
IPC分类号： B01D71/06
CPC分类号： B01D71/06 , B01D67/0006 , B01D67/0088 , B01D69/125 , B01D71/08 , B01D71/38 , B01D71/48 , B01D71/56 , B01D71/60 , B01D2323/30 , B01D2323/40 , B01D2325/08 , B01D2325/36 , C02F1/44 , C02F1/441 , C02F1/442 , C02F1/444 , C02F2103/08
摘要： A separation membrane is provided containing hydrophilic molecules and having, as formed on at least one surface of a feed side and a permeate side thereof, a height difference of from 80 μm to 2000 μm, in which a weight of the hydrophilic molecules in a bone-dry separation membrane is from 0.1% to 40% based on a weight of the bone-dry separation membrane from which the weight of the hydrophilic molecules has been subtracted.
摘要翻译：提供了含有亲水性分子的分离膜，并且在其进料侧和渗透侧的至少一个表面上形成80μm至2000μm的高差，其中骨中的亲水性分子的重量基于亲水分子的重量从其中减去的骨干分离膜的重量，干燥分离膜为0.1％至40％。

4. 发明申请

US20060016754A1 Water-treating microbicide, water treatment method and water treatment apparatus 审中-公开
标题翻译：水处理杀微生物剂，水处理方法和水处理设备
公开(公告)号：US20060016754A1
公开(公告)日：2006-01-26
申请号：US11239577
申请日：2005-09-29
申请人： Akihiko Ito , Katsufumi Oto , Kazuya Sugita , Yoshinari Fusaoka
发明人： Akihiko Ito , Katsufumi Oto , Kazuya Sugita , Yoshinari Fusaoka
IPC分类号： B01D61/58
CPC分类号： B01D61/025 , A01N59/02 , B01D65/02 , B01D2321/16 , B01D2321/168 , C02F1/441 , C02F1/50 , C02F2103/08 , Y02A20/131 , A01N37/04 , A01N2300/00
摘要： A water-treating microbicide, containing an inorganic acid and a corrosion inhibitor, and further containing a carboxylic acid having 8 or less carbon atoms or any of alkali metal salts thereof. The present invention can provide a water-treating microbicide, water treatment method and water treatment apparatus exhibiting a high sterilization effect in a membrane separation device for seawater desalination, etc.
摘要翻译：含有无机酸和腐蚀抑制剂的水处理杀微生物剂，还含有碳原子数为8以下的羧酸或其碱金属盐。本发明可以提供一种在用于海水淡化等的膜分离装置中表现出高灭菌效果的水处理杀微生物剂，水处理方法和水处理装置。

5. 发明授权

US09387445B2 Separation membrane element 有权
标题翻译：分离膜元件
公开(公告)号：US09387445B2
公开(公告)日：2016-07-12
申请号：US13642449
申请日：2011-06-02
申请人： Masahiro Kimura , Katsufumi Oto , Kentarou Takagi , Hiroho Hirozawa , Masakazu Koiwa , Yutaro Suzuki
发明人： Masahiro Kimura , Katsufumi Oto , Kentarou Takagi , Hiroho Hirozawa , Masakazu Koiwa , Yutaro Suzuki
IPC分类号： B01D69/12 , B01D69/06
CPC分类号： B01D69/12 , B01D69/06 , B01D2313/146 , B01D2325/06
摘要： To provide a separation membrane element that is able to increase the amount of permeate fluid per unit time and also able to improve stability performance, provided is a separation membrane element, comprising a separation membrane and a permeate spacer, wherein a separation functional layer is arranged on the surface of said separation membrane and a nonwoven fabric served as a substrate is arranged on the back surface of said separation membrane, wherein said permeate spacer is arranged on the back surface side of said substrate, wherein said permeate spacer is made of a different material from said separation membrane, and a projection area ratio of said permeate spacer to said separation membrane is 0.03 to 0.80.
摘要翻译：为了提供能够增加每单位时间的渗透液的量并且还能够提高稳定性的分离膜元件，提供了分离膜元件，其包括分离膜和渗透物间隔物，其中分离功能层被布置在所述分离膜的表面上配置作为基材的非织造布，其特征在于，所述分离膜的背面配置有所述渗透隔离物，其中所述渗透隔离物由不同的来自所述分离膜的材料，并且所述渗透物间隔物与所述分离膜的投影面积比为0.03至0.80。

6. 发明授权

US07090780B2 Bactericide for use in water treatment, method for water treatment and apparatus for water treatment 失效
标题翻译：用于水处理的杀菌剂，水处理方法和水处理设备
公开(公告)号：US07090780B2
公开(公告)日：2006-08-15
申请号：US10432583
申请日：2002-04-02
申请人： Akihiko Ito , Katsufumi Oto , Kazuya Sugita , Yoshinari Fusaoka
发明人： Akihiko Ito , Katsufumi Oto , Kazuya Sugita , Yoshinari Fusaoka
IPC分类号： C02F1/68
CPC分类号： C02F9/00 , A01N25/00 , A01N59/00 , B01D61/025 , B01D61/04 , B01D65/022 , B01D2311/04 , B01D2321/168 , C02F1/001 , C02F1/20 , C02F1/44 , C02F1/441 , C02F1/50 , C02F1/66 , C02F1/76 , C02F2103/08 , C02F2201/00 , C02F2209/06 , C02F2303/08 , C02F2303/18 , C02F2303/185 , Y02A20/131 , A01N37/02 , A01N2300/00 , B01D2311/12 , B01D2311/2688
摘要： A water-treating microbicide, containing an inorganic acid and a corrosion inhibitor, and further containing a carboxylic acid having 8 or less carbon atoms or any of alkali metal salts thereof. The present invention can provide a water-treating microbicide, water treatment method and water treatment apparatus exhibiting a high sterilization effect in a membrane separation device for seawater desalination, etc.
摘要翻译：含有无机酸和腐蚀抑制剂的水处理杀微生物剂，还含有碳原子数为8以下的羧酸或其碱金属盐。本发明可以提供一种在用于海水淡化等的膜分离装置中表现出高灭菌效果的水处理杀微生物剂，水处理方法和水处理装置。

7. 发明申请

US20140224726A1 SEPARATION MEMBRANE ELEMENT 有权
标题翻译：分离膜元件
公开(公告)号：US20140224726A1
公开(公告)日：2014-08-14
申请号：US13642449
申请日：2011-06-02
申请人： Masahiro Kimura , Katsufumi Oto , Kentarou Takagi , Hiroho Hirozawa , Masakazu Koiwa , Yutaro Suzuki
发明人： Masahiro Kimura , Katsufumi Oto , Kentarou Takagi , Hiroho Hirozawa , Masakazu Koiwa , Yutaro Suzuki
IPC分类号： B01D69/12
CPC分类号： B01D69/12 , B01D69/06 , B01D2313/146 , B01D2325/06
摘要： To provide a separation membrane element that is able to increase the amount of permeate fluid per unit time and also able to improve stability performance, provided is a separation membrane element, comprising a separation membrane and a permeate spacer, wherein a separation functional layer is arranged on the surface of said separation membrane and a nonwoven fabric served as a substrate is arranged on the back surface of said separation membrane, wherein said permeate spacer is arranged on the back surface side of said substrate, wherein said permeate spacer is made of a different material from said separation membrane, and a projection area ratio of said permeate spacer to said separation membrane is 0.03 to 0.80.
摘要翻译：为了提供能够增加每单位时间的渗透液的量并且还能够提高稳定性的分离膜元件，提供了分离膜元件，其包括分离膜和渗透物间隔物，其中分离功能层被布置在所述分离膜的表面上配置作为基材的非织造布，其特征在于，所述分离膜的背面配置有所述渗透隔离物，其中所述渗透隔离物由不同的来自所述分离膜的材料，并且所述渗透物间隔物与所述分离膜的投影面积比为0.03至0.80。

8. 发明授权

US4634531A Membrane treatment method for semipermeable membranes 失效
标题翻译：半透膜的膜处理方法
公开(公告)号：US4634531A
公开(公告)日：1987-01-06
申请号：US700331
申请日：1985-02-12
申请人： Yukio Nakagawa , Katsufumi Oto , Masaru Kurihara
发明人： Yukio Nakagawa , Katsufumi Oto , Masaru Kurihara
IPC分类号： B01D61/08 , B01D65/06 , B01D67/00 , B01D71/82 , B01D13/00
CPC分类号： B01D67/0088
摘要： The present invention relates to the membrane treatment method for semipermeable membranes, that is, a method wherein it is characterized that not only remarkable improving effect of selective separation performance of semipermeable membranes is obtained but also durability of said improving effect for selective separation performance is improved by means of extremely simple and easy procedures such as said semipermeable membranes are successively brought into contact with very dilute of aqueous solutions including effective substances which are individually water-soluble in due order and for a short time, where said effective water-soluble substances form water-insoluble or very little water-soluble materials thereof fixed on the surface of said semipermeable membranes.The aforesaid remarkable effect is observed especially in the case of semipermeable membranes consisted of cross-linked polymers based of furfuryl alcohol including furfuryl alcohol as an essential monomer component, and polyamides, when, at the same time, the due combination of water-soluble amines and water-soluble aldehyde is employed as said aqueous solutions including effective water-soluble substances.
摘要翻译：本发明涉及半透膜的膜处理方法，即其特征在于，不仅可以获得半透膜的选择性分离性能显着的提高效果，而且提高选择性分离性能的提高效果的耐久性通过非常简单和容易的方法，例如所述半透膜连续地与非常稀的水溶液接触，所述水溶液包括有效物质，其中所述有效物质在适当顺序和短时间内分别是水溶性的，其中所述有效的水溶性物质形成水不溶性或非常少的水溶性材料固定在所述半透膜的表面上。观察到上述显着的效果，特别是在半透膜由包含糠醇作为必需单体组分的糠醇的交联聚合物和聚酰胺的情况下，当同时将水溶性胺并且使用水溶性醛作为包括有效的水溶性物质的所述水溶液。

9. 发明授权

US07279097B2 Composite semipermeable membrane, and production process thereof 有权
标题翻译：复合半透膜及其制备方法
公开(公告)号：US07279097B2
公开(公告)日：2007-10-09
申请号：US10865888
申请日：2004-06-14
申请人： Hiroki Tomioka , Kazuya Sugita , Katsufumi Oto
发明人： Hiroki Tomioka , Kazuya Sugita , Katsufumi Oto
IPC分类号： B01D61/02 , B01D39/16 , B01D63/00 , B01D61/08
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/02 , B01D69/125 , B01D71/56 , B01D2323/30 , C02F1/44 , C02F2101/108 , C02F2103/08 , Y02A20/131
摘要： A composite semipermeable membrane which satisfies the following relationship when seawater at 25° C. having a pH of 6.5, a boron concentration of 5 ppm and a TDS concentration of 3.5% by weight is permeated under an operation pressure of 5.5 MPa: Boron removal ratio (%)≧95−4×membrane permeation flow rate (m3/m2·day).
摘要翻译：在5.5MPa的操作压力下渗透pH值为6.5，硼浓度为5ppm，TDS浓度为3.5重量％的25℃的海水，满足以下关系的复合半透膜：硼除去率（％）> = 95〜4×膜渗透流量（m 3 /秒±2℃）。

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