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    • 2. 发明授权
    • Cold-accumulating material and cold-accumulating refrigerator using the same
    • 蓄冷材料和使用其的冷堆冰箱
    • US06334909B1
    • 2002-01-01
    • US09331157
    • 1999-06-17
    • Masami OkamuraTomohisa AraiKeisuke Hashimoto
    • Masami OkamuraTomohisa AraiKeisuke Hashimoto
    • H01F1053
    • F25B9/14C09K5/14F25B2309/003H01F1/0009H01F1/015
    • A cold accumulating material comprising magnetic substance expressed by the general formula: RCu1−xM1+x  (1) wherein R denotes at least one of rare earth element selected from the group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Er, Ho, Tm and Yb, M denotes at least one element selected from the group consisting of Ag, Au, Al, Ga, In, Ge, Sn, Sb, Si, Bi, Ni, Pd, Pt, Zn, Co, Rh, Ir, Mn, Fe, Ru, Cr, Mo, W, V, Nb, Ta, Ti, Zr and Hf, and wherein Ni and Ge are not simultaneously selected, and x in atomic ratio satisfies a relation: −0.95≧x≧0.90. According to the above structure, there can be provided a cold accumulating material and a refrigerator using the cold accumulating material capable of exhibiting a remarkable and stable refrigerating performance at an extremely low temperature for a long time.
    • 一种由以下通式表示的磁性物质的蓄冷材料:其中R表示选自Y,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy中的至少一种稀土元素 ,Er,Ho,Tm和Yb,M表示选自Ag,Au,Al,Ga,In,Ge,Sn,Sb,Si,Bi,Ni,Pd,Pt,Zn,Co中的至少一种元素 ,Rh,Ir,Mn,Fe,Ru,Cr,Mo,W,V,Nb,Ta,Ti,Zr和Hf,并且其中不同时选择Ni和Ge,原子比为x满足关系:-0.95 > = x> = 0.90。 根据上述结构,可以提供一种使用能够在极低温度下长期显现出显着且稳定的制冷性能的蓄冷材料的蓄冷材料和冷藏库。
    • 4. 发明授权
    • Cold accumulating material and cold accumulation refrigerator using the same
    • 蓄冷材料和冷堆冰箱使用相同
    • US06363727B1
    • 2002-04-02
    • US09468878
    • 1999-12-22
    • Keisuke HashimotoMasami OkamuraTomohisa Arai
    • Keisuke HashimotoMasami OkamuraTomohisa Arai
    • F25B900
    • F28D20/0056C09K5/14F25B9/14F25B2309/003Y02E60/142
    • A cold accumulating material comprises a set of particulate cold accumulating substances, pores formed between the particulate cold accumulating substances, and a binder for mutually binding the particulate cold accumulating substances, wherein a porosity of the cold accumulating material is 15-70 vol %. A median diameter of the pores existing in the cold accumulating material is preferably set to 10-300 &mgr;m. An oxygen concentration at an area ranging from a surface of the particulate cold accumulating substance to a portion having a depth of 100 angstroms (A) from the surface is preferably set to 5-80 at %. According to the above structure, there can be provided a cold accumulating material and a refrigerator using the cold accumulating material which is free from being finely pulverized, and has a high mechanical strength, and capable of exhibiting a significant refrigerating performance at low temperature range for a long period of time in a stable condition, and which can be mass-produced with a high production yield and low cost.
    • 蓄冷材料包括一组颗粒蓄冷物质,颗粒状蓄冷物质之间形成的孔和用于相互结合颗粒蓄冷物质的粘合剂,其中蓄冷材料的孔隙率为15-70体积%。 存在于蓄冷材料中的孔的中等直径优选设定为10〜300μm。 从颗粒蓄冷物质的表面到表面的深度为100埃的部分的范围内的氧浓度优选设定为5-80原子%。 根据上述结构,可以提供一种蓄冷材料和使用该蓄冷材料的冷藏库,该蓄冷材料不被细粉碎,机械强度高,能够在低温范围内表现出显着的制冷性能 长时间处于稳定状态,可以大批量生产,产量高,成本低。
    • 6. 发明授权
    • Magnet powder and method for producing the same, and bonded magnet using the same
    • 磁粉及其制造方法以及使用其的粘结磁铁
    • US06468440B1
    • 2002-10-22
    • US09646793
    • 2000-09-22
    • Shinya SakuradaTomohisa AraiMasami OkamuraKeisuke HashimotoTakahiro Hirai
    • Shinya SakuradaTomohisa AraiMasami OkamuraKeisuke HashimotoTakahiro Hirai
    • C04B3504
    • H01F1/059
    • Magnet powder has a composition expressed by (R1XR2YBZT100−X−Y−Z)100−QNQ (in formula, R1 is at least one kind of element selected from rare earth elements, R2 is at least one kind of element selected from Zr, Hf and Sc, T is at least one kind of element selected from Fe and Co, and X, Y, Z and Q are numbers satisfying 2 atomic %≦X, 0.01 atomic %≦Y, 4≦X+Y≧20 atomic %, 0≦Z≦10 atomic %, and 0.1≦Q≦20 atomic %, respectively), and TbCu7 crystal phase as a principal phase. In such magnet powder, a ratio of fine particles of which maximum diameter is 22 &mgr;m or less is 20% by weight or less. Alternatively, surface roughness of particles constituting the magnet powder is 5 &mgr;m or less in terms of maximum height Ry provided in JIS B 0601-1994. Accordingly, to such a magnet powder, excellent magnetic properties can be obtained with reproducibility.
    • 磁铁粉末具有由(R1XR2YBZT100-XYZ)100-QNQ表示的组成(式中,R1为选自稀土元素中的至少一种元素,R2为选自Zr,Hf,Sc,T中的至少一种元素 是选自Fe和Co中的至少一种元素,X,Y,Z和Q是满足2原子%<= X,0.01原子%<= Y,4 <= X + Y> = 20原子%的数, 0 <= Z <= 10原子%,分别为0.1 <= Q <= 20原子%),TbCu7晶相为主相。 在这种磁铁粉末中,最大直径为22μm以下的微粒的比例为20重量%以下。 或者,构成磁体粉末的颗粒的表面粗糙度以JIS B 0601-1994中规定的最大高度Ry计为5um以下。 因此,对于这种磁铁粉末,可以以重现性获得优异的磁特性。