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    • 2. 发明授权
    • Lactone-modified diketene (meth)acrylate compound, a process for the
preparation thereof, and a (co)polymer
    • 内酯改性的二烯丙基(甲基)丙烯酸酯化合物,其制备方法和(共)聚合物
    • US5721329A
    • 1998-02-24
    • US754288
    • 1996-11-20
    • Takaaki FujiwaTomohisa Isobe
    • Takaaki FujiwaTomohisa Isobe
    • C07C69/72C08F20/28C08F16/36
    • C08F20/28C07C69/72
    • Disclosed are a novel lactone-modified diketene (meth)acrylate compound having an active methylene group in the molecule and a process for the preparation thereof. The novel lactone-modified diketene (meth)acrylate compound of the present invention can be preferably used as resins for coatings, adhesives, inks, photosensitive materials for photographs, dispersants for pigments, agents for processing fibers, and modifiers for rubbers. Furthermore, disclosed is a novel (co)polymer which comprises the novel lactone-modified diketene (meth)acrylate compound and, optionally, a polymerizable monomer having an ethylenically unsaturated double bond. Still further, disclosed is a curable composition which comprises a lactone-modified diketene (meth)acrylate compound and at least one selected from the group consisting of a melamine, an isocyanate, and aldehyde, and an amine.
    • 公开了分子中具有活性亚甲基的新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物及其制备方法。 本发明的新型内酯改性双烯酮(甲基)丙烯酸酯化合物可以优选用作涂料,粘合剂,油墨,照相感光材料,颜料用分散剂,纤维加工剂和橡胶改性剂的树脂。 此外,公开了一种新型(共)聚合物,其包含新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物和任选的具有烯键式不饱和双键的可聚合单体。 此外,还公开了包含内酯改性的二烯酮(甲基)丙烯酸酯化合物和选自三聚氰胺,异氰酸酯和醛和胺中的至少一种的可固化组合物。
    • 3. 发明授权
    • Lactone-modified diketene(meth)acrylate compound, a process for the
preparation thereof, and a (co)polymer
    • 内酯改性的二烯丙基(甲基)丙烯酸酯化合物,其制备方法和(共)聚合物
    • US5631342A
    • 1997-05-20
    • US562113
    • 1995-11-22
    • Takaaki FujiwaTomohisa Isobe
    • Takaaki FujiwaTomohisa Isobe
    • C07C69/72C08F20/28C08G18/10
    • C08F20/28C07C69/72
    • Disclosed are a novel lactone-modified diketene (meth)acrylate compound having an active methylene group in the molecule and a process for the preparation thereof.The novel lactone-modified diketene(meth)acrylate compound of the present invention can be preferably used as resins for coatings, adhesives, inks, photosensitive materials for photographs, dispersants for pigments, agents for processing fibers, and modifiers for rubbers.Furthermore, disclosed is a novel (co)polymer which comprises the novel lactone-modified diketene(meth)acrylate compound and, optionally, a polymerizable monomer having an ethylenically unsaturated double bond.Still further, disclosed is a curable composition which comprises a lactone-modified diketene(meth)acrylate compound and at least one selected from the group consisting of a melamine, an isocyanate, and aldehyde, and an amine.
    • 公开了分子中具有活性亚甲基的新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物及其制备方法。 本发明的新型内酯改性双烯酮(甲基)丙烯酸酯化合物可以优选用作涂料,粘合剂,油墨,照相感光材料,颜料用分散剂,纤维加工剂和橡胶改性剂的树脂。 此外,公开了一种新型(共)聚合物,其包含新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物和任选的具有烯键式不饱和双键的可聚合单体。 此外,还公开了包含内酯改性的二烯酮(甲基)丙烯酸酯化合物和选自三聚氰胺,异氰酸酯和醛和胺中的至少一种的可固化组合物。
    • 7. 发明授权
    • Lactone-modified polyvinyl alcohol, a process for the preparation thereof
    • 内酯改性的聚乙烯醇,其制备方法
    • US5612412A
    • 1997-03-18
    • US476676
    • 1995-06-07
    • Kazushi WatanabeTakaaki FujiwaTomohisa IsobeHiroshi Sagane
    • Kazushi WatanabeTakaaki FujiwaTomohisa IsobeHiroshi Sagane
    • C08F8/16C08G63/00C08L87/00C08L101/00C08L29/04C08F16/06
    • C08F8/16C08G63/00C08L101/00C08L2201/04C08L87/00
    • Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof.The lactone-modified polyvinyl alcohol can be used in wide fields owing to capability of freely adjusting a water solubility such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing both properties in PVA and lactones.Furthermore, the lactone-modified polyvinyl alcohol has a property as plasticizers or softening agents, as a result, there can be provided a polymer composition having an excellent property by mixing with hydrophilic polymer or polar polymer.Still further, a blend resin composition in which a variety of resins are blended with the lactone-modified polyvinyl alcohol has an excellent permanently-anti-electrostatic property, and the resin composition having a permanently-anti-electrostatic property can be preferably employed as a variety of molded articles such as parts for electric appliances, textiles, films, etc.
    • 公开了内酯改性的聚乙烯醇及其制备方法,聚合物组合物,永久性抗静电树脂组合物,具有羟基的内酯改性树脂及其制备方法。 内酯改性的聚乙烯醇可以通过由内酯化合物改性的程度自由调节水溶性,逐渐水溶性,低水溶性和水不溶性的水溶性的能力而广泛使用,以及 由于在PVA和内酯中具有两者性质。 此外,内酯改性的聚乙烯醇具有增塑剂或软化剂的性质,结果可以提供通过与亲水性聚合物或极性聚合物混合而具有优异性能的聚合物组合物。 此外,其中各种树脂与内酯改性的聚乙烯醇共混的共混树脂组合物具有优异的永久防静电性,并且可以优选使用具有永久抗静电性的树脂组合物作为 各种模制品如电器,纺织品,薄膜等部件
    • 9. 发明授权
    • Lacton-modified polyvinyl alcohol and permanently anti-static resin
composition
    • 乳酸改性聚乙烯醇和永久性防静电树脂组合物
    • US5712334A
    • 1998-01-27
    • US774675
    • 1996-12-26
    • Kazushi WatanabeTakaaki FujiwaTomohisa IsobeHiroshi Sagane
    • Kazushi WatanabeTakaaki FujiwaTomohisa IsobeHiroshi Sagane
    • C08F8/16C08G63/00C08L87/00C08L101/00C08K3/24C08K3/30C08L29/04
    • C08F8/16C08G63/00C08L101/00C08L2201/04C08L87/00
    • Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof. The lactone-modified polyvinyl alcohol can be used in wide fields owing to the capability of freely adjusting the water solubility, such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing properties both of PVA and lactones. Furthermore, the lactone-modified polyvinyl alcohol has properties such as being plasticizers or softening agents, and as a result, there can be provided a polymer composition having excellent properties by mixing with a hydrophilic polymer or polar polymer. Still further, a blend resin composition in which a variety of resins are blended with the lactone-modified polyvinyl alcohol has an excellent permanently-anti-electrostatic property, and the resin composition having a permanently-anti-electrostatic property can be preferably employed as a variety of molded articles such as parts for electric appliances, textiles, films, etc.
    • 公开了内酯改性的聚乙烯醇及其制备方法,聚合物组合物,永久性抗静电树脂组合物,具有羟基的内酯改性树脂及其制备方法。 内酯改性的聚乙烯醇可以广泛使用,由于内酯化合物改性的程度,水溶性,逐渐水溶性,低水溶性和水不溶性自由调节水溶性的能力 ,并且由于具有PVA和内酯的性质。 此外,内酯改性的聚乙烯醇具有增塑剂,软化剂等的特性,结果可以提供通过与亲水性聚合物或极性聚合物混合而具有优异性能的聚合物组合物。 此外,其中各种树脂与内酯改性的聚乙烯醇共混的共混树脂组合物具有优异的永久防静电性,并且可以优选使用具有永久抗静电性的树脂组合物作为 各种模制品如电器,纺织品,薄膜等部件