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1. 发明授权

US06794471B2 Acrylic ester compound usage thereof 有权
标题翻译：丙烯酸酯化合物用途
公开(公告)号：US06794471B2
公开(公告)日：2004-09-21
申请号：US09960308
申请日：2001-09-24
申请人： Tadashi Ohkuma , Masao Imai , Mitsuo Nakamura , Atsuo Otsuji
发明人： Tadashi Ohkuma , Masao Imai , Mitsuo Nakamura , Atsuo Otsuji
IPC分类号： C08F2038
CPC分类号： C07D409/04 , C07D339/06 , C08F20/38 , G02B1/04 , C08L33/14
摘要： An acrylic ester compound represented by the general formula (1): wherein, R1 and R2 represent independently a hydrogen atom, an alkyl group which may have a substituent, an aromatic alkyl group which may have a substituent or an aromatic residue which may have a substituent, respectively; R3 represents a hydrogen atom or an alkyl group; A represents a divalent organic group; and X represents a sulfur atom or an oxygen atom; provided that when X is an oxygen atom, R1 represents an aromatic residue that may have a substituent, a polymerizable composition comprising the compound, and a cured article and optical components obtained by polymerizing the polymerizable composition.
摘要翻译：由通式（1）表示的丙烯酸酯化合物：其中，R 1和R 2分别独立地表示氢原子，可以具有取代基的烷基，可以具有取代基的芳香族烷基或可具有取代基的芳香族残基取代基; R3表示氢原子或烷基; A表示二价有机基团; X表示硫原子或氧原子; 条件是当X是氧原子时，R 1表示可以具有取代基的芳族残基，包含该化合物的可聚合组合物和固化物以及通过使可聚合组合物聚合而获得的光学组分。

2. 发明授权

US07307107B2 Photopolymerizable composition and use thereof 有权
标题翻译：可光聚合组合物及其用途
公开(公告)号：US07307107B2
公开(公告)日：2007-12-11
申请号：US10522532
申请日：2003-07-17
申请人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
发明人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
IPC分类号： C08F2/46 , G02B1/10 , G03B21/60
CPC分类号： G02B1/041 , C08F22/105 , C08F222/1006 , C08L33/14 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , Y10T428/10 , Y10T428/1036 , Y10T428/105 , Y10T428/1059 , Y10T428/1073 , Y10T428/1082 , C08L41/00 , H01L2924/00014 , H01L2924/00012
摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.
摘要翻译：一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。

3. 发明授权

US06835844B2 Acrylic esters and use thereof 有权
标题翻译：丙烯酸酯及其用途
公开(公告)号：US06835844B2
公开(公告)日：2004-12-28
申请号：US10332742
申请日：2003-01-13
申请人： Mitsuo Nakamura , Masao Imai , Atsuo Otsuji
发明人： Mitsuo Nakamura , Masao Imai , Atsuo Otsuji
IPC分类号： C07D33902
CPC分类号： C07D409/14 , C07D339/06 , C07D411/14 , C08F22/105 , C08F22/24 , G02B1/04 , G02B1/041 , C08L33/14 , C08L35/02
摘要： The present invention provides an acrylic ester compound represented by formula (1), a polymerizable composition containing the acrylic ester compound, and a cured product and an optical component obtained by polymerizing the polymerizable composition: (wherein “a” is an integer of 0 to 4; R1 is a directly bonded single bond, an alkylene group, an aralkylene group or arylene group which may have a substituent, or a —Y3—S—R4—S—Y4— group (R4 is an alkylene group, an aralkylene group or an arylene group; and Y3 and Y4 are each an alkylene group); R2 and R3 are each a hydrogen atom or an alkyl group; X1 and X2 are each an oxygen atom or a sulfur atom; and Y1 and Y2 are each an alkylene group which may contain an oxygen atom or a sulfur atom).
摘要翻译：本发明提供由式（1）表示的丙烯酸酯化合物，含有丙烯酸酯化合物的聚合性组合物和通过使聚合性组合物聚合而得到的固化物和光学部件（其中，“a”为0〜 4; R1是直接键合的单键，可以具有取代基的亚烷基，亚芳基或亚芳基，或-Y 3 -S-R 4 -S-Y 4 - 基（R 4是亚烷基，亚芳基或亚芳基; Y 3和Y 4各自为亚烷基）; R 2和R 3各自为氢原子或烷基; X 1和X 2各自为氧原子或硫原子，Y 1和Y 2各自为亚烷基可以含有氧原子或硫原子的基团）。

4. 发明授权

US08637633B2 Polymerizable composition, and resin and optical part using the same 有权
标题翻译：可聚合组合物，以及使用其的树脂和光学部件
公开(公告)号：US08637633B2
公开(公告)日：2014-01-28
申请号：US13611773
申请日：2012-09-12
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G75/04
CPC分类号： C08G75/06 , C08G75/04 , C08G75/08 , C08L81/02 , G02B1/04 , C08L81/00
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.
摘要翻译：一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。

5. 发明申请

US20130005934A1 Polymerizable Composition, and Resin and Optical Part Using the Same 有权
标题翻译：可聚合组合物，以及使用其的树脂和光学部件
公开(公告)号：US20130005934A1
公开(公告)日：2013-01-03
申请号：US13611773
申请日：2012-09-12
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G79/00
CPC分类号： C08G75/06 , C08G75/04 , C08G75/08 , C08L81/02 , G02B1/04 , C08L81/00
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.
摘要翻译：一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1或更大的整数; p表示1至n的整数; n表示金属原子M的价数; Y各自独立地表示无机或有机残基，其中当n-p为2或更大时， Y可以彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。

6. 发明申请

US20100298519A1 POLYMERIZABLE COMPOSITION, AND RESIN AND OPTICAL PART USING THE SAME 审中-公开
标题翻译：可聚合组合物，以及使用其的树脂和光学部件
公开(公告)号：US20100298519A1
公开(公告)日：2010-11-25
申请号：US12294683
申请日：2007-03-29
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G79/00
CPC分类号： C08G75/06 , C08G75/08 , G02B1/04 , C08L81/00
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n-p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), and a thiol compound.
摘要翻译：一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以彼此键合形成含有金属原子M的环）和硫醇化合物。

7. 发明申请

US20060003261A1 Photopolymerizable composition and use thereof 有权
标题翻译：可光聚合组合物及其用途
公开(公告)号：US20060003261A1
公开(公告)日：2006-01-05
申请号：US10522532
申请日：2003-07-17
申请人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
发明人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
IPC分类号： C08F2/46
CPC分类号： G02B1/041 , C08F22/105 , C08F222/1006 , C08L33/14 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , Y10T428/10 , Y10T428/1036 , Y10T428/105 , Y10T428/1059 , Y10T428/1073 , Y10T428/1082 , C08L41/00 , H01L2924/00014 , H01L2924/00012
摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.
摘要翻译：一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。

8. 发明申请

US20070191615A1 Polymerizable compound and use thereof 有权
标题翻译：可聚合化合物及其用途
公开(公告)号：US20070191615A1
公开(公告)日：2007-08-16
申请号：US10594497
申请日：2005-03-31
申请人： Atsuo Otsuji , Hiroshi Naruse , Mitsuo Nakamura
发明人： Atsuo Otsuji , Hiroshi Naruse , Mitsuo Nakamura
IPC分类号： C07D327/00
CPC分类号： C08G75/06 , G02B1/04
摘要： The present invention is to provide a polymerizable compound which can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7, and an optical component composed of such a resin. Disclosed is a compound represented by the general formula (3), wherein, in the formula, M represents a metal atom; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or more; p represents an integer of from 1 to n; q represents an integer of from 1 to (n-p); n represents a valence of a metal atom M; Yq each independently represent an inorganic or organic residue; and when q is 2 or more, Yq may be bonded to one another for forming a ring structure with the intermediary of a metal atom M.
摘要翻译：本发明提供一种聚合性化合物，其可以成为具有高透明度，高耐热性和塑料透镜等的光学部件所需的机械强度的树脂的原料，同时获得高折射率（nd） 1.7，以及由这种树脂构成的光学部件。公开了由通式（3）表示的化合物，其中在式中，M表示金属原子; X 1和X 2各自独立地表示硫原子或氧原子; R 1表示二价有机基团; m表示0或1以上的整数， p表示1〜n的整数， q表示1〜（n-p）的整数。 n表示金属原子M的化合价; Yq各自独立地表示无机或有机残基; 当q为2以上时，可以将Yq彼此结合形成具有金属原子M的中间环状结构。

9. 发明申请

US20100179333A1 POLYMERIZABLE COMPOUND AND USE THEREOF 有权
标题翻译：可聚合化合物及其用途
公开(公告)号：US20100179333A1
公开(公告)日：2010-07-15
申请号：US12732728
申请日：2010-03-26
申请人： Atsuo OTSUJI , Hiroshi Naruse , Mitsuo Nakamura
发明人： Atsuo OTSUJI , Hiroshi Naruse , Mitsuo Nakamura
IPC分类号： C07D331/04
CPC分类号： C08G75/06 , G02B1/04
摘要： The present invention is to provide a polymerizable compound which can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7, and an optical component composed of such a resin.Disclosed is a compound represented by the general formula (3), wherein, in the formula, M represents a metal atom; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or more; p represents an integer of from 1 to n; q represents an integer of from 1 to (n−p); n represents a valence of a metal atom M; Yq each independently represent an inorganic or organic residue; and when q is 2 or more, Yq may be bonded to one another for forming a ring structure with the intermediary of a metal atom M.
摘要翻译：本发明提供一种聚合性化合物，其可以成为具有高透明度，高耐热性和塑料透镜等的光学部件所需的机械强度的树脂的原料，同时获得高折射率（nd） 1.7，以及由这种树脂构成的光学部件。公开了由通式（3）表示的化合物，其中在式中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m表示0或1以上的整数， p表示1〜n的整数， q表示1〜（n-p）的整数。 n表示金属原子M的化合价; Yq各自独立地表示无机或有机残基; 当q为2以上时，可以将Yq彼此结合形成具有金属原子M的中间环状结构。

10. 发明申请

US20080027198A1 Metal-Containing Compound and Use Thereof 有权
标题翻译：含金属化合物及其用途
公开(公告)号：US20080027198A1
公开(公告)日：2008-01-31
申请号：US11667227
申请日：2005-11-16
申请人： Hiroshi Naruse , Atsuo Otsuji , Mitsuo Nakamura
发明人： Hiroshi Naruse , Atsuo Otsuji , Mitsuo Nakamura
IPC分类号： C08G75/04 , C07C321/00 , C08G79/00 , G02B1/04 , C08G18/38
CPC分类号： C08G18/3874 , C08G18/3855 , C08G18/3863 , C08G18/3876 , C08G18/7642 , C08G18/791 , C08G18/8125 , C08G75/00 , C08G75/04 , C08G75/045 , C08G79/00
摘要： A compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin are provided. The polymerizable composition can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7.
摘要翻译：具有两个以上硫醇基和选自分子中的金属原子的原子的化合物，含有该化合物的多硫醇组合物，含有这种多硫醇组合物的聚合性组合物，通过聚合该聚合性组合物得到的树脂和光学提供了由这种树脂获得的组分。聚合性组合物可以是获得高于1.7的高折射率（nd）的树脂的原料，其具有高透明性，良好的耐热性和诸如塑料透镜等的光学部件所需的机械强度。

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