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1. 发明授权

US08025986B2 Organic electroluminescent element and light-emitting device or display device incorporated therewith 有权
标题翻译：有机电致发光元件和与其结合的发光器件或显示器件
公开(公告)号：US08025986B2
公开(公告)日：2011-09-27
申请号：US10487584
申请日：2003-06-25
申请人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
发明人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
IPC分类号： H01J1/62 , H01L29/08 , H01L29/18
CPC分类号： H01L51/0054 , C09K11/06 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , H01L51/0052 , H01L51/006 , H01L51/0081 , H01L51/5012 , H01L51/5048 , Y10S428/917
摘要： The present invention provides an organic electroluminescent element which is superior in luminance, reliability, and thermal stability and is capable of selectively emitting light with comparative long wavelengths such as red and good color purity and a light-emitting device or display device incorporated therewith. The organic electroluminescent element consists of a glass substrate (1), an anode (2), a hole transporting layer (10), an emitting layer (11), an electron transporting layer (12), and a cathode (3), which are sequentially laminated on top of the other. The emitting layer (11) is formed from a mixture composed of at least one species of the styryl compound represented by the general formula [I] below and a material with charge transporting capability. Y—CH═CH—X General formula [I] (where X denotes an aryl group (such as phenyl group) which has a substituent group (such as cyano group and methyl group), and Y denotes a group having a skeleton of aminophenyl group or the like.)
摘要翻译：本发明提供了一种有优异的亮度，可靠性和热稳定性的有机电致发光元件，并且能够选择性地发射具有比较长的波长（例如红色和良好的色纯度）的光以及与其结合的发光器件或显示装置。有机电致发光元件由玻璃基板（1），阳极（2），空穴传输层（10），发光层（11），电子传输层（12）和阴极（3）组成，顺序层压在另一个之上。发光层（11）由由下述通式[I]表示的至少一种苯乙烯基化合物和具有电荷输送能力的材料构成的混合物形成。 Y-CH = CH-X通式[I]（其中X表示具有取代基（如氰基和甲基）的芳基（如苯基），Y表示具有氨基苯基组等。）

2. 发明申请

US20060051617A1 Organic electroluminescence device 审中-公开
标题翻译：有机电致发光器件
公开(公告)号：US20060051617A1
公开(公告)日：2006-03-09
申请号：US11262019
申请日：2005-10-27
申请人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
发明人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
IPC分类号： H05B33/14
CPC分类号： H01L51/0052 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , H01L51/0054 , H01L51/0059 , H01L51/006 , H01L51/0081 , H01L51/5012 , H01L51/5048 , H01L2251/308 , H05B33/14
摘要： The organic electroluminescence device emits a stable red light with high luminance. In the organic electroluminescence device, at least a part of an organic layer (5), (5a), or (5b) having a light emitting area includes a mixture containing at least one of the aminostyryl compound represented by the following general formula [I] or [II], Y1—CH═CH—X1—CH═CH—Y2 General formula [I]: Y3—CH═CH—X2 General formula [II]: [wherein in the general formulas, X1, X2 represents an aryl group such as anthracene, Y1, Y2, Y3 represents an aryl amino group and the like.]
摘要翻译：有机电致发光元件以高亮度发出稳定的红光。在有机电致发光元件中，具有发光面的有机层（5），（5a）或（5b）的至少一部分包含含有以下通式表示的氨基苯乙烯基化合物中的至少一种的混合物 [I]或[I

3. 发明申请

US20050064232A1 Organic field emission device and emission device 审中-公开
标题翻译：有机场致发射装置及排放装置
公开(公告)号：US20050064232A1
公开(公告)日：2005-03-24
申请号：US10240328
申请日：2002-05-31
申请人： Tadashi Ishibashi , Shinichiro Tamura , Naoyuki Ueda , Mari Ichimura , Jiro Yamada
发明人： Tadashi Ishibashi , Shinichiro Tamura , Naoyuki Ueda , Mari Ichimura , Jiro Yamada
IPC分类号： H01L51/50 , H05B33/14
CPC分类号： H01L51/5012
摘要： The present invention provides an organic electroluminescence light emitting device capable of preventing a color (hue) of light and a luminous efficiency from being varied depending on a concentration of a luminous material contained in a light emission layer and an operational condition such as an applied voltage, thereby exhibiting a high luminance, a high performance, and a stable, reliability. The light emitting device includes an anode (6), a hole transport layer (2), a light emission layer (3), an electron transport layer (4), or includes an anode (6), a hole transport layer (2), and a light emission layer (4) serving as an electron transport layer. A light emission region is formed by a mixed layer made from a luminescent material and a charge injection accelerating material. The luminescent material exhibits, in a state held as a single thin film between the anode (6) and the cathode (7), electroluminescence light emission when a DC voltage is applied thereto and has a charge transport characteristic. The charge injection accelerating material is different from the luminous material and has a charge transport characteristic capable of accelerating injection of charges in the luminescent material. The light emission region exists not only at an interface with an adjacent layer or its vicinity but also over a specific thickness region in the layer thickness direction.
摘要翻译：本发明提供一种能够防止光的颜色（色调）和发光效率根据发光层中包含的发光材料的浓度和施加电压等操作条件而变化的有机电致发光发光装置。，从而表现出高亮度，高性能和稳定的可靠性。发光器件包括阳极（6），空穴传输层（2），发光层（3），电子传输层（4），或包括阳极（6），空穴传输层（2），以及用作电子传输层的发光层（4）。发光区域由发光材料和电荷注入加速材料制成的混合层形成。发光材料在阳极（6）和阴极（7）之间作为单个薄膜保持的状态下，在施加直流电压时具有电致发光，并具有电荷传输特性。电荷注入加速材料与发光材料不同，并且具有能够加速在发光材料中注入电荷的电荷传输特性。发光区域不仅存在于与相邻层或其附近的界面处，而且存在于层厚度方向上的特定厚度区域上。

4. 发明授权

US07255935B2 Organic electroluminescent element and luminescent apparatus employing the same 失效
标题翻译：有机电致发光元件和采用其的发光装置
公开(公告)号：US07255935B2
公开(公告)日：2007-08-14
申请号：US10009021
申请日：2001-04-09
申请人： Tadashi Ishibashi , Mari Ichimura , Naoyuki Ueda , Shinichiro Tamura
发明人： Tadashi Ishibashi , Mari Ichimura , Naoyuki Ueda , Shinichiro Tamura
IPC分类号： H01J1/62
CPC分类号： H01L51/5012 , C07C211/54 , C07C211/58 , C07C217/92 , C07C255/58 , H01L27/32 , H01L51/0052 , H01L51/0059 , H01L51/006 , H01L51/0081 , H01L51/5048 , H01L2251/308 , Y10S428/917
摘要： This invention provides an organic electroluminescent element which emits red light with high color purity, high luminance, and high reliability, owing to the compound used therein which has high fluorescence yields and good thermal stability. The organic electroluminescent element which is made up of a glass substrate (1), an ITO transparent electrode (2), a hole transfer layer (6), an electron transfer layer (7), and a metal electrode (3) (which are laminated in the order mentioned), with the hole transfer layer (6) and/or the electron transfer layer (7) being formed of a mixture containing at least one species of the aminostyryl compound represented by the following general formula [I], and a hole blocking layer (30) is interposed between the hole transfer layer (6) and the electron transfer layer (7). Y1—CH═CH—X1—CH═CH—Y2General formula [I] [where, in the general formula [I] above, X1 denotes any aryl group such as a phenyl group having a substituent groups such as a nitro group, and Y1 and Y2 each is a group having an aminophenyl group in the skeleton.]
摘要翻译：本发明提供了由于其中使用的具有高荧光产率和良好的热稳定性的化合物而发出具有高纯度，高亮度和高可靠性的红光的有机电致发光元件。由玻璃基板（1），ITO透明电极（2），空穴转移层（6），电子转移层（7）和金属电极（3）构成的有机电致发光元件以所述顺序层叠），空穴转移层（6）和/或电子转移层（7）由含有至少一种由以下通式[I]表示的氨基苯乙烯基化合物的混合物形成，以及在空穴转移层（6）和电子转移层（7）之间插入空穴阻挡层（30）。 <？in-line-formula description =“In-line Formulas”end =“lead”？> Y -CH-CH-X 1 -CH-CH- 通式[I] <？in-line-formula description =“In-line Formulas”end =“tail”？> [其中，在上述通式[I]中，X < SUP> 1表示任何芳基，例如具有硝基等取代基的苯基，Y 1和Y 2各自为基团在骨架中具有氨基苯基。]

5. 发明申请

US20050158577A1 Organic electroluminescent element and lumiscent device or display including the same 有权
标题翻译：有机电致发光元件和包含其的发光器件或显示器
公开(公告)号：US20050158577A1
公开(公告)日：2005-07-21
申请号：US10487584
申请日：2003-06-25
申请人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
发明人： Tadashi Ishibashi , Mari Ichimura , Shinichiro Tamura , Naoyuki Ueda
IPC分类号： H01L51/50 , C09K11/06 , H01L51/00 , H01L51/30 , H05B33/12
CPC分类号： H01L51/0054 , C09K11/06 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , H01L51/0052 , H01L51/006 , H01L51/0081 , H01L51/5012 , H01L51/5048 , Y10S428/917
摘要： The present invention provides an organic electroluminescent element which is superior in luminance, reliability, and thermal stability and is capable of selectively emitting light with comparative long wavelengths such as red and good color purity and a light-emitting device or display device incorporated therewith. The organic electroluminescent element consists of a glass substrate (1), an anode (2), a hole transporting layer (10), an emitting layer (11), an electron transporting layer (12), and a cathode (3), which are sequentially laminated on top of the other. The emitting layer (11) is formed from a mixture composed of at least one species of the styryl compound represented by the general formula [I] below and a material with charge transporting capability. Y—CH═CH—X General formula [I](where X denotes an aryl group (such as phenyl group) which has a substituent group (such as cyano group and methyl group), and Y denotes a group having a skeleton of aminophenyl group or the like.)
摘要翻译：本发明提供了一种有优异的亮度，可靠性和热稳定性的有机电致发光元件，并且能够选择性地发射具有比较长的波长（例如红色和良好的色纯度）的光以及与其结合的发光器件或显示装置。有机电致发光元件由玻璃基板（1），阳极（2），空穴传输层（10），发光层（11），电子传输层（12）和阴极（3）组成，顺序层压在另一个之上。发光层（11）由由下述通式[I]表示的至少一种苯乙烯基化合物和具有电荷输送能力的材料构成的混合物形成。 <？in-line-formula description =“In-line Formulas”end =“lead”？> Y-CH-CH-X通用公式[I] <？in-line-formula description =“In-line Formulas”end =“尾”→（其中X表示具有取代基（例如氰基和甲基）的芳基（例如苯基），Y表示具有氨基苯基的骨架等的基团。

6. 发明授权

US06916552B2 Organic electroluminescent device and display unit 失效
标题翻译：有机电致发光器件和显示单元
公开(公告)号：US06916552B2
公开(公告)日：2005-07-12
申请号：US10068353
申请日：2002-02-06
申请人： Naoyuki Ueda , Ichinori Takada , Tetsuo Shibanuma , Mari Ichimura , Shinichiro Tamura
发明人： Naoyuki Ueda , Ichinori Takada , Tetsuo Shibanuma , Mari Ichimura , Shinichiro Tamura
IPC分类号： H01L51/50 , C09K11/06 , H01L51/00 , H01L51/30 , B32B19/00 , B32B9/00 , H01J1/62 , H01J63/04
CPC分类号： H01L51/0058 , H01L51/0059 , H01L51/5012 , H01L51/5048 , Y10S428/917 , Y10T428/10
摘要： An organic electroluminescent device capable of blue emission with a high color purity, and a display unit capable of full-color display with high color expressivity by using the organic electroluminescent device are provided. The organic electroluminescent device includes at least a hole transportation layer and a luminescent layer held between a lower electrode to become an anode and an upper electrode to become a cathode in a state of lamination in that order from the anode side. The luminescent layer is made of a spiro compound, and the hole transportation layer is made of triphenylamine tetramer. Furthermore, the display unit includes organic electroluminescent devices as blue-emitting elements arrayed for a plurality of pixels.
摘要翻译：本发明提供能够实现高色纯度的蓝色发光的有机电致发光元件，以及能够通过使用有机电致发光元件具有高色彩表现力的全色显示的显示单元。有机电致发光器件至少包括空穴传输层和保持在成为阳极的下电极之间的发光层和以从阳极侧依次层叠的状态成为阴极的上电极。发光层由螺环化合物制成，空穴输送层由三苯基胺四聚体构成。此外，显示单元包括作为用于多个像素排列的蓝色发光元件的有机电致发光器件。

7. 发明申请

US20060147750A1 Organic electroluminescence device and display apparatus 审中-公开
标题翻译：有机电致发光元件及显示装置
公开(公告)号：US20060147750A1
公开(公告)日：2006-07-06
申请号：US11257281
申请日：2005-10-24
申请人： Yasuharu Ujiie , Yoshihisa Miyabayashi , Naoyuki Ueda , Mari Ichimura , Ichinori Takada , Yukinari Sakamoto , Tadahiko Yoshinaga , Shinichiro Tamura
发明人： Yasuharu Ujiie , Yoshihisa Miyabayashi , Naoyuki Ueda , Mari Ichimura , Ichinori Takada , Yukinari Sakamoto , Tadahiko Yoshinaga , Shinichiro Tamura
IPC分类号： H01L51/54 , H05B33/14 , C09K11/06
CPC分类号： H01L51/5012 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , H01L27/32 , H01L51/006 , H05B33/14
摘要： An organic electroluminescence device having excellent life characteristics and high reliability and a display apparatus using such a device are provided. In the organic electroluminescence device having organic thin film layers provided between a lower electrode and an upper electrode and including at least a luminescent layer, any one of the organic thin film layers (particularly, the luminescent layer) contains a styrylamine derivative represented by the general formula shown below.
摘要翻译：提供了具有优异的寿命特性和高可靠性的有机电致发光器件以及使用这种器件的显示装置。在具有设置在下电极和上电极之间并且至少包含发光层的有机薄膜层的有机电致发光器件中，有机薄膜层（特别是发光层）中的任一个含有由通式公式如下。

8. 发明申请

US20060182994A1 Anthracene derivative, organic electroluminescent device, and display unit 审中-公开
标题翻译：蒽衍生物，有机电致发光器件和显示单元
公开(公告)号：US20060182994A1
公开(公告)日：2006-08-17
申请号：US11329647
申请日：2006-01-11
申请人： Yukinari Sakamoto , Yoshihisa Miyabayashi , Shinichiro Tamura , Naoyuki Ueda , Kenji Ueda , Tadahiko Yoshinaga
发明人： Yukinari Sakamoto , Yoshihisa Miyabayashi , Shinichiro Tamura , Naoyuki Ueda , Kenji Ueda , Tadahiko Yoshinaga
IPC分类号： H01L51/54 , H05B33/14 , C09K11/06 , C07C211/00
CPC分类号： C07C211/54 , C07C211/58 , C07C217/78 , C09K11/06 , C09K2211/1011 , H01L51/0052 , H01L51/0054 , H01L51/0058 , H01L51/0059 , H01L51/006 , H01L51/0067 , H01L51/0071 , H01L51/0072 , H01L51/0081 , H01L51/5012 , H01L2251/308 , H05B33/14
摘要： An anthracene derivative with general formula (1) is provided: wherein X represents a substituted or unsubstituted C6-28 arylene group, or a substituted or unsubstituted C5-21 divalent heterocyclic group; A and B each independently represent a substituted or unsubstituted C1-20 alkyl group, a substituted or unsubstituted C6-28 aryl group, or a substituted or unsubstituted C5-21 heterocyclic group, and A and B may be bonded together to form a ring; Y1 and Y2 each independently represent a hydrogen atom, a substituted or unsubstituted C1-20 alkyl group or a C1-20 alkoxy group; and Z represents a substituted or unsubstituted C6-30 aryl group atoms, a substituted or unsubstituted C5-21 heterocyclic group, a hydrogen atom, a substituted or unsubstituted C1-20 alkyl group, or a C1-20 alkoxy group.
摘要翻译：提供通式（1）的蒽衍生物：其中X表示取代或未取代的C 6-8亚芳基，或取代或未取代的C 5-21二价杂环基; A和B各自独立地表示取代或未取代的C 1-20烷基，取代或未取代的C 6-8芳基或取代或未取代的C 3-20杂环基，并且A和B可以键合在一起形成环; Y 1和Y 2各自独立地表示氢原子，取代或未取代的C 1-20烷基或C 1-20烷氧基; Z表示取代或未取代的C 6-30芳基原子，取代或未取代的C 3-20杂环基，氢原子，取代或未取代的C 1-20烷基或C 1-20烷氧基。

9. 发明授权

US06806641B2 Light-emitting device and its use 失效
标题翻译：发光装置及其用途
公开(公告)号：US06806641B2
公开(公告)日：2004-10-19
申请号：US09808317
申请日：2001-03-14
申请人： Naoyuki Ueda , Yasunori Kajima , Shinichiro Tamura
发明人： Naoyuki Ueda , Yasunori Kajima , Shinichiro Tamura
IPC分类号： H05B3302
CPC分类号： H01L51/5281 , H01L51/0059 , H01L51/0077 , H01L51/0081 , H01L51/5206 , H01L51/5215
摘要： A light-emitting device having a layer including an emission region and provided between an anode and a cathode wherein the anode has a visible light (with a wavelength of 380 to 780 nm) transmittance ranging from 35 to 75%, and the anode has a work function of 3.0 to 7.0 ev wherein the device has an improved contrast characteristic while keeping high luminance.
摘要翻译：一种发光器件，其具有包括发光区域并且设置在阳极和阴极之间的层，其中阳极具有可见光（波长380〜780nm）的透射率为35〜75％，阳极具有工作功能为3.0〜7.0ev，其中该装置具有改善的对比度特性，同时保持高亮度。

10. 发明授权

US07208868B2 Light-emitting device and its use 有权
标题翻译：发光装置及其用途
公开(公告)号：US07208868B2
公开(公告)日：2007-04-24
申请号：US10779005
申请日：2004-02-13
申请人： Naoyuki Ueda , Yasunori Kuima , Shinichiro Tamura
发明人： Naoyuki Ueda , Yasunori Kuima , Shinichiro Tamura
IPC分类号： H05B33/26
CPC分类号： H01L51/5281 , H01L51/0059 , H01L51/0077 , H01L51/0081 , H01L51/5206 , H01L51/5215 , Y10S428/917
摘要： A light-emitting device comprises a layer including an emission region and provided between an anode and a cathode wherein the anode has a visible light (with a wavelength of 380 to 780 nm) transmittance ranging from 35 to 75%, and the anode has a work function of 3.0 to 7.0 eV whereby the device has an improved contrast characteristic while keeping high luminance.
摘要翻译：发光装置包括包含发射区域并设置在阳极和阴极之间的层，其中阳极具有35〜75％的可见光（波长380〜780nm）的透射率，阳极具有工作功能为3.0至7.0eV，由此该装置在保持高亮度的同时具有改善的对比度特性。

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