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    • 4. 发明授权
    • Process for the production of block copolymer of propylene and ethylene
    • 制备丙烯和乙烯的嵌段共聚物的方法
    • US4921905A
    • 1990-05-01
    • US205484
    • 1988-06-01
    • Ichiro FujioKaneo ItoTadashi Asanuma
    • Ichiro FujioKaneo ItoTadashi Asanuma
    • C08F293/00B01J19/18C08F2/00C08F2/01C08F297/08
    • B01J19/1862C08F297/083B01J2208/00539B01J2208/00548B01J2219/00162B01J2219/00164
    • A block copolymer of propylene can be obtained with its quality controlled uniform by conducting at first continuous polymerization of propylene in a polymerization system, receiving a polymer slurry, which has been discharged continuously from the polymerization system, in a batchwise polymerization tank, feeding ethylene to the tank to conduct batchwise polymerization of ethylene and propylene. Upon discharge of a copolymer slurry formed by the preceding batchwise polymerization, at least a predetermined amount of unreacted ethylene is left over in the tank. Into the tank with the unreacted ethylene still left over therein, there are simultaneously charged the polymer slurry from the polymerization system and a deactivator. During this charging, ethylene is not supplied. The charging rate of the deactivator is controlled in such a way that the partial pressure of ethylene in the vapor phase of the tank always reaches a predetermined value at the time point of completion of reception of the polymer slurry therein.
    • 丙烯的嵌段共聚物可以通过在聚合体系中首先连续聚合丙烯而进行质量控制的均匀化,接受在间歇式聚合槽中连续从聚合体系中排出的聚合物浆料,将乙烯加入到 该罐进行乙烯和丙烯的分批聚合。 在排出通过前述分批聚合形成的共聚物浆料时,至少预定量的未反应的乙烯留在罐中。 在未反应的乙烯仍然残留在罐中的同时,从聚合体系中同时加入聚合物淤浆和失活剂。 在充电期间,不提供乙烯。 以这样的方式控制失活剂的充电速率,使得在其中的聚合物浆料的接收完成时,罐的气相中的乙烯分压总是达到预定值。