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    • 4. 发明申请
    • POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE COMPLEX AND SOLID POLYMER-TYPE FUEL CELL EACH PRODUCED USING SAME
    • 聚合物电解质组合物和聚合物电解质膜,膜电极复合物和固体聚合物型燃料电池
    • US20150295262A1
    • 2015-10-15
    • US14647781
    • 2013-11-22
    • TORAY INDUSTRIES, INC.
    • Tomoyuki KunitaDaisuke IzuharaNaoki ShimoyamaYuka FujiedaHiroaki Umeda
    • H01M8/10
    • H01M8/103C08G2650/40C08J5/2256C08J2371/10C08K5/3437C08K5/42C08L71/00C08L71/10C08L101/02H01B1/122H01M8/1004H01M8/1025H01M8/1044H01M8/1051H01M2008/1095H01M2250/20H01M2250/30H01M2300/0082Y02B90/18Y02E60/521Y02T90/32
    • The present invention provides: a polymer electrolyte composition which can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability, has excellent practicality, and can be produced using a nitrogen-containing additive, wherein the nitrogen-containing additive can prevent the elution of the additive under a strongly acidic atmosphere during the operation of a fuel cell, has excellent chemical stability so as to tolerate a strongly acidic atmosphere, can be dissolved in various general-purpose organic solvents, has superior processability, can be mixed with an ionic-group-containing polymer, can prevent the occurrence of phase separation during the formation of a film, and can prevent the formation of an island-in-sea-like phase separation structure or the occurrence of bleeding out during the formation of a film; and a polymer electrolyte membrane, a membrane electrode assembly and a polymer electrolyte fuel cell, each of which is produced using the polymer electrolyte composition. The polymer electrolyte composition according to the present invention comprises at least an ionic-group-containing polymer (A) and a nitrogen-containing additive (B), said polymer electrolyte composition being characterized in that the nitrogen-containing additive (B) is represented by a specific structural formula.
    • 本发明提供:在微加湿条件下能够获得优异的质子传导性,优异的机械强度和优异的物理耐久性的高分子电解质组合物具有优异的实用性,可以使用含氮添加剂制造含氮添加剂 在燃料电池运行过程中阻止添加剂在强酸性气氛下的溶出,具有优异的化学稳定性,耐受强酸性气氛,可溶于各种通用有机溶剂,具有优异的加工性能,可混合 具有含离子基团的聚合物可以防止在膜形成期间发生相分离,并且可以防止海岛状相分离结构的形成或在形成期间出现渗出的情况 一个电影; 以及使用高分子电解质组合物制造的高分子电解质膜,膜电极接合体和固体高分子型燃料电池。 本发明的高分子电解质组合物至少含有含离子性基团的聚合物(A)和含氮添加剂(B),所述高分子电解质组合物的特征在于,含氮添加剂(B) 通过具体的结构式。