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    • 2. 发明授权
    • Process for class viiib metals ore reduction
    • US3833353A
    • 1974-09-03
    • US40326173
    • 1973-10-03
    • TAYLOR P
    • TAYLOR P
    • C22B11/00C21B
    • C22B11/00Y02P10/214
    • The class VIIIB metals are generally found clustered and bound together within common ores, and most often include gold, silver, and copper. One such ore is of the Cobalt series comprised of the metals cobalt, nickel, silver, copper, and iron. Another one is of the Platinum series comprised of the metals platinum, nickel, copper, and iron. These are known respectively as Smaltite ore, and Pentlandite ore. Other platinum ore is found as alluvial deposits in regions of known noble metal-bearing formations such as the Ural Mountains, Colombia, and the Transvaal. They are sometimes referred to as ''''black sand'''' deposits and are mined by placer operations. This group includes platinum, palladium, rhodium, ruthenium, iridium, osmium, and usually with gold and silver. Much of it''s noble metal may be recovered by such means as by washing with water to produce particles and nuggets. However, much of this ore as well as all other of the types above mentioned are so bound with oxygen and gange material chemically that such simple recovery methods are rendered ineffective, and indeed, oftentimes requires definite chemical reactions for their reductions. Such material is usually the resultant ''''tailing'''' product from hydraulic concentration and benefication processes. Consequently huge amounts of such material cannot be so simply processed, as by washing, for the economic recovery of the boundup metals. The instant process operates for the reduction of the metals within all such ores. The process requires such material to be in finely divided form and concentrated for economic advantage. It is then admixed with a certain liquid formula solution within a suitable reduction container, followed by additions of finely divided limestone and stirred for homogeneous uniformity while chemical reactions go to completion. The liquid formula is comprised of phosphoric acid, zinc oxide, and an alkylphenol polyglycol ether type sulfated surfactant. The mixture within the container is then heated by endothermic heat sources until the ore has reacted fully chemically with the liquid formula solution. Gases are expelled until the ore reaches a dry, solid state. The reduced matrix material is then pulverized for convenient entry into a smelting medium, and there smelted to produce the metals as either ingot of individual metals or in matte-alloyed forms. The smelting amounts to only a melting out of the metals from the matrix material, such metals being already chemically reduced and released by the foregoing reaction with the reduction components under heating. The smelted metal forms into either type according to selective heat applications to the smelting medium as the operator may choose. The combination of reduction ingredients are effective, therefore, in liberating the metals from chemically-bound oxygen and gange impurities upon admixing with the ore, heating the mixture, and smelting the resulting residue matrix material to the metals.
    • 5. 发明授权
    • Process for lanthanide and actinide metals ore reduction
    • US3791815A
    • 1974-02-12
    • US3791815D
    • 1972-12-13
    • TAYLOR P
    • TAYLOR P
    • C22B59/00C22B60/02C22B60/00
    • C22B60/0213C22B59/00C22B60/0243Y02P10/214
    • The Lanthanide and Actinide series of metals are found mainly in the three ores Monazite, Carnotite, and Uraninite or Pitchblende. In winning these metals from the ores usually the oxides are separated either seperately or in groups first, then the oxides are reduced either separately or in groups, thereby providing individual metals, or an alloy known as a commercially designated Misch metal. Such separations and reductions apply to only the ores as found natural and does not include the manmade nuclear transformation elements of the series. The separations and reductions both from the ores, the oxides, and the Misch metal are quite complicated, cumbersome, costly, and at times are inefficient. By application of the instant process such ores and oxides may be reduced in either of those forms in a more simple manner to either the individual metals or the alloy. The alloy metal may then be subsequently separated into individual metals at great savings in operations and cost in comparison to that which is known. The ores or oxides are subjected to a certain liquid formula solution, such material being finely pulverized, by mixing together within a suitable container, followed by additions of pulverized limestone and stirred while the reaction goes to completion. The liquid formula is comprised of phosphoric acid, zinc oxide, and an alkylphenol polyglycol ether type sulfated surfactant. The mixture is heated within the container by an endothermic heat source until the ore has been digested by the liquid formula solution with the consequent release of gases and expanded in volume to a dry, spongelike state. In this condition the material is considered as being ''''fixed'''' for smelting. Upon smelting the material releases the metal which forms into ingot-like masses at the bottom of the furnace as reduced and smelted metal. The combination of reduction ingredients are effective, therefore, in liberating the metals from chemically bound oxygen and other impurities upon heating the mixture and then smelting the residue.