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1. 发明申请

US20130131229A1 PROCESS FOR PREPARING GRAFT POLYMERS WITHOUT INITIATOR AND WITHOUT SOLVENT AND BITUMEN/POLYMER COMPOSITIONS COMPRISING SAID GRAFT POLYMERS 有权
标题翻译：制备聚合物的方法，不含发光体，无溶剂和含有聚合物的双酚/聚合物组合物
公开(公告)号：US20130131229A1
公开(公告)日：2013-05-23
申请号：US13809546
申请日：2011-07-08
申请人： Sylvia Harders , Romuald Botel , IIias Iliopoulos , Ludwik Leibler , Ornella Annabelle Zovi
发明人： Sylvia Harders , Romuald Botel , IIias Iliopoulos , Ludwik Leibler , Ornella Annabelle Zovi
IPC分类号： C08F8/34
CPC分类号： C08L95/00 , C08C19/20 , C08F8/34 , C08F2800/20 , C08J3/24 , C08J2351/04 , C08K5/37 , C08L2555/22 , C08L2555/80 , C08L2555/84 , C08L51/04 , C08F297/04
摘要： A process for preparing graft polymers from a polymer is based on conjugated diene units and a graft which is a thiol derivative. The process has an absence of solvent and any radical initiator. The graft polymer can be advantageously be used as additive for a bitumen/polymer composition and in particular permits thermoreversible cross-linking.
摘要翻译：从聚合物制备接枝聚合物的方法是基于共轭二烯单元和作为硫醇衍生物的接枝物。该方法没有溶剂和任何自由基引发剂。接枝聚合物可以有利地用作沥青/聚合物组合物的添加剂，特别是允许热可逆交联。

2. 发明授权

US08883930B2 Process for preparing graft polymers without initiator and without solvent and bitumen/polymer compositions comprising said graft polymers 有权
标题翻译：制备不含引发剂且不含溶剂的接枝聚合物和包含所述接枝聚合物的沥青/聚合物组合物的方法
公开(公告)号：US08883930B2
公开(公告)日：2014-11-11
申请号：US13809546
申请日：2011-07-08
申请人： Sylvia Harders , Romuald Botel , Ilias Iliopoulos , Ludwik Leibler , Ornella Annabelle Zovi
发明人： Sylvia Harders , Romuald Botel , Ilias Iliopoulos , Ludwik Leibler , Ornella Annabelle Zovi
IPC分类号： C08F8/34 , C08C19/20 , C08L95/00 , C08J3/24 , C08K5/37
CPC分类号： C08L95/00 , C08C19/20 , C08F8/34 , C08F2800/20 , C08J3/24 , C08J2351/04 , C08K5/37 , C08L2555/22 , C08L2555/80 , C08L2555/84 , C08L51/04 , C08F297/04
摘要： A process for preparing graft polymers from a polymer is based on conjugated diene units and a graft which is a thiol derivative. The process has an absence of solvent and any radical initiator. The graft polymer can be advantageously be used as additive for a bitumen/polymer composition and in particular permits thermoreversible cross-linking.
摘要翻译：从聚合物制备接枝聚合物的方法是基于共轭二烯单元和作为硫醇衍生物的接枝物。该方法没有溶剂和任何自由基引发剂。接枝聚合物可以有利地用作沥青/聚合物组合物的添加剂，特别是允许热可逆交联。

3. 发明申请

US20130036941A1 USE OF ORGANOGELATOR MOLECULES IN BITUMINOUS COMPOSITIONS TO IMPROVE THE RESISTANCE OF SAME TO CHEMICAL STRESS 有权
标题翻译：在组合物中使用有机元素分子，以提高其对化学应力的抵抗力
公开(公告)号：US20130036941A1
公开(公告)日：2013-02-14
申请号：US13643245
申请日：2011-04-29
申请人： Sylvia Harders , Laurence Lapalu , Romuald Botel
发明人： Sylvia Harders , Laurence Lapalu , Romuald Botel
IPC分类号： C08L95/00 , C09D195/00 , C08L9/06
CPC分类号： C04B26/26 , C04B2103/0062 , C04B2111/0075 , C04B2111/20 , C08L95/00 , C08L2555/22 , C08L2555/80 , C04B24/085 , C04B24/2676 , C04B24/124 , C04B24/126 , C08L83/00
摘要： The use in a bituminous composition of an organogelator molecule of the following general formula (I) is disclosed below: where: A is a hydrocarbon group which can be straight or branched, saturated or unstaurated, acyclic, cyclic or polycyclic, having 3 to 92 carbon atoms, resulting from the polymerization of lateral chains of at least one unsaturated fatty acid, X is an NH group or an oxygen atom O, R1 is a group chosen from: a straight or branched hydrocarbon group with 2 to 40 carbon atoms, optionally including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise, R2 is a group selected among: a hydrogen atom, a straight or branched hydrocarbon group with 1 to 40 carbon atoms, including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise; m and n are, separately from one another, an integer ranging from 1 to 4, p is an integer ranging from 0 to 4, q is an integer ranging from 1 to 4 or a combination of the values, Y is a group including a hydrogen bond donor such as the NH grouping and a hydrogen bond acceptor such as the C═O grouping, to improve the resistance thereof to aggressive chemical agents, in particular to hydrocarbons such as gasolines, diesels and/or kerosenes.
摘要翻译：在下列通式（I）的有机凝胶分子的沥青组合物中的用途如下：其中：A是可以是直链或支链，饱和或未取代的无环，环状或多环的烃基，其具有3至92个由至少一种不饱和脂肪酸的侧链聚合得到的碳原子，X是NH基或氧原子O，R 1是选自：具有2至40个碳原子的直链或支链烃基，任选地包括一个或多个杂原子，并且任选地包括一个或多个不饱和基团，或芳族基团，被取代的或另外的，R 2是选自：氢原子，具有1至40个碳原子的直链或支链烃基，包括一个或多个杂原子和任选地包括一个或多个不饱和基团，或芳族基团，被取代或以其它方式; m和n彼此分开，为1至4的整数，p为0至4的整数，q为1至4的整数或该组合，Y为包括氢键供体如NH基团和氢键受体如C = O基团，以改善其对腐蚀性化学试剂，特别是烃类如汽油，柴油和/或煤油的耐受性。

4. 发明申请

US20130237646A1 THERMOREVERSIBLY CROSS-LINKED GRAFT POLYMERS 审中-公开
标题翻译：热熔交联聚合物
公开(公告)号：US20130237646A1
公开(公告)日：2013-09-12
申请号：US13884831
申请日：2011-11-08
申请人： Sylvia Harders , Ludwik Leibler , Ilias Iliopoulos , Julie Prevost
发明人： Sylvia Harders , Ludwik Leibler , Ilias Iliopoulos , Julie Prevost
IPC分类号： C08F36/06 , C08L95/00 , C08F8/34
CPC分类号： C08F36/06 , C08C19/20 , C08C19/22 , C08C19/30 , C08F8/34 , C08L9/00 , C08L53/025 , C08L95/00 , E01C7/18 , C08L51/08
摘要： A graft polymer PG includes a polymer backbone P and at least one side graft G linked to the polymer backbone, the graft G having the general formula (1): in which R1 and R2 represent, separately from one another, straight or branched, unsaturated or saturated hydrocarbon groups, such that the total number of carbon atoms in groups R1 and R2 is between 2 and 110; X represents an amide, amino-acid, urea or urethane function, the graft G being linked to the polymer backbone P via the sulphur atom. The graft polymer PG is a polymer that allows thermoreversible cross-linking and can be used in many fields such as coatings, paints, thermoplastics, adhesives, lubricants, fuels, inks, cements, construction materials, rubbers and bitumens. The graft polymer PG can be used in particular for thermoreversibly cross-linking bitumen/polymer compositions and thus for reducing coating, spreading and/or compaction temperatures during the production of bituminous coated materials.
摘要翻译：接枝聚合物PG包括聚合物骨架P和连接到聚合物主链的至少一个侧接枝G，具有通式（1）的接枝G：其中R 1和R 2彼此分别表示直链或支链不饱和的或饱和烃基，使得基团R1和R2中的碳原子总数在2和110之间; X表示酰胺，氨基酸，脲或氨基甲酸酯官能团，接枝G通过硫原子与聚合物骨架P连接。接枝聚合物PG是允许热可逆交联并可用于许多领域的聚合物，例如涂料，油漆，热塑性塑料，粘合剂，润滑剂，燃料，油墨，水泥，建筑材料，橡胶和沥青。接枝聚合物PG特别可用于热可逆地交联沥青/聚合物组合物，因此用于在生产沥青涂层材料期间减少涂层，铺展和/或压实温度。

5. 发明授权

US09150454B2 Use of organogelator molecules in bituminous compositions to improve the resistance of same to chemical stress 有权
标题翻译：在沥青组合物中使用有机凝胶分子以改善与化学应力相同的电阻
公开(公告)号：US09150454B2
公开(公告)日：2015-10-06
申请号：US13643245
申请日：2011-04-29
申请人： Sylvia Harders , Laurence Lapalu , Romuald Botel
发明人： Sylvia Harders , Laurence Lapalu , Romuald Botel
IPC分类号： C08L95/00 , C04B26/26 , C04B103/00 , C04B111/00 , C04B111/20
CPC分类号： C04B26/26 , C04B2103/0062 , C04B2111/0075 , C04B2111/20 , C08L95/00 , C08L2555/22 , C08L2555/80 , C04B24/085 , C04B24/2676 , C04B24/124 , C04B24/126 , C08L83/00
摘要： The use in a bituminous composition of an organogelator molecule of the following general formula (I) is disclosed below: where: A is a hydrocarbon group which can be straight or branched, saturated or unsaturated, acyclic, cyclic or polycyclic, having 3 to 92 carbon atoms, resulting from the polymerization of lateral chains of at least one unsaturated fatty acid, X is an NH group or an oxygen atom O, R1 is a group chosen from: a straight or branched hydrocarbon group with 2 to 40 carbon atoms, optionally including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise, R2 is a group selected among: a hydrogen atom, a straight or branched hydrocarbon group with 1 to 40 carbon atoms, including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise; m and n are, separately from one another, an integer ranging from 1 to 4, p is an integer ranging from 0 to 4, q is an integer ranging from 1 to 4 or a combination of the values, Y is a group including a hydrogen bond donor such as the NH grouping and a hydrogen bond acceptor such as the C═O grouping, to improve the resistance thereof to aggressive chemical agents, in particular to hydrocarbons such as gasolines, diesels and/or kerosenes.
摘要翻译：在下列通式（I）的有机凝胶分子的沥青组合物中的用途如下：其中：A是可以是直链或支链，饱和或不饱和，无环，环状或多环的烃基，其具有3至92 由至少一种不饱和脂肪酸的侧链聚合得到的碳原子，X是NH基或氧原子O，R 1是选自：具有2至40个碳原子的直链或支链烃基，任选地包括一个或多个杂原子，并且任选地包括一个或多个不饱和基团，或芳族基团，被取代的或另外的，R 2是选自：氢原子，具有1至40个碳原子的直链或支链烃基，包括一个或多个杂原子和任选地包括一个或多个不饱和基团，或芳族基团，被取代或以其它方式; m和n彼此分开，为1至4的整数，p为0至4的整数，q为1至4的整数或该组合，Y为包括氢键供体如NH基团和氢键受体如C = O基团，以改善其对腐蚀性化学试剂，特别是烃类如汽油，柴油和/或煤油的耐受性。

6. 发明授权

US08772381B2 Use of waxes in a cross-linked bitumen/polymer composition for improving its resistance to chemical attack and cross-linked bitumen/ polymer composition comprising said waxes 有权
标题翻译：在交联沥青/聚合物组合物中使用蜡以改善其对化学侵蚀的抗性和包含所述蜡的交联沥青/聚合物组合物
公开(公告)号：US08772381B2
公开(公告)日：2014-07-08
申请号：US13504876
申请日：2010-10-29
申请人： Sylvia Harders , Julien Chaminand
发明人： Sylvia Harders , Julien Chaminand
IPC分类号： C08L95/00
CPC分类号： C08L95/00 , C08L91/06 , C08L2666/02
摘要： The present disclosure relates to the use of 2 to 6% by mass of Fischer-Tropsch waxes in a cross-linked bitumen/polymer composition for improving the cross-linked bitumen/polymer composition's resistance to aggressive chemical agents.
摘要翻译：本公开涉及在交联沥青/聚合物组合物中使用2〜6质量％的费 - 托蜡用于改善交联沥青/聚合物组合物对侵蚀性化学试剂的抗性。

7. 发明申请

US20120214912A1 USE OF FATTY ACID DERIVATIVES IN BITUMINOUS COMPOSITIONS FOR IMPROVING THEIR RESISTANCE TO CHEMICAL ATTACK AND BITUMINOUS COMPOSITIONS COMPRISING SAID DERIVATIVES 审中-公开
标题翻译：在化学组合物中使用脂肪酸衍生物以改善其对化学品的抵抗力和包含上述衍生物的含白色组合物
公开(公告)号：US20120214912A1
公开(公告)日：2012-08-23
申请号：US13504829
申请日：2010-10-29
申请人： Sylvia Harders , Julien Chaminand
发明人： Sylvia Harders , Julien Chaminand
IPC分类号： C09D195/00
CPC分类号： C08L95/00 , C08K3/06 , C08K5/20 , C08L53/02 , C08L91/06 , C08L2666/02
摘要： The present disclosure relates to the use of at least one fatty acid derivative of general formula (1) in a bituminous composition for improving their resistance to aggressive chemical agents, and in particular to hydrocarbons, such as gasolines, gas oils and/or kerosenes, general formula (1) being: with, when n is equal to 0, an X group chosen from the NH2 or NHR3 groups and when n is equal to 1, an X group which represents the —NH—(CH2)m—NH— group, the R1, R2, R3 groups being, independently of each other, saturated or unsaturated, linear or branched hydrocarbon groups with 8 to 24 carbon atoms, m being between 1 and 8.
摘要翻译：本公开内容涉及在沥青组合物中使用至少一种通式（1）的脂肪酸衍生物来改善其对腐蚀性化学试剂的抵抗力，特别是烃类，例如汽油，瓦斯油和/或煤油，通式（1）为：当n等于0时，选自NH 2或NHR 3基团的X基团，当n等于1时，表示-NH-（CH 2）m -NH- 基团，R 1，R 2，R 3基团彼此独立地为具有8至24个碳原子的饱和或不饱和的直链或支链烃基，m为1至8。

8. 发明授权

US09127162B2 Use of organogelator derivatives in bituminous compositions to improve the resistance of same to chemical stress 有权
标题翻译：在沥青组合物中使用有机凝胶衍生物以改善与化学应力相同的电阻
公开(公告)号：US09127162B2
公开(公告)日：2015-09-08
申请号：US13643237
申请日：2011-04-29
申请人： Sylvia Harders , Laurence Lapalu , Julien Chaminand , Régis Vincent
发明人： Sylvia Harders , Laurence Lapalu , Julien Chaminand , Régis Vincent
IPC分类号： C08L95/00 , C09D195/00 , C08K5/1575 , C08K5/20
CPC分类号： C08L95/00 , C08K5/1575 , C08K5/20 , C08L2555/50 , C08L2666/66
摘要： The disclosure includes the use in a bituminous composition of an organogelator derivative which has a molar mass no higher than 2,000 g/mol and includes at least one hydrogen bonds donor D, at least one hydrogen bonds acceptor A and at least one compatibilizer agent C in the bitumen, the compatibilizer agent C including a group selected among: at least one straight hydrocarbon chain including at least 4 carbon atoms, or at least one aliphatic cycle of 3 to 8 atoms, or at least one aromatic cycle, or at least one aliphatic or partly aromatic, or even entirely aromatic, condensed polycyclic system, each cycle including 5 or 6 atoms taken alone or as a mixture, to improve the resistance to aggressive chemical agents, in particular to hydrocarbons, such as gasolines, diesels and/or kerosenes, excluding N,N′-ethylene bis(stearamide) and excluding fatty-chains polyamines obtained by reacting polyalkylene fatty-chains polyamines of general formula (I) R—NH—(CH2—CH2—CH2—NH)n—H wherein R is a linear hydrocarbon chain, saturated and/or unsaturated, of 8 to 22 carbon atoms, n being an integer from 1 to 5, with formic acid.
摘要翻译：本公开内容包括在沥青组合物中使用摩尔质量不高于2,000g / mol的有机凝胶衍生物，并且包括至少一个氢键供体D，至少一个氢键受体A和至少一种增容剂C 沥青，增容剂C，其包括选自以下的基团：至少一个包含至少4个碳原子的直链烃链，或至少一个3至8个原子的至少一个脂肪族环，或至少一个芳族环，或至少一个脂族或部分芳族的或甚至完全芳香的稠合多环体系，每个循环包括单独的或作为混合物的5或6个原子，以改善对侵蚀性化学试剂，特别是烃，如汽油，柴油和/或煤油的耐受性不包括N，N'-亚乙基双（硬脂酰胺），不包括通过使通式（I）的聚亚烷基脂肪链多胺R-NH-（CH2-CH2-CH2-NH）n-Hw 本文R是具有8至22个碳原子的饱和和/或不饱和的直链烃链，n是1至5的整数，与甲酸。

9. 发明申请

US20140024735A1 METHOD FOR PREPARING CROSS-LINKED BITUMEN/POLYMER COMPOSITIONS BY MEANS OF ELECTROMAGNETIC WAVE RADIATION 审中-公开
标题翻译：通过电磁波辐射制备交联的双胺/聚合物组合物的方法
公开(公告)号：US20140024735A1
公开(公告)日：2014-01-23
申请号：US13983927
申请日：2012-02-08
申请人： Sylvia Harders , Julien Chaminand , David Vuillot , Jean-François Rochas
发明人： Sylvia Harders , Julien Chaminand , David Vuillot , Jean-François Rochas
IPC分类号： C08L95/00
CPC分类号： C08L95/00 , C08J3/246 , C08J3/28 , C08J2395/00 , C08L2555/22 , C08L2555/52 , C08L2555/84 , C08L25/10 , C08L25/16
摘要： The disclosure includes a process for preparing cross-linked bitumen/polymer compositions without adding a cross-linking agent, the process comprising contacting at least one bitumen with at least one polymer, and subjecting a mixture of the bitumen and the polymer to electromagnetic wave radiation in a high frequency and/or microwave range.
摘要翻译：本公开内容包括在不添加交联剂的情况下制备交联的沥青/聚合物组合物的方法，该方法包括使至少一种沥青与至少一种聚合物接触，并将沥青与聚合物的混合物接触电磁波辐射在高频和/或微波范围内。

10. 发明授权

US08748517B2 Stock solutions having high concentrations of polymers based on oils of plant and/or animal origin for the preparation of bitumen/polymer compositions 有权
标题翻译：具有基于植物和/或动物来源的油的高浓度聚合物的储备溶液用于制备沥青/聚合物组合物
公开(公告)号：US08748517B2
公开(公告)日：2014-06-10
申请号：US13501920
申请日：2010-10-14
申请人： Sylvia Harders , Guillaume Dulac
发明人： Sylvia Harders , Guillaume Dulac
IPC分类号： C08L95/00
CPC分类号： C08J3/226 , C08J2395/00 , C08J2491/00 , C08K3/06 , C08K5/101 , C08K5/103 , C08K2201/014 , C08L53/02 , C08L91/00 , C08L95/00 , C08L2666/02 , C08L91/06 , C08L2666/06
摘要： The present disclosure relates to a mother solution free from oil of petroleum origin including at least one oil of vegetable and/or animal origin, from 20% to 50% by mass of polymer, with respect to the mass of the mother solution, with or without at least one cross-linking agent, the oil of vegetable and/or animal origin being acid, with an acid value measured according to the standard NF EN ISO 660 including between 50 and 300 mg KOH/g. This mother solution with a very high concentration of polymer is stable and does not gel and can therefore be diluted and used for preparing cross-linked bitumen/polymer compositions, then bituminous mixes.
摘要翻译：本公开内容涉及一种无石油原油的母溶液，包括至少一种植物和/或动物来源的油，相对于母液的质量为20〜50质量％没有至少一种交联剂，植物和/或动物来源的油是酸，具有根据标准NF EN ISO 660测量的酸值，包括50-300mg KOH / g。具有非常高浓度聚合物的母溶液是稳定的并且不凝胶，因此可以稀释并用于制备交联沥青/聚合物组合物，然后沥青混合物。

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