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1. 发明申请

US20050060815A1 Novel heteroaromatic trinuclear black direct dyes 审中-公开
标题翻译：新型杂芳族三核黑色直接染料
公开(公告)号：US20050060815A1
公开(公告)日：2005-03-24
申请号：US10678635
申请日：2003-10-06
申请人： Sylvain Kravtchenko , Alain Lagrange , Herve David , Andrew Greaves , Nicole Bonaventure , Laurent Vidal
发明人： Sylvain Kravtchenko , Alain Lagrange , Herve David , Andrew Greaves , Nicole Bonaventure , Laurent Vidal
IPC分类号： A61K8/49 , A61Q5/06 , A61K7/13
CPC分类号： A61Q5/065 , A61K8/4926 , A61K8/494 , A61K8/4953
摘要： The invention relates to novel heteroaromatic trinuclear direct dyes, to dye compositions containing these dyes and to the process for dyeing keratin fibres using them. In particular, the invention relates to heteroaromatic trinuclear direct dyes comprising a pyridine nucleus. These novel dyes make it possible to obtain black shades that show good fastness and good stability in the dye compositions.
摘要翻译：本发明涉及新颖的杂芳族三核直接染料，含有这些染料的染料组合物和使用它们染色角蛋白纤维的方法。特别地，本发明涉及包含吡啶核的杂芳族三核直接染料。这些新型染料使得可以获得在染料组合物中显示出良好牢度和良好稳定性的黑色色调。

2. 发明申请

US20060096043A1 Dicationic bis-hydrazone compound, dye composition comprising at least one such compound, implementation process therefor and uses thereof 失效
标题翻译：二元双腙化合物，包含至少一种这样的化合物的染料组合物，其实施方法及其用途
公开(公告)号：US20060096043A1
公开(公告)日：2006-05-11
申请号：US11249370
申请日：2005-10-14
申请人： Herve David , Andrew Greaves , Leila Hercouet , Alain Lagrange
发明人： Herve David , Andrew Greaves , Leila Hercouet , Alain Lagrange
IPC分类号： A61K8/49
CPC分类号： A61K8/4946 , A61K8/494 , A61Q5/065 , A61Q5/10
摘要： The present disclosure relates to a novel family of dicationic bis-hydrazone compounds that may be used as direct dyes, and to a dye composition for dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising, in a suitable dyeing medium, at least one such compound. Also disclosed are dyeing processes implementing this composition and uses thereof.
摘要翻译：本公开涉及可用作直接染料的新型双阳离子双腙化合物系列，以及用于染色角蛋白纤维的染料组合物，例如人角蛋白纤维如毛发，其包含在合适的染色介质，至少一种这样的化合物。还公开了实施该组合物和用途的染色方法。

3. 发明申请

US20060021160A1 Polycationic azo compounds for dyeing keratin fibers, dye compositions containing the same, and methods for making such compounds 失效
标题翻译：用于染色角蛋白纤维的聚阳离子偶氮化合物，含有它们的染料组合物以及制备这些化合物的方法
公开(公告)号：US20060021160A1
公开(公告)日：2006-02-02
申请号：US11139626
申请日：2005-05-31
申请人： Alain Lagrange , Herve David , Andrew Greaves
发明人： Alain Lagrange , Herve David , Andrew Greaves
IPC分类号： A61K8/00
CPC分类号： C09B43/00 , A61K8/4926 , A61K8/4946 , A61Q5/065 , A61Q5/10
摘要： The present disclosure relates to compounds used as direct dyes, and dyeing compositions comprising such compounds. The disclosed compounds have the formula A-L-B, wherein A and B are chosen from arylazoimidazolium coloring functional groups, and L is a linker comprising at least one cationic group C. The disclosure also relates methods of using such compositions for coloring keratin fibers, such as the hair.
摘要翻译：本公开涉及用作直接染料的化合物和包含这些化合物的染色组合物。所公开的化合物具有式ALB，其中A和B选自芳基偶氮咪唑鎓着色官能团，L是包含至少一个阳离子基团C的接头。本公开还涉及使用这种组合物来着色角蛋白纤维的方法，例如头发。

4. 发明申请

US20090300856A1 SPECIFIC MONOCATIONIC MONOCHROMOPHORIC COMPOUNDS OF HYDRAZONE TYPE COMPRISING A 2-, 4-PYRIDINIUM OR 2-, 4-QUINOLINIUM UNIT, SYNTHESIS THEREOF, DYE COMPOSITIONS CONTAINING THEM, AND METHOD FOR DYEING KERATIN FIBRES 失效
标题翻译：包含2-，4-吡啶鎓或2-，4-喹啉鎓单元，合成它们的组合物，含有它们的染料组合物和含有KERATIN纤维的染料的方法的特定的单相单色化合物
公开(公告)号：US20090300856A1
公开(公告)日：2009-12-10
申请号：US12296721
申请日：2007-04-13
申请人： Herve David , Nadege Murguet , Andrew Greaves
发明人： Herve David , Nadege Murguet , Andrew Greaves
IPC分类号： A61K8/49 , C07D213/36 , C07D413/12 , C07D215/12 , A61Q5/10
CPC分类号： C07D213/53 , A61K8/4926 , A61Q5/065 , C07D215/12 , C09B26/04
摘要： One subject of the present invention is monocationic monochromophoric compounds of formula (I) and/or (II) below: in which: R1 represents a hydrogen or an alkyl, phenyl, benzyl, alkylcarbonyl, alkylsulphonyl, aminosulphonyl or aminocarbonyl radical; R5 represents an alkyl, phenyl or benzyl radical; R2 and R3, represent a halogen or an alkyl, aryloxy, arylamino, hydroxyl, alkoxy, (poly)hydroxyalkoxy, alkoxycarbonyl, alkylcarbonyloxy, amino, alkylcarbonylamino, aminocarbonyl, ureido, aminosulphonyl, alkylthio, alkylsulphonylamino, cyano, trifluoromethyl, thio, alkylsulphinyl or alkylsulphonyl radical; R4 represents a hydrogen or an alkyl, amino, alkylcarbonylamino, ureido, alkylsulphonylamino, hydroxycarbonyl, alkoxycarbonyl, cyano, phenyl or benzyl radical; R6 and R7, represent a hydrogen or an alkyl, alkylcarbonyl, alkoxycarbonyl, alkoxyaryl, aminoaryl, aminocarbonyl or alkylsulphonyl radical; and n is between 0 and 4, n′ is between 0 and 4, the electroneutrality of the compounds of formulae (I) and (II) being ensured by one or more cosmetically acceptable anions An. Another subject of the invention is dyeing compositions comprising said compounds as direct dye, and also a method for dyeing keratin fibres using this composition and a multicompartment device.It finally relates to methods for synthesizing compounds of formula (I) and/or (II).
摘要翻译：本发明的一个主题是下式的式（I）和/或（II）的单取代单色化合物：其中：R1表示氢或烷基，苯基，苄基，烷基羰基，烷基磺酰基，氨基磺酰基或氨基羰基; R5表示烷基，苯基或苄基; R 2和R 3表示卤素或烷基，芳氧基，芳基氨基，羟基，烷氧基，（聚）羟基烷氧基，烷氧基羰基，烷基羰基氧基，氨基，烷基羰基氨基，氨基羰基，脲基，氨基磺酰基，烷硫基，烷基磺酰基氨基，氰基，三氟甲基，硫代，烷基亚磺酰基或烷基磺酰基; R4表示氢或烷基，氨基，烷基羰基氨基，脲基，烷基磺酰基氨基，羟基羰基，烷氧基羰基，氰基，苯基或苄基; R6和R7表示氢或烷基，烷基羰基，烷氧基羰基，烷氧基芳基，氨基芳基，氨基羰基或烷基磺酰基; 并且n在0和4之间，n'在0和4之间，式（I）和（II）化合物的电中性由一种或多种化妆品可接受的阴离子An确保。本发明的另一主题是包含所述化合物作为直接染料的染色组合物，以及使用该组合物和多室装置染色角蛋白纤维的方法。最后涉及合成式（I）和/或（II）化合物的方法。

5. 发明申请

US20080196175A1 Particular Dissymmetrical Cationic Polyazo Compounds, Compositions Comprising Them as Direct Dye, Process For Dyeing Keratin Fibres and Device Therefor 审中-公开
标题翻译：特殊的不对称阳离子多偶氮化合物，包含它们作为直接染料的组合物，染色角蛋白纤维的方法及其装置
公开(公告)号：US20080196175A1
公开(公告)日：2008-08-21
申请号：US11791457
申请日：2005-11-24
申请人： Andrew Greaves , Herve David
发明人： Andrew Greaves , Herve David
IPC分类号： A61K8/49 , C09B44/10 , C09B44/16 , A61Q5/10 , C09B44/12 , C09B44/14
CPC分类号： A61K8/4926 , A61K8/4946 , A61K2800/88 , A61Q5/10 , C09B44/106 , C09B44/126 , C09B44/14 , C09B44/16
摘要： The present invention concerns a new dissymmetrical cationic polyazo compounds of formula (I) Dye1-L-Dye2. The present invention also relates to dye compositions comprising such compounds as direct dye in a medium that is suitable for dyeing keratin fibres, and also to a process for dyeing keratin fibres using this composition and a multi-compartment device. The present invention provides direct dyes with which strong and varied shades that are resistant to external attacking factors such as bad weather and shampooing, for which there is no observation of any problem of change in colour over time.
摘要翻译：本发明涉及新的式（I）Dye1-L-Dye2的不对称阳离子多偶氮化合物。本发明还涉及染料组合物，其包含在适于染色角蛋白纤维的培养基中的直接染料等化合物，以及使用该组合物和多室装置染色角蛋白纤维的方法。本发明提供了直接染料，其具有强烈和变化的阴影，其抵抗诸如恶劣天气和洗发的外部攻击因素，其中没有观察到颜色随时间变化的任何问题。

6. 发明申请

US20080115296A1 Symmetrical Cationic Tetraazo Compounds, for Dyeing Keratin Fibres 审中-公开
标题翻译：对称阳离子四氮唑化合物，用于染色角蛋白纤维
公开(公告)号：US20080115296A1
公开(公告)日：2008-05-22
申请号：US11791675
申请日：2005-11-24
申请人： Andrew Greaves , Herve David
发明人： Andrew Greaves , Herve David
IPC分类号： A61K8/49 , C07C245/08 , A61K8/40 , A61Q5/10
CPC分类号： C07D233/88 , A61K8/4926 , A61K8/494 , A61K8/4946 , A61Q5/065 , A61Q5/10 , C09B44/106 , C09B44/14
摘要： The present invention relates to symmetrical tetraazo cationic compounds of formula (I) Dye1-L-Dye1 in which formula: Dye1 represents: in which: W1, which are identical, represent: W2, which are identical, represent: W3, which are identical, represent: L represents an optionally substituted C1-C60 hydrocarbon-based chain, optionally bearing at least one cationic charge, optionally interrupted with and/or terminated at one and the other of the ends with at least one hetero atom or group comprising at least one hetero atom; the electrical neutrality of the compounds being ensured by means of one or more cosmetically acceptable, identical or different anions An. A subject of the invention is similarly a composition comprising such a dye as direct dye, and also a process using the said composition for dyeing keratin fibres.
摘要翻译：本发明涉及式（I）的对称四偶氮阳离子化合物<？in-line-formula description =“In-line Formulas”end =“lead”→Dye1-L-Dye1 <？in-line-formula description = “在线公式”end =“tail”？>其中公式：Dye1表示：其中：W 1是相同的，表示：W 2，其中相同，表示：相同的，代表：L表示任选取代的C 1 -C 60烃基链，任选地带有至少一个阳离子电荷，任选地被至少一个杂原子或包含至少一个杂原子的基团中的一个和另一个末端处终止和/或终止; 通过一种或多种化妆品可接受，相同或不同的阴离子An确保化合物的电中性。本发明的主题类似地是包含诸如直接染料的染料的组合物，以及使用所述组合物染色角蛋白纤维的方法。

7. 发明申请

US20060005324A1 Cationic diazo compounds, compositions comprising them as direct dye, process for dyeing keratin fibers and device therefor 失效
标题翻译：阳离子重氮化合物，包含它们作为直接染料的组合物，染色角蛋白纤维的方法及其装置
公开(公告)号：US20060005324A1
公开(公告)日：2006-01-12
申请号：US11159242
申请日：2005-06-23
申请人： Andrew Greaves , Herve David
发明人： Andrew Greaves , Herve David
IPC分类号： A61K8/00 , A61Q5/10
CPC分类号： A61K8/4946 , A61Q5/10 , C09B43/00
摘要： The present disclosure relates to cationic diazo dye compounds of formula (I): Dye1-LK-Dye2 (I), dye compositions comprising the direct dye compounds, and also to a process for dyeing keratin fibers using this composition and a multi-compartment kit.
摘要翻译：本公开内容涉及式（I）的阳离子重氮染料化合物：<？in-line-formula description =“In-line Formulas”end =“lead”→Dye1-LK-Dye2（I），< line-formula description =“In-line Formulas”end =“tail”？>包含直接染料化合物的染料组合物，以及使用该组合物和多室试剂盒染色角蛋白纤维的方法。

8. 发明申请

US20080168607A1 Unsymmetrical Diazo Compounds, Compositions Comprising Same, Dyeing Method and Device Comprising Said Compositions 审中-公开
标题翻译：不对称重氮化合物，包含其的组合物，染色方法和包含所述组合物的装置
公开(公告)号：US20080168607A1
公开(公告)日：2008-07-17
申请号：US11793013
申请日：2005-12-15
申请人： Herve David , Andrew Greaves , Nicolas Daubresse
发明人： Herve David , Andrew Greaves , Nicolas Daubresse
IPC分类号： A61K8/00
CPC分类号： C07D403/14 , A61K8/4926 , A61K8/4946 , A61Q5/065 , C07D213/77 , C07D401/14 , C07D455/04 , C09B44/126 , C09B44/16
摘要： The invention concerns symmetric diazo cationic compounds of formula (I), their resonance forms, as well as their acid-addition salts and their solvates, wherein W1, identical represent a hydrogen atom, a halogen atom, a —NR5R6, OR7, —NR1-Ph-NR5R6, —NR4-Ph-OR7, —O-Ph-OR7, —O-Ph-NR5R6 group; L represents a cationic of non-cationic linker arm. The invention also concerns dyeing compositions comprising in a suitable medium for dyeing keratinous fibers, such compounds as direct dyeing agent, as well as a method for dyeing keratinous fibers using said composition and a multiple-compartment device.
摘要翻译：本发明涉及式（I）的对称重氮阳离子化合物，它们的共振形式，以及它们的酸加成盐及其溶剂化物，其中W 1是相同的，表示氢原子，卤素原子， -NR 5 R 6，或7，-NR 1 -CR 3 -NR 5， R 6，R 6，R 6，R 6，R 6，R 7，，-O-Ph-NR 5 R 6 C 6基团; L表示非阳离子连接臂的阳离子。本发明还涉及包含在用于染色角质纤维的合适介质中的染色组合物，诸如直接染色剂的化合物，以及使用所述组合物和多室装置染色角质纤维的方法。

9. 发明申请

US20060174422A1 Symmetrical diazo compounds comprising 4-pyridinium groups and a cationic or non-cationic linker, compositions comprising them, method for coloring, and device 失效
标题翻译：包含4-吡啶鎓基团和阳离子或非阳离子接头的对称重氮化合物，包含它们的组合物，着色方法和装置
公开(公告)号：US20060174422A1
公开(公告)日：2006-08-10
申请号：US11300303
申请日：2005-12-15
申请人： Herve David , Andrew Greaves , Nicolas Daubresse
发明人： Herve David , Andrew Greaves , Nicolas Daubresse
IPC分类号： C09B67/00
CPC分类号： C09B44/126 , C09B27/00
摘要： Disclosed herein are symmetrical cationic diazo compounds chosen from compounds of formula (I), their resonance forms, their acid addition salts, and their solvates: Also disclosed herein are dyeing compositions comprising such compounds as a direct dye in a medium appropriate for the dyeing of keratin fibers, a method of coloring keratin fibers comprising contacting the keratin fibers with such compositions, and a device comprising a plurality of compartments.
摘要翻译：本文公开的是选自式（I）化合物，其共振形式，其酸加成盐和它们的溶剂合物的对称阳离子重氮化合物：本文还公开了包含这样的化合物的染色组合物，所述染料组合物包含适于染色角蛋白纤维，着色角蛋白纤维的方法，包括使角蛋白纤维与这种组合物接触，以及包含多个隔室的装置。

10. 发明申请

US20060156490A1 Symmetrical diazo compounds comprising 2-imidazolium groups and a cationic linker, compositions comprising them, method of coloring, and device 审中-公开
标题翻译：包含2-咪唑鎓基团和阳离子接头的对称重氮化合物，包含它们的组合物，着色方法和装置
公开(公告)号：US20060156490A1
公开(公告)日：2006-07-20
申请号：US11300512
申请日：2005-12-15
申请人： Herve David , Andrew Greaves , Nicolas Daubresse
发明人： Herve David , Andrew Greaves , Nicolas Daubresse
IPC分类号： A61K8/49 , C07D403/02
CPC分类号： C07D471/06 , A61K8/4946 , A61Q5/065 , A61Q5/10 , C07D233/88 , C07D403/14 , C09B44/101 , C09B44/16
摘要： The present invention relates to symmetrical cationic diazo compounds of formula (I) below, their resonance forms, and also their acid addition salts and their solvates: in which W1 radicals, which are identical, represent a halogen atom or an —NR4—Ph—NR5R6, —NR4—Ph—OR7, —O—Ph—OR7 or —O—Ph—NR5R6 group; L, a cationic linker connecting the two identical azo chromophores represents a C2-C40 alkyl radical which carries at least one cationic charge and is optionally substituted and/or optionally interrupted by one or more, saturated or unsaturated (hetero)cycles; the linker L containing no azo, nitro, nitroso or peroxo bond. The invention further relates to dyeing compositions comprising such compounds as a direct dye in a medium appropriate for the dyeing of keratin fibres, and also to a method of colouring keratin fibres that employs this composition, and a device having a plurality of compartments.
摘要翻译：本发明涉及以下式（I）的对称阳离子重氮化合物，它们的共振形式，以及它们的酸加成盐及其溶剂合物：其中相同的W 1个基团代表卤素原子或-NR 4 -OR-NR 5 R 6，-NR 4 -OR-OR 6， -O-Ph-OR 7或-O-Ph-NR 5 R 6 C 6基团; L，连接两个相同的偶氮发色团的阳离子接头表示携带至少一种阳离子电荷且任选被取代和/或任选中断的C 2 -C 40 -C 40烷基通过一个或多个饱和或不饱和（杂）周期; 连接体L不含偶氮，硝基，亚硝基或过氧键。本发明还涉及包含适合于染色角蛋白纤维的培养基中的直接染料等化合物的染色组合物，以及使用该组合物的角蛋白纤维着色方法，以及具有多个隔室的装置。

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