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    • 1. 发明授权
    • Hair treatment gels containing itaconic acid monoester/acrylate copolymer
    • 含有衣康酸单酯/丙烯酸酯共聚物的头发处理凝胶
    • US06716455B2
    • 2004-04-06
    • US10228408
    • 2002-08-27
    • Susanne BirkelHarald WendelMichael FranzkeSilke Niesig
    • Susanne BirkelHarald WendelMichael FranzkeSilke Niesig
    • A61K910
    • A61Q5/06A61K8/042A61K8/8152A61K2800/43A61Q5/065Y10S514/844Y10S514/944
    • The aqueous hair fixing gel has special rheological properties so that it can be dispensed from a container without dripping or becoming stringy. It contains from 1.5 to 10 percent by weight of at least one itaconic acid monoester/acrylate copolymer and from 0.1 to 15 percent by weight of at least one non-ionic, anionic, zwitterionic or amphoteric hair-fixing polymer. The itaconic acid monoester has a formula CH2═C(COOR1)CH2COOR2, wherein one of R1 and R2 represents hydrogen and the other represents —(CH2CH2O)x—R3, x is between 1 to 100 and R3 is an alkyl group having 8 to 30 carbon atoms. The aqueous hair treatment gel has a pH of greater than 7 and a viscosity of preferably from 2000 to 50,000 mPa.s, as measured at 25° C. The gel is formulated so that there is a gel viscosity maximum as a function of shear rate with increasing shear rate, preferably between 0.1 to 5.0 s−1.
    • 水性头发固定凝胶具有特殊的流变性质,使得其可以从容器中分配而不会滴落或变得粗糙。 它包含1.5至10重量%的至少一种衣康酸单酯/丙烯酸酯共聚物和0.1至15重量%的至少一种非离子,阴离子,两性离子或两性固定聚合物。 衣康酸单酯具有式CH 2 = C(COOR 1)CH 2 COOR 2,其中R 1和R 2之一表示氢,另一个表示 - (CH 2 CH 2 O)x R 3,x为 1〜100,R 3为碳原子数为8〜30的烷基。 水性毛发处理凝胶的pH值大于7,粘度优选为2000至50,000mPa.s,在25℃下测定。凝胶配制成使凝胶粘度最大值作为剪切速率的函数 剪切速率增加,优选在0.1至5.0s -1之间。
    • 2. 发明授权
    • Hair styling stick containing polyethylene glycols of different molecular weights
    • 含有不同分子量的聚乙二醇的发型棒
    • US07135166B2
    • 2006-11-14
    • US10125824
    • 2002-04-19
    • Susanne BirkelHarald WendelMichael FranzkeBernd SteinManuela Hannich
    • Susanne BirkelHarald WendelMichael FranzkeBernd SteinManuela Hannich
    • A61K8/00A61K8/18A61K8/72A61K6/00A61K8/02
    • A61Q5/06A61K8/86
    • The hair styling stick contains from 30 to 55 percent by weight of one or more polyethylene glycols with a molecular weight of from 2500 to 5000 g/mol; and from 40 to 70 percent by weight of at least one other polyethylene glycol with a molecular weight of from 570 to 800 g/mol together with cosmetic ingredients. In preferred embodiments the hair styling stick contains from 30 to 55 percent by weight of one or more polyethylene glycols with a molecular weight of from 2500 to 5000 g/mol; from 15 to 35 percent by weight of one or more polyethylene glycols with a molecular weight of from 850 to 1600 g/mol, from 15 to 35 percent by weight of one or more liquid polyethylene glycols with a molecular weight of from 570 to 800 g/mol and additional cosmetic ingredients, as needed. The additional cosmetic ingredients can include an aqueous or organic solvent, emulsifier, perfume or fragrance, dye, preservative and/or pearlescence-imparting agent.
    • 头发定型棒包含30至55重量%的一种或多种分子量为2500至5000g / mol的聚乙二醇; 和40至70重量%的至少一种分子量为570-800g / mol的其它聚乙二醇与化妆品成分一起。 在优选实施方案中,头发定型棒包含30至55重量%的一种或多种分子量为2500至5000g / mol的聚乙二醇; 15至35重量%的一种或多种分子量为850至1600g / mol的聚乙二醇,15至35重量%的一种或多种分子量为570至800g的液体聚乙二醇 / mol和额外的化妆品成分。 另外的化妆品成分可以包括水性或有机溶剂,乳化剂,香料或香料,染料,防腐剂和/或珠光赋予剂。
    • 7. 发明申请
    • Hair-Treatment Agent Comprising Terpolymer Of Vinylpyrrolidone, Methacrylamide And Vinylimidazole And Active Ingredients And Additives
    • 包含乙烯基吡咯烷酮,甲基丙烯酰胺和乙烯基咪唑三元共聚物和活性成分和添加剂的护发剂
    • US20080020004A1
    • 2008-01-24
    • US10589372
    • 2005-02-18
    • Susanne BirkelThomas KrauseMichael Franzke
    • Susanne BirkelThomas KrauseMichael Franzke
    • A61K8/81A61K8/06A61Q5/06
    • A61K8/046A61K8/8152A61K8/8182A61K8/87A61K2800/594A61Q5/06
    • A hair-treatment agent is described with a content of a combination of a terpolymer constructed from vinylpyrrolidone, methacrylamide and vinylimidazole, and at least one active ingredient or additive chosen from viscosity-modifying substances, haircare substances, hair-setting substances, silicone compounds, photoprotective substances, oils, waxes, preservatives, pigments, soluble dyes, particulate substances, and surfactants in a suitable cosmetic base. The hair-treatment agent can be in the form of a gel, a viscous lotion, a spray gel, an O/W emulsion, a W/O emulsion, a microemulsion, a hair spray, a foamable product in combination with a device for foaming, or in the form of a hair wax. Preference is given to products which are foamable with a propellant in which the active ingredient or additive is chosen from chitosan, chitosan salts, chitosan derivatives, cationic cellulose compounds and copolymers of vinylpyrrolidone, vinylcaprolactam and a basic acrylamide monomer.
    • 描述了由乙烯基吡咯烷酮,甲基丙烯酰胺和乙烯基咪唑构成的三元共聚物和至少一种选自粘度调节物质,护发物质,定型物质,硅氧烷化合物, 光保护物质,油,蜡,防腐剂,颜料,可溶性染料,颗粒物质和表面活性剂。 毛发处理剂可以是凝胶,粘性洗剂,喷雾凝胶,O / W乳液,W / O乳液,微乳液,喷发剂,可发泡产品的形式,与用于 发泡,或以发蜡的形式。 优选使用推进剂发泡的产品,其中活性成分或添加剂选自壳聚糖,壳聚糖盐,壳聚糖衍生物,阳离子纤维素化合物以及乙烯基吡咯烷酮,乙烯基己内酰胺和碱性丙烯酰胺单体的共聚物。
    • 9. 发明申请
    • Moisture resistant hair styling composition containing two copolymers
    • 含有两种共聚物的防潮发型组合物
    • US20070197704A1
    • 2007-08-23
    • US11787710
    • 2007-04-17
    • Andrea WalterSusanne BirkelMichael FranzkeKatja Schmitt
    • Andrea WalterSusanne BirkelMichael FranzkeKatja Schmitt
    • C08K5/05
    • A61K8/8147A61K8/8152A61K2800/548A61Q5/06C08K5/17
    • The compositions of the present invention relate to improved aqueous or aqueous-alcoholic hair styling compositions comprising a combination of two copolymers. The first copolymer is a copolymer of (a1) acidic vinyl monomers, e.g., acrylic or methacrylic acid, with (a2) hydrophobic nonionic vinyl monomers, e.g., acrylic or methacrylic acid esters, with (a3) a first associative monomer and (a4) at least one other monomer which can be a second associative monomer different from the first associative monomer or a semihydrophobic monomer. The associative monomers having (i) an ethylenically unsaturated end group, (ii) a hydrophilic midsection and (iii) a hydrophobic or semi-hydrophobic end group. The second copolymer is a copolymer of (b1) C3 to C8 monoethylenically unsaturated monocarboxylic acid monomers, (b2) acrylic or methacrylic acid alkyl esters, and (b3) acrylic or methacrylic acid hydroxyalkyl esters. Preferred product forms are gels, additionally containing a gel forming agent. The compositions can be used for increasing the humidity resistance, moisture resistance or sweat resistance of a hair style.
    • 本发明的组合物涉及包含两种共聚物的组合的改进的含水或含水的发型组合物。 第一共聚物是(a1)酸性乙烯基单体,例如丙烯酸或甲基丙烯酸与(a2)疏水性非离子乙烯基单体(例如丙烯酸或甲基丙烯酸酯)与(a3)第一缔合单体和(a4) 至少一种其它单体,其可以是不同于第一缔合单体或半疏水单体的第二缔合单体。 具有(i)烯属不饱和端基,(ii)亲水性中部和(iii)疏水或半疏水端基的缔合单体。 第二共聚物是(b1)C 3〜C 8〜单碳烯不饱和一元羧酸单体的共聚物,(b2)丙烯酸或甲基丙烯酸烷基酯,和(b3)丙烯酸 或甲基丙烯酸羟烷基酯。 优选的产品形式是凝胶,另外含有凝胶形成剂。 该组合物可用于增加发型的耐湿性,耐湿性或耐汗性。