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1. 发明授权

US5414161A Process for the preparation of ethanol from methanol 失效
标题翻译：从甲醇制备乙醇的方法
公开(公告)号：US5414161A
公开(公告)日：1995-05-09
申请号：US214240
申请日：1994-03-17
申请人： Sung J. Uhm , Sung H. Han , Jun W. Oh , Oh S. Joo , Kwang D. Jung , Jung Y. Beak
发明人： Sung J. Uhm , Sung H. Han , Jun W. Oh , Oh S. Joo , Kwang D. Jung , Jung Y. Beak
IPC分类号： B01J21/18 , B01J23/80 , B01J23/887 , B01J27/06 , B01J27/122 , B01J27/13 , B01J27/138 , B01J31/02 , B01J31/16 , B01J31/20 , B01J31/22 , B01J31/24 , B01J37/02 , B01J37/03 , C07C51/12 , C07C51/54 , C07C51/56 , C07C67/36 , C10K1/00 , C07C29/147 , C07C31/18
CPC分类号： C10K1/00 , B01J23/80 , B01J27/13 , B01J31/20 , B01J31/2291 , B01J31/2404 , B01J31/26 , B01J31/30 , B01J37/03 , C07C29/149 , C07C51/12 , C07C51/54 , C07C51/56 , C07C67/36 , B01J21/18 , B01J23/8873 , B01J2531/16 , B01J2531/26 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J27/122 , B01J27/138 , B01J37/0201 , Y02P20/52 , Y02P20/584
摘要： Ethanol is produced economically by a gas phase carbonylation of methanol with carbon monoxide followed by a hydrogenation. Specifically, the inventive process comprises:(a) carbonylating methanol in a gas phase with carbon monoxide in a carbonylation reactor, said carbon monoxide being optionally in admixture of hydrogen, in the presence of a rhodium catalyst comprised of a rhodium compound and a second metallic component selected from the group consisting of an alkali metal, an alkaline earth metal, a transition metal and a mixture thereof, and supported on an inert material, and a halide co-catalyst under mild carbonylation conditions and a high GHSV(Gas Hourly Space Velocity) of methanol to produce a mixture of acetic acid and methyl acetate;(b) separating from the production mixture in a distillation column the acetic acid as a high boiling fraction thereof, and a mixture of the methyl acetate and the co-catalyst as a low boiling fraction thereof;(c) further separating said methyl acetate and the co-catalyst from the low boiling fraction and recycling the separated co-catalyst to the carbonylation reactor;(d) hydrogenating the separated methyl acetate with hydrogen gas in a hydrogenation reactor in the presence of a copper-containing hydrogenation catalyst to produce ethanol at a high yield.
摘要翻译：通过甲醇与一氧化碳的气相羰基化，然后氢化，经济地生产乙醇。具体地，本发明的方法包括：（a）在羰基化反应器中用一氧化碳在气相中羰基化甲醇，所述一氧化碳任选地与氢混合，在由铑化合物和第二金属选自碱金属，碱土金属，过渡金属及其混合物的组分，并负载在惰性材料上，卤化物助催化剂在温和羰基化条件和高GHSV（气时空速））甲醇以产生乙酸和乙酸甲酯的混合物; （b）在蒸馏塔中从生产混合物中分离出作为其高沸点馏分的乙酸，以及作为低沸点馏分的乙酸甲酯和助催化剂的混合物; （c）从低沸点馏分进一步分离乙酸甲酯和助催化剂，并将分离的助催化剂再循环到羰基化反应器中; （d）在氢化反应器中，在含铜氢化催化剂存在下，用氢气氢化分离出的乙酸甲酯，以高产率制备乙醇。

2. 发明授权

US5430178A Process for the preparation of acetic esters from methanol 失效
标题翻译：从甲醇制备乙酸酯的方法
公开(公告)号：US5430178A
公开(公告)日：1995-07-04
申请号：US281187
申请日：1994-07-27
申请人： Sung J. Uhm , Sung H. Han , Jun W. Oh , Oh S. Joo , Kwang D. Jung , Moon S. Lee
发明人： Sung J. Uhm , Sung H. Han , Jun W. Oh , Oh S. Joo , Kwang D. Jung , Moon S. Lee
IPC分类号： B01J27/13 , B01D3/00 , B01J31/22 , B01J31/30 , C01B32/40 , C07B61/00 , C07C67/03 , C07C67/36 , C07C69/14
CPC分类号： C07C67/03 , B01D3/009 , C07C67/36 , Y02P20/127 , Y02P20/584
摘要： Acetic ester is produced economically by a gas phase carbonylation of methanol with carbon monoxide followed by a transesterification. Specifically, the inventive process comprises (a) carbonylating methanol in a gas phase with carbon monoxide to produce a mixture of acetic acid and methyl acetate; (b) separating from the production mixture the acetic acid, and a mixture of the methyl acetate and the co-catalyst; (c) further separating said methyl acetate and the co-catalyst and recycling the separated co-catalyst to the carbonylation reactor; (d) introducing the separated methyl acetate into a lower region of a transesterification reactor at a temperature of above its boiling point; (e) introducing an C.sub.2 or higher alcohol into an upper region of the trans-esterification reactor at a temperature of up to its boiling point; (f) transesterifying the methyl acetate with the alcohol in the presence of an acid catalyst to produce a mixture containing acetic esters; and (g) recovering the acetic esters from the mixture as a bottom product while recycling the unreacted methyl acetate and methanol to the carbonylation reactor or distillation column.
摘要翻译：通过甲醇与一氧化碳的气相羰基化，然后进行酯交换，经济地生产乙酸酯。具体地，本发明的方法包括（a）在气相中用一氧化碳羰基化甲醇以产生乙酸和乙酸甲酯的混合物; （b）从生产混合物中分离出乙酸，以及乙酸甲酯和助催化剂的混合物; （c）进一步分离所述乙酸甲酯和助催化剂并将分离的助催化剂再循环到羰基化反应器中; （d）在高于其沸点的温度下将分离的乙酸甲酯引入酯交换反应器的下部区域; （e）在高达其沸点的温度下将C2或更高级醇引入反式酯化反应器的上部区域; （f）在酸催化剂存在下，用乙醇使乙酸甲酯酯交换反应产生含乙酸酯的混合物; 和（g）将作为底部产物的乙酸酯从混合物中回收，同时将未反应的乙酸甲酯和甲醇再循环到羰基化反应器或蒸馏塔中。

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