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    • 6. 发明授权
    • Polyarylene polyether made using mixed base system
    • 聚亚芳基聚醚用混合基体制成
    • US4789722A
    • 1988-12-06
    • US80144
    • 1987-07-29
    • Harold JablonerTuyen T. Nguyen
    • Harold JablonerTuyen T. Nguyen
    • C08G65/40C08G65/48C08G75/23
    • C08G65/48C08G65/4093
    • Polyarylene polyethers, made by a process comprising reacting a dihydroxy compound and strong and weak bases in a liquid reaction medium at 100.degree.-200.degree. C. to form a double salt and then reacting the double salt with a slight molar excess of dihalobenzenoid compound bearing two replaceable halogens, are disclosed. The process reliably produces halogen-terminated polyarylene polyethers of select degrees of polymerization and desirable correspondence between weight and number average molecular weights. In subsequent steps amine-terminated polyarylene polyethers are made using the strong and weak bases. The resulting amine-terminated polyethers have a low, select degree of polymerization, desirable correspondence between weight and number average molecular weights and high level of amine termination.
    • 聚亚芳基聚醚,其通过包括在液体反应介质中在100℃-200℃下使二羟基化合物与强碱和弱碱反应以形成双重盐,然后使双重盐与少量摩尔过量的二卤代苯基化合物 两种可更换的卤素被公开。 该方法可靠地生产具有选择聚合度的卤素封端的聚亚芳基聚醚,并且其重量和数均分子量之间是期望的对应关系。 在随后的步骤中,使用强碱和弱碱制备胺封端的聚亚芳基聚醚。 所得的胺封端的聚醚具有低的选择聚合度,重量和数均分子量之间的期望对应性以及高水平的胺终止。