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    • 3. 发明授权
    • Process for preparing textured ceramic composites
    • 陶瓷复合材料制备工艺
    • US5645781A
    • 1997-07-08
    • US309853
    • 1994-09-21
    • Dragan Popovic' John W. HalloranGregory E. HilmasGuy Allen BradyScott SomersAndrew BardaGregory Zywicki
    • Dragan Popovic' John W. HalloranGregory E. HilmasGuy Allen BradyScott SomersAndrew BardaGregory Zywicki
    • C04B35/80B29C47/06B28B5/00B29C63/00
    • C04B35/80
    • A method for the preparation of a fibrous monolithic ceramic which exhibits non-brittle fracture characteristics from green monofilament ceramic fibers having a controlled texture. This method includes the steps of: (a) forming a first ceramic-laden composition includes a thermoplastic polymer and at least about 40 vol. % of a ceramic particulate into a substantially cylindrical core, (b) applying a layer of a second ceramic-laden composition includes a thermoplastic polymer and at least about 40 vol. % of a ceramic particulate which differs from the particulate contained in the first composition onto the core to form a substantially cylindrical feed rod having an average initial diameter, (c) extruding the feed rod to form a green ceramic monofilament fiber which has an average diameter that is less than the average diameter of the feed rod, and (e) arranging the green ceramic monofilament fibers into a desired configuration to provide a green fibrous monolith, wherein, during the extrusion step, each ceramic-laden composition has a viscosity which is approximately equivalent to that of each other ceramic-laden composition, and, if the ceramics present in the extruded ceramic monofilament fiber are sintered, a plane of weakness defined by the interface of the core and the layer is provided, the interface being relatively weaker than the core. The green fibrous monolith may be sintered to provide a fibrous monolith.
    • 一种制备具有受控质地的绿色单丝陶瓷纤维具有非脆性断裂特性的纤维整体陶瓷的方法。 该方法包括以下步骤:(a)形成第一含陶瓷的组合物,其包含热塑性聚合物和至少约40vol。 %的陶瓷颗粒进入基本上圆柱形的芯中,(b)施​​加第二含陶瓷的组合物层包括热塑性聚合物和至少约40vol。 %的陶瓷颗粒与第一组合物中包含的颗粒不同于芯,以形成具有平均初始直径的基本上圆柱形的进料棒,(c)挤出进料棒以形成具有平均直径的生坯陶瓷单丝纤维 小于所述进料棒的平均直径,以及(e)将所述生坯陶瓷单丝纤维布置成所需的构型以提供绿色纤维整料,其中在所述挤出步骤期间,每个载有陶瓷的组合物的粘度为 大致相当于彼此含有陶瓷的组合物,并且如果在挤出的陶瓷单丝纤维中存在的陶瓷被烧结,则提供由芯和层的界面界定的弱平面,其界面相对弱于 核心。 可以将绿色纤维整料烧结以提供纤维整料。
    • 8. 发明授权
    • Electrical superconducting ceramic fiber devices
    • 电气超导陶瓷纤维器件
    • US4990490A
    • 1991-02-05
    • US202964
    • 1988-06-03
    • Viren M. PathareJohn W. Halloran
    • Viren M. PathareJohn W. Halloran
    • H01L39/14
    • H01L39/143H01L39/248Y10S505/887Y10S505/927Y10T29/49014
    • A coating composition for ceramic fibers is provided which includes metal particles and a vehicle. The coating can be applied to a green ceramic or a sintered ceramic, and is co-sintered or sintered therewith. Such coatings are useful for coating high temperature superconducting ceramic fibers and can be co-sintered therewith. The coated superconducting fibers, in which case the coating is porous to allow for annealing to adjust the oxygen stoichiometry, can then be sandwiched between metal cladding layers to provide a multifilamentary electrical conductor including superconducting active components. The coating is useful for such conductors because it compatibilizes the ceramic fiber with metal components, such as a solder, as well as protecting the ceramic from possibly degrading reactions. The compositions are also generally advantageous in compatibilizing ceramic fibers with a metal matrix.
    • 提供了一种陶瓷纤维用涂料组合物,其包括金属颗粒和载体。 涂层可以应用于生坯陶瓷或烧结陶瓷,并与其共烧结或烧结。 这种涂层可用于涂覆高温超导陶瓷纤维并可与其共烧结。 涂覆的超导纤维,在这种情况下,涂层是多孔的以允许退火以调节氧化学计量,然后可以夹在金属包覆层之间,以提供包括超导活性组分的多丝电导体。 该涂层可用于这种导体,因为它使陶瓷纤维与诸如焊料的金属组分相容,并且保护陶瓷免受可能的降解反应。 组合物通常也有利于使陶瓷纤维与金属基质相容。