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1. 发明授权

US5935491A Gradient-index polymer rods and fibers 失效
标题翻译：梯度折射率聚合物棒和纤维
公开(公告)号：US5935491A
公开(公告)日：1999-08-10
申请号：US929382
申请日：1997-09-15
申请人： Sukant Tripathy , Kethinni G. Chittibabu , Jayant Kumar
发明人： Sukant Tripathy , Kethinni G. Chittibabu , Jayant Kumar
IPC分类号： B29C47/00 , B29C71/00 , B29D11/00 , G02B1/04 , G02B6/028
CPC分类号： G02B6/02038 , B29C71/0009 , B29D11/00682 , B29D11/00721 , G02B1/046 , B29C2071/0027 , B29C2071/0054 , B29C47/00 , B29C47/0014
摘要： The invention features a method of making a gradient-index polymer rod involving the steps of: combining a polymer with an additive, wherein the refractive index of the polymer material is different than the refractive index of the additive material; extruding the polymer and the additive into a polymer rod having a substantially uniform index of refraction profile; and immersing the rod having the substantially uniform index of refraction profile in a non-solvent under conditions and for a time that enables the non-solvent to permeate the rod and out-diffuse a portion of the additive material, thereby producing the gradient-index polymer rod. The rod produced by the method can be drawn into a graded index polymer fiber. The invention also features a gradient-index polymer rod (or fiber) of condensation-type polymer that is doped with an additive material. The refractive index of the additive material is different than the refractive index of the polymer and the rod (or fiber) has a concentration profile of the additive that varies along the radial direction of the rod (or fiber) from the center to the surface of the rod (or fiber).
摘要翻译：本发明的特征在于一种制备梯度折射率聚合物棒的方法，包括以下步骤：将聚合物与添加剂结合，其中聚合物材料的折射率不同于添加剂材料的折射率; 将聚合物和添加剂挤出成具有基本均匀的折射率分布的聚合物棒; 并且将条件下的基本上均匀的折射率分布的棒浸渍在非溶剂中，使得非溶剂渗透到棒中并使一部分添加剂材料扩散，从而产生梯度指数聚合物棒。通过该方法制备的棒可以被拉伸成渐变折射率聚合物纤维。本发明还具有掺杂有添加剂材料的缩合型聚合物的梯度折射率聚合物棒（或纤维）。添加剂材料的折射率不同于聚合物的折射率，并且棒（或纤维）具有沿棒（或纤维）的径向方向从中心到表面变化的添加剂的浓度分布杆（或纤维）。

2. 发明申请

US20050084888A1 Enzymatic template polymerization 失效
公开(公告)号：US20050084888A1
公开(公告)日：2005-04-21
申请号：US10958907
申请日：2004-10-05
申请人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
IPC分类号： C08G73/02 , H01B1/12 , C12Q1/68 , C08G63/48 , C08G63/91
CPC分类号： C08G73/0266 , H01B1/128 , Y10S977/704 , Y10T436/143333
摘要： A conductive polymer is formed enzymatically in the presence of a polynucleotide template. The method includes combining at least one redox monomer with a polynucleotide template and a redox enzyme, such as horseradish peroxidase, to form a reaction mixture. The monomer aligns along the template before or during the polymerization. Therefore, the polynucleotide template thereby affects the molecular weight and conformation of the conductive polymer. When the conductive polymer is complexed to a polynucleotide duplex, the conformation of the polynucleotide duplex can be modulated by changing the oxidation state of the conductive polymer.

3. 发明授权

US06153272A Liquid crystal alignment by covalently bound anisotropes 失效
标题翻译：通过共价键结合的各向异性液晶取向
公开(公告)号：US06153272A
公开(公告)日：2000-11-28
申请号：US080598
申请日：1998-05-18
申请人： Dong-Yu Kim , Jayant Kumar , Sukant Tripathy
发明人： Dong-Yu Kim , Jayant Kumar , Sukant Tripathy
IPC分类号： C09K19/56 , G02F1/1337
CPC分类号： G02F1/133788 , C09K19/56 , G02F1/133711 , G02F2202/022 , Y10T428/1005 , Y10T428/1041 , Y10T428/1059
摘要： A polymer surface in contact with a liquid crystal medium is exposed to polarized light, whereby a covalently bound anisotropic component of the polymer surface aligns in response to the polarized light. Alignment of the anisotropic component causes alignment of the liquid crystal medium. An interference pattern of two polarized lights causes the covalently bound anisotropic component to form microgrooves on the polymer surface. A liquid crystal cell includes at least one polymer surface that has a covalently bound anisotropic component that can align in response to polarized light and a liquid crystal in contact with the polymer surface.
摘要翻译：与液晶介质接触的聚合物表面暴露于偏振光，由此聚合物表面的共价结合的各向异性成分响应于偏振光而对准。各向异性成分的排列导致液晶介质的对准。两个偏振光的干涉图案导致共价结合的各向异性成分在聚合物表面上形成微槽。液晶单元包括至少一个聚合物表面，该聚合物表面具有共价结合的各向异性成分，该各向异性成分可响应于偏振光而对齐，以及与聚合物表面接触的液晶。

4. 发明授权

US6106948A Nonlinear optical structure and methods of making 失效
标题翻译：非线性光学结构及其制作方法
公开(公告)号：US6106948A
公开(公告)日：2000-08-22
申请号：US870345
申请日：1997-06-06
申请人： Xiaogong Wang , Srinivasan Balasubramanian , Lian Li , Sukant Tripathy , Jayant Kumar
发明人： Xiaogong Wang , Srinivasan Balasubramanian , Lian Li , Sukant Tripathy , Jayant Kumar
IPC分类号： G02F1/361 , B32B27/38 , B05D1/36 , B05D5/06 , B32B27/00
CPC分类号： G02F1/361
摘要： A method for making a multilayer structure having macroscopic second order nonlinear optical properties is described. The resulting nonlinear optical structures made by the method are also described. The method includes the steps of contacting a substrate having ionic adsorption sites with a first charged polyion; ceasing contact of the substrate with the first charged polyion; and thereafter, contacting the substrate with a second charged polyion having a charge opposite to that of the first charged polyion, wherein at least one of the polyions includes a nonlinear optical chromophoric side chain.
摘要翻译：描述了制造具有宏观二阶非线性光学特性的多层结构的方法。还描述了由该方法制成的所得非线性光学结构。该方法包括使具有离子吸附位点的底物与第一带电的聚阳离子接触的步骤; 停止基板与第一带电的聚阳离子的接触; 然后使所述衬底与具有与所述第一带电聚氨离子的电荷相反的电荷的第二带电聚阴离子接触，其中所述多个离子中的至少一个包括非线性光学发色侧链。

5. 发明授权

US5994498A Method of forming water-soluble, electrically conductive and optically active polymers 失效
标题翻译：形成水溶性，导电和旋光聚合物的方法
公开(公告)号：US5994498A
公开(公告)日：1999-11-30
申请号：US915827
申请日：1997-08-21
申请人： Sukant Tripathy , Lynne A. Samuelson , K. Shridhara Alva , Jayant Kumar , Kenneth A. Marx
发明人： Sukant Tripathy , Lynne A. Samuelson , K. Shridhara Alva , Jayant Kumar , Kenneth A. Marx
IPC分类号： C08G73/02 , H01B1/12 , C08G73/00
CPC分类号： C08G73/0266 , H01B1/128
摘要： Water-soluble polymers are formed by combining a water-soluble analog of a water-insoluble monomer, such as a water-insoluble redox monomer, with a water-based solvent and an enzyme. The water-soluble polymers formed can be electrically conductive or optically active. The water-soluble analog can be copolymerized with a water-insoluble redox monomer to form a copolymer that is also water-soluble. Polymers formed by the method of this invention can be layered on a surface to form, for example, alternating layers of polyanions and polycations.
摘要翻译：通过将水不溶性单体如水不溶性氧化还原单体的水溶性类似物与水基溶剂和酶组合而形成水溶性聚合物。形成的水溶性聚合物可以是导电的或光学活性的。水溶性类似物可以与水不溶性氧化还原单体共聚以形成也是水溶性的共聚物。通过本发明的方法形成的聚合物可以在表面上层叠以形成例如聚阴离子和聚阳离子的交替层。

6. 发明申请

US20070021587A1 Polymerization of aromatic monomers using derivatives of hematin 失效
标题翻译：使用血红素衍生物聚合芳族单体
公开(公告)号：US20070021587A1
公开(公告)日：2007-01-25
申请号：US11337964
申请日：2006-01-23
申请人： Sukant Tripathy , Susan Tripathy , Lynne Samuelson , Ferdinando Bruno , Sucharita Roy , Ramaswamy Nagarajan , Jayant Kumar , Bon-Cheol Ku , Soo-Hyoung Lee
发明人： Sukant Tripathy , Susan Tripathy , Lynne Samuelson , Ferdinando Bruno , Sucharita Roy , Ramaswamy Nagarajan , Jayant Kumar , Bon-Cheol Ku , Soo-Hyoung Lee
IPC分类号： C08G73/00
CPC分类号： C07D487/22 , B01J31/1815 , B01J2231/14 , B01J2531/025 , B01J2531/842 , B82Y30/00 , C08F4/00 , C08G73/0266 , C08L25/18 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958
摘要： Hematin, a hydroxyferriprotoporphyrin, is derivatized with one or more non-proteinaceous amphipathic groups. The derivatized hematin can serve as a mimic of horseradish peroxidase in polymerizing aromatic monomers, such as aromatic compounds. These derivatized hematins can also be used as catalysts in polymerizing aromatic monomers, and can exhibit significantly greater catalytic activity than underivatized hematin in acidic solutions. In one embodiment, polymerization is in the presence of a template, along which aromatic monomers align. An assembled hematin includes alternating layers of hematin and a polyelectrolyte, which are deposited on an electrically charged substrate. Assembled hematin can also be used to polymerize aromatic monomers.
摘要翻译：血红素羟脯氨酸卟啉用一种或多种非蛋白质两亲性基团衍生化。衍生的血红蛋白可以作为芳香族单体如芳香族化合物的聚合中的辣根过氧化物酶的模拟物。这些衍生化的血红素也可以用作聚合芳族单体的催化剂，并且与酸性溶液中的未衍生的血红蛋白相比，可显示更大的催化活性。在一个实施方案中，聚合在模板存在下，芳族单体沿着该模板对准。组装的血红蛋白包括沉积在带电衬底上的血红蛋白和聚电解质的交替层。组装的血红蛋白也可用于聚合芳族单体。

7. 发明申请

US20050147990A1 Enzymatic template polymerization 审中-公开
公开(公告)号：US20050147990A1
公开(公告)日：2005-07-07
申请号：US10958452
申请日：2004-10-05
申请人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
IPC分类号： C08G73/02 , H01B1/12 , C12Q1/68 , C12P19/34
CPC分类号： C08G73/0266 , H01B1/128 , Y10S977/704 , Y10T436/143333
摘要： A conductive polymer is formed enzymatically in the presence of a polynucleotide template. The method includes combining at least one redox monomer with a polynucleotide template and a redox enzyme, such as horseradish peroxidase, to form a reaction mixture. The monomer aligns along the template before or during the polymerization. Therefore, the polynucleotide template thereby affects the molecular weight and conformation of the conductive polymer. When the conductive polymer is complexed to a polynucleotide duplex, the conformation of the polynucleotide duplex can be modulated by changing the oxidation state of the conductive polymer.

8. 发明申请

US20080090103A1 Polymerization of aromatic monomers using derivatives of hematin 失效
标题翻译：使用血红素衍生物聚合芳族单体
公开(公告)号：US20080090103A1
公开(公告)日：2008-04-17
申请号：US11904119
申请日：2007-09-26
申请人： Sukant Tripathy , Susan Tripathy , Lynne Samuelson , Ferdinando Bruno , Sucharita Roy , Ramaswamy Nagarajan , Jayant Kumar , Bon-Cheol Ku , Soo-Hyoung Lee
发明人： Sukant Tripathy , Susan Tripathy , Lynne Samuelson , Ferdinando Bruno , Sucharita Roy , Ramaswamy Nagarajan , Jayant Kumar , Bon-Cheol Ku , Soo-Hyoung Lee
IPC分类号： B32B23/08
CPC分类号： C07D487/22 , B01J31/1815 , B01J2231/14 , B01J2531/025 , B01J2531/842 , B82Y30/00 , C08F4/00 , C08G73/0266 , C08L25/18 , Y10T428/12861 , Y10T428/12951 , Y10T428/12958
摘要： Hematin, a hydroxyferriprotoporphyrin, is derivatized with one or more non-proteinaceous amphipathic groups. The derivatized hematin can serve as a mimic of horseradish peroxidase in polymerizing aromatic monomers, such as aromatic compounds. These derivatized hematins can also be used as catalysts in polymerizing aromatic monomers, and can exhibit significantly greater catalytic activity than underivatized hematin in acidic solutions. In one embodiment, polymerization is in the presence of a template, along which aromatic monomers align. An assembled hematin includes alternating layers of hematin and a polyelectrolyte, which are deposited on an electrically charged substrate. Assembled hematin can also be used to polymerize aromatic monomers.
摘要翻译：血红素羟脯氨酸卟啉用一种或多种非蛋白质两亲性基团衍生化。衍生的血红蛋白可以作为芳香族单体如芳香族化合物的聚合中的辣根过氧化物酶的模拟物。这些衍生化的血红素也可以用作聚合芳族单体的催化剂，并且与酸性溶液中的未衍生的血红蛋白相比，可显示更大的催化活性。在一个实施方案中，聚合在模板存在下，芳族单体沿着该模板对准。组装的血红蛋白包括沉积在带电衬底上的血红蛋白和聚电解质的交替层。组装的血红蛋白也可用于聚合芳族单体。

9. 发明申请

US20050084887A1 Enzymatic template polymerization 审中-公开
公开(公告)号：US20050084887A1
公开(公告)日：2005-04-21
申请号：US10958900
申请日：2004-10-05
申请人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
IPC分类号： C08G73/02 , H01B1/12 , C12Q1/68
CPC分类号： C08G73/0266 , H01B1/128 , Y10S977/704 , Y10T436/143333
摘要： A conductive polymer is formed enzymatically in the presence of a polynucleotide template. The method includes combining at least one redox monomer with a polynucleotide template and a redox enzyme, such as horseradish peroxidase, to form a reaction mixture. The monomer aligns along the template before or during the polymerization. Therefore, the polynucleotide template thereby affects the molecular weight and conformation of the conductive polymer. When the conductive polymer is complexed to a polynucleotide duplex, the conformation of the polynucleotide duplex can be modulated by changing the oxidation state of the conductive polymer.

10. 发明申请

US20060041110A1 ENZYMATIC TEMPLATE POLYMERIZATION 失效
标题翻译：酶模式聚合
公开(公告)号：US20060041110A1
公开(公告)日：2006-02-23
申请号：US10324736
申请日：2002-12-19
申请人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Lynne Samuelson , Ferdinando Bruno , Sukant Tripathy , Susan Tripathy , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
IPC分类号： C07H21/04 , C07H21/02
CPC分类号： C08G73/0266 , H01B1/128 , Y10S977/704 , Y10T436/143333
摘要： A conductive polymer is formed enzymatically in the presence of a polynucleotide template. The method includes combining at least one redox monomer with a polynucleotide template and a redox enzyme, such as horseradish peroxidase, to form a reaction mixture. The monomer aligns along the template before or during the polymerization. Therefore, the polynucleotide template thereby affects the molecular weight and conformation of the conductive polymer. When the conductive polymer is complexed to a polynucleotide duplex, the conformation of the polynucleotide duplex can be modulated by changing the oxidation state of the conductive polymer.
摘要翻译：在多核苷酸模板的存在下，酶促形成导电聚合物。该方法包括将至少一种氧化还原单体与多核苷酸模板和氧化还原酶如辣根过氧化物酶组合以形成反应混合物。在聚合之前或聚合过程中，单体沿着模板排列。因此，多核苷酸模板因此影响导电聚合物的分子量和构象。当导电聚合物与多核苷酸双链体复合时，可通过改变导电聚合物的氧化态来调节多核苷酸双链体的构象。

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