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1. 发明申请

US20130131256A1 Polymeric Compositions Useful as Rheology Modifiers and Methods for Making Such Compositions 有权
标题翻译：用作流变学改性剂的聚合组合物和制备这种组合物的方法
公开(公告)号：US20130131256A1
公开(公告)日：2013-05-23
申请号：US13745573
申请日：2013-01-18
申请人： Sudhin Datta , Jo Ann M. Canich , Liehpao O. Farng , Rainer Kolb , Vera Minak-Bernero , Eric B. Sirota , Thomas T. Sun , Mun-Fu Tse , Manika Varma-Nair
发明人： Sudhin Datta , Jo Ann M. Canich , Liehpao O. Farng , Rainer Kolb , Vera Minak-Bernero , Eric B. Sirota , Thomas T. Sun , Mun-Fu Tse , Manika Varma-Nair
IPC分类号： C08L23/16
CPC分类号： C10M143/08 , C08F4/65908 , C08F210/06 , C08F210/16 , C08L23/16 , C10M143/00 , C10M143/04 , C10M143/06 , C10M2205/022 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2220/033 , C10N2220/082 , C10N2230/02 , C10N2230/68 , C08F4/65927 , C10M2205/024 , C10M2209/062 , C08F2500/12 , C08F2500/03 , C10M2205/026 , C10M2205/028
摘要： Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity.
摘要翻译：公开了包含可用于改变润滑流体的流变性质的组成分散聚合物组合物和/或结晶度分散聚合物组合物的流变改性剂以及制备这种组合物的方法。组成分散的聚合物组合物由至少两种离散的乙烯共聚物组合物形成。结晶度分散聚合物组合物由具有至少两个离散值的残留结晶度的乙烯共聚物形成。

2. 发明授权

US08058461B2 Mono-indenyl transition metal compounds and polymerization therewith 有权
标题翻译：单茚基过渡金属化合物及其聚合反应
公开(公告)号：US08058461B2
公开(公告)日：2011-11-15
申请号：US12715068
申请日：2010-03-01
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
IPC分类号： C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： This invention relates to transition metal compounds, catalyst systems comprising said compounds and polymerization processes using such catalyst systems, where the transition metal compound is represented by the formula: This invention also relates to process to produce such compounds.
摘要翻译：本发明涉及过渡金属化合物，包含所述化合物的催化剂体系和使用这种催化剂体系的聚合方法，其中过渡金属化合物由下式表示：本发明还涉及制备这些化合物的方法。

3. 发明授权

US07868197B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US07868197B2
公开(公告)日：2011-01-11
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

4. 发明授权

US07763562B2 Heteroatom bridged metallocene compounds for olefin polymerization 有权
标题翻译：异质桥接金属茂化合物用于烯烃聚合
公开(公告)号：US07763562B2
公开(公告)日：2010-07-27
申请号：US11302998
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/6392 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2231/12 , B01J2531/48 , C08F4/65912 , C08F10/06 , C08F110/02 , C08F210/16 , C08F2420/06 , Y10S526/943 , C08F2500/03 , C08F210/14 , C08F2500/01 , C08F110/06 , C08F2500/20 , C08F210/06 , C08F10/00 , C08F4/65927
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

5. 发明申请

US20100113717A1 Process For Producing Substituted Metallocene Compounds For Olefin Polymerization 有权
标题翻译：用于生产用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US20100113717A1
公开(公告)日：2010-05-06
申请号：US12641123
申请日：2009-12-17
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/16 , C07F17/00 , B01J31/12 , B01J31/14
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

6. 发明授权

US07709670B2 Process for producing substituted metallocene compounds for olefin polymerization 失效
标题翻译：制备用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US07709670B2
公开(公告)日：2010-05-04
申请号：US11302997
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

7. 发明申请

US20090239999A1 Polymerization Process and Adhesives Therefrom 有权
标题翻译：聚合工艺和粘合剂
公开(公告)号：US20090239999A1
公开(公告)日：2009-09-24
申请号：US12480988
申请日：2009-06-09
申请人： Jo Ann M. Canich , Peijun Jiang
发明人： Jo Ann M. Canich , Peijun Jiang
IPC分类号： C08L23/00 , C08F110/06
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/17 , C08F2500/20
摘要： This invention relates to a propylene polymer comprising a component having a crystallinity of 10% or less and a component having a crystallinity of 20% or more, said propylene polymer having: a) a melting point of X ° C. or more where X=−0.0038(Tp)2+0.36(Tp)+150, where Tp is the temperature of polymerization in ° C.; b) an Mw of 10,000 g/mol or more; c) a heat of fusion of from 1-70 J/g; d) Stereodefects per 10,000 monomer units of Y or less where Y=2.35(Tp)−100 (where Tp is the temperature of polymerization in ° C.) for the portion of the blend that is insoluble in hexane at 23° C.; e) a dot T-Peel on Kraft paper of 1 N or more; and f) a branching factor of 0.98 or less, where the branching factor is the ratio of g′ measured at Mz to g′ measured at Mw, and process to produce such polymers.
摘要翻译：本发明涉及包含结晶度为10％以下的成分和结晶度为20％以上的成分的丙烯聚合物，所述丙烯类聚合物具有：a）熔点X℃以上，X = -0.0038（Tp）2 + 0.36（Tp）+150，其中Tp是以℃表示的聚合温度。 b）10,000g / mol以上的Mw; c）熔化热为1-70J / g; d）对于在23℃下不溶于己烷的共混物部分，每10,000单位单元的Y = 2.35（Tp）-100（其中Tp是聚合温度）的Y或更低的单位单位的立体缺陷度。 e）N型牛皮纸上的T型剥皮; 和f）0.98或更小的支化因子，其中支化因子是在Mw下测量的在Mz测量的g'与g'的比率，以及产生这种聚合物的方法。

8. 再颁专利

USRE40234E1 Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system 失效
标题翻译：用单环戊二烯基过渡金属催化剂体系生产结晶聚-α-烯烃的方法
公开(公告)号：USRE40234E1
公开(公告)日：2008-04-08
申请号：US07973107
申请日：1992-11-06
申请人： Jo Ann M. Canich
发明人： Jo Ann M. Canich
IPC分类号： C08F4/642
CPC分类号： C08F10/00 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F2500/17 , C08F2500/03 , C08F2500/24 , C08F2500/01 , C08F2500/10 , C08F232/08 , C08F2500/25 , C08F210/08 , C08F210/14 , C08F236/20
摘要： The invention is a catalytic process using a Group IV B transition metal component and an alumoxane component to polymerize α-olefins to produce high crystallinity and high molecular weight poly-α-olefins.
摘要翻译：本发明是使用IVB族过渡金属组分和铝氧烷组分聚合α-烯烃以产生高结晶度和高分子量聚-α-烯烃的催化方法。

9. 发明授权

US5502124A Transition metal olefin polymerization processes 失效
标题翻译：过渡金属烯烃聚合方法
公开(公告)号：US5502124A
公开(公告)日：1996-03-26
申请号：US445062
申请日：1995-05-19
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to processes using non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及使用可用作烯烃聚合催化剂的非4族过渡金属组合物的方法，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

10. 发明授权

US5096867A Monocyclopentadienyl transition metal olefin polymerization catalysts 失效
标题翻译：单环戊二烯基过渡金属烯烃聚合催化剂
公开(公告)号：US5096867A
公开(公告)日：1992-03-17
申请号：US581841
申请日：1990-09-13
申请人： Jo Ann M. Canich
发明人： Jo Ann M. Canich
IPC分类号： C07F7/10 , C07F7/28 , C07F17/00 , C08F4/02 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18
CPC分类号： C07F7/10 , C07F17/00 , C08F10/00 , C08F10/06 , C08F210/16 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： The invention is a catalyst system including a Group IV B transition metal component and an alumoxane component which may be employed to polymerize olefins to produce a high molecular weight polymer.
摘要翻译：本发明是包括IVB族过渡金属组分和铝氧烷组分的催化剂体系，其可用于聚合烯烃以产生高分子量聚合物。

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