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    • 6. 发明授权
    • Process for manufacture and improved manganese dioxide for electrochemical cells
    • 电化学电池的制造和改善二氧化锰的方法
    • US06585881B2
    • 2003-07-01
    • US09788754
    • 2001-02-20
    • Stuart M. DavisPeter R. MosesGary Miller
    • Stuart M. DavisPeter R. MosesGary Miller
    • C25B100
    • C01G45/02C01P2006/10C01P2006/12C01P2006/40C01P2006/80C25B1/21H01M4/50
    • A process for manufacture of manganese dioxide comprising subjecting an aqueous bath comprising manganese sulfate (MnSO4) and sulfuric acid (H2SO4) to electrolysis in a closed cell wherein the electrolysis bath is maintained at an elevated temperature above 110° C., preferably above 115° C. and at superatmospheric pressure. Desirably the bath can be maintained at an elevated temperature between about 115° C. and 155° C. The electrolysis is carried out preferably at elevated current density of between about 12.5 and 37 Amp/sq. ft (135 and 400 Amp/sq. meter) which allows for smaller or fewer electrolysis units. An MnO2 product having a specific surface area (SSA) within desired range of between 18-45 m2/g can be obtained. A doping agent, preferably a soluble titanium dopant is employed to help obtain the desired specific surface area (SSA) of the MnO2 product. The manganese dioxide product in zinc/MnO2 alkaline cells gives excellent service life, particularly in high power application.
    • 一种制造二氧化锰的方法,包括使包含硫酸锰(MnSO 4)和硫酸(H 2 SO 4)的水浴在闭孔中电解,其中电解浴保持在110℃以上,优选高于115℃的高温 C.和超大气压。 理想地,浴可以保持在约115℃和155℃之间的升高的温度。电解优选在升高的电流密度为约12.5A和37安培/平方米之间进行。 ft(135和400安培/平方米),允许更小或更少的电解单元。 可以获得具有在18-45m 2 / g之间的期望范围内的比表面积(SSA)的MnO 2产物。 使用掺杂剂,优选可溶性钛掺杂剂来帮助获得MnO 2产物的所需比表面积(SSA)。 锌/锰氧化物碱性电池中的二氧化锰产品具有优异的使用寿命,特别是在高功率应用中。