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    • 5. 发明授权
    • Photographic material and a process for its manufacture
    • 摄影材料及其制造工艺
    • US4510238A
    • 1985-04-09
    • US471556
    • 1983-03-02
    • Samuel B. KingstonGraham Evans
    • Samuel B. KingstonGraham Evans
    • G03C1/04C08L33/00C08L33/02C08L33/04C08L89/00G03C1/053G03C1/72
    • G03C1/053
    • Photographic material containing on a support at least one silver halide emulsion layer which contains as binders both gelatin and a polymer latex, wherein the particle size is less than 0.05 .mu.m, and which is obtained by emulsion polymerizing a monomer or monomer mixture which consists of an alkyl acrylate or an alkyl methacrylate or a monomer mixture comprising both an alkyl acrylate and an alkyl methacrylate or a mixture comprising an alkyl acrylate and/or an alkyl methacrylate together with up to 5% by weight of an ethylenically unsaturated copolymerizable acid and/or up to 30% by weight of other ethylenically unsaturated comonomers in the presence of at least 12% by weight of the monomers present of an anionic surfactant at a temperature of from 15.degree. C. to 90.degree. C. by use of a redox initiator system which is present to the extent of from 0.1% to 3% by weight of the monomers present.The latexes are of use to partially replace gelatin in photographic materials. These latex/gelatin binders are suitable for highspeed coating and drying processes and confer to the photographic materials an increased dimensional stability.
    • 在载体上含有至少一种含有明胶和聚合物胶乳作为粘合剂的卤化银乳剂层的照相材料,其中粒径小于0.05μm,其通过乳液聚合单体或单体混合物获得,所述单体或单体混合物由 丙烯酸烷基酯或甲基丙烯酸烷基酯或包含丙烯酸烷基酯和甲基丙烯酸烷基酯或包含丙烯酸烷基酯和/或甲基丙烯酸烷基酯的混合物的单体混合物,以及至多5重量%的烯键式不饱和可共聚酸和/或 在至少12重量%存在阴离子表面活性剂的单体的存在下,在15℃至90℃的温度下,使用氧化还原引发剂体系,存在至多30重量%的其它烯属不饱和共聚单体 其存在的量为所述单体的0.1重量%至3重量%。 胶乳可用于部分替代照相材料中的明胶。 这些胶乳/明胶粘合剂适用于高速涂布和干燥过程,并赋予照相材料增加的尺寸稳定性。