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    • 6. 发明授权
    • Process for the production of photographic images and photographic
materials used in this process
    • 用于生产此过程中使用的摄影图像和照相材料的方法
    • US4353974A
    • 1982-10-12
    • US237012
    • 1981-02-23
    • Terence C. WebbPatrick D. P. ThomasWilliam E. Long
    • Terence C. WebbPatrick D. P. ThomasWilliam E. Long
    • G03C7/02G03C1/00G03C5/16G03C5/29G03C5/30G03C7/28G03C8/08G03C5/54
    • G03C8/08G03C5/16G03C5/3028G03C7/28Y10S430/162
    • A process for the production of a photographic image which comprises(a) imagewise exposing a photographic assembly which comprises at least during a silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a layer substantive hydroxypyridone azamethine compound of the general formula ##STR1## wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl, amino or heterocyclic radical, Y represents hydrogen or hydroxy, --CN, --COOR.sup.1, --CONR.sup.1 R.sup.2 or --COR.sup.1 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical and Z is hydrogen or is --CN, --COOR.sup.3, --CONR.sup.3 R.sup.4, --SO.sub.3 H, --SO.sub.3.sup.- or --COR.sup.3, where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represent hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical, and E represents the atoms necessary to complete an optionally substituted heterocyclic or aromatic ring, and a support, there being optionally one or more interlayers between each of said components,(b) treating the exposed photographic assembly with an aqueous alkaline processing bath, containing a silver halide developer and(c) in the non-latent image areas, allowing the silver halide developer to diffuse in a counter-imagewise manner from the silver halide emulsion layer(s) to the layer containing the compound of formula (1) and there to bleach the compound to form a photographic dye image.The developers used in this process exhibit an increased stability against oxidizing agents.
    • 一种用于生产照相图像的方法,其包括(a)成像曝光照相组合件,其至少包括在卤化银显影步骤期间,任选地为超涂层,至少一个卤化银乳剂层,含有层 (1)其中R 1是氢或任选取代的烷基,芳烷基,环烷基,芳基,氨基或杂环基团的实质羟基吡啶酮氮杂酮化合物,Y代表氢或羟基,-CN,-COOR1,-CONR1R2或 -COR1或任选取代的烷基,芳烷基,环烷基,芳基或杂环基,Z是氢或是-CN,-COOR 3,-CONR 3 R 4,-SO 3 H,-SO 3 - 或-COR 3,其中R 1,R 2,R 3和R 4各自 独立地表示氢或任选取代的烷基,芳烷基,环烷基,芳基或杂环基,E表示完成任选取代的杂环或芳环所必需的原子,以及支持物, 每个所述组分之间的一个或多个中间层,(b)用含有卤化银显影剂的水性碱性处理浴处理曝光的照相组合物,和(c)在非潜像区域中,使卤化银显影剂扩散 以相对成像的方式从卤化银乳剂层到含有式(1)化合物的层,并漂白化合物以形成照相染料图像。 在该方法中使用的显影剂表现出对氧化剂的增加的稳定性。