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    • 8. 发明授权
    • Process for producing chemicals from oxygenate
    • 从含氧化合物生产化学品的方法
    • US06506954B1
    • 2003-01-14
    • US09687749
    • 2000-10-13
    • Stephen H. BrownLarry A. GreenMark F. MathiasDavid H. OlsonRobert A. WareWilliam A. WeberReuel Shinnar
    • Stephen H. BrownLarry A. GreenMark F. MathiasDavid H. OlsonRobert A. WareWilliam A. WeberReuel Shinnar
    • C07C120
    • C07C2/865C07C1/20C07C2/864C07C15/073C07C15/08C07C2521/02C07C2521/08C07C2521/10C07C2527/16C07C2529/40C07C2529/65C07C2529/70C07C2529/85Y02P30/42
    • There is provided a process for converting methanol and/or dimethyl ether to a product containing olefin, e.g., C2 to C4 olefins, C9+ aromatics and non-C9+ aromatics which comprises: 1) contacting a feed which contains methanol and/or dimethyl ether with a catalyst comprising a porous crystalline material, said contacting step being conducted in the presence of aromatics comprising C9 or C9+ aromatic compound produced in said process under conversion conditions including a temperature of 350° C. to 480° C. and a methanol partial pressure in excess of 10 psia (70 kPa), said porous crystalline material having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1 sec−1 to about 20 sec−1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa), and the aromatics being capable of alkylation by the methanol and/or dimethyl ether under said conversion conditions to provide a stream which contains C2 to C4 olefins and C9 or C9+ aromatic compound; 2) separating said stream to form a substantially C2 to C4 olefin product stream and a substantially C9 or C9+ aromatic compound stream; and 3) recycling at least a portion of said substantially C9 or C9+ aromatic compound stream to step 1).
    • 提供了将甲醇和/或二甲醚转化为含烯烃的产物,例如C 2 -C 4烯烃,C 9+芳族化合物和非C 9+芳族化合物的方法,其包括:1)将含有甲醇和/或二甲醚的进料与 包括多孔结晶材料的催化剂,所述接触步骤在包含C9或C9 +芳族化合物的芳族化合物存在下进行,所述芳族化合物在所述方法中产生的转化条件包括350℃至480℃的温度和甲醇分压 超过10psia(70kPa)时,当在120℃的温度下测量时,所述多孔结晶材料具有约0.1秒-1至约20秒-1的2,2-二甲基丁烷扩散参数和2,2 二甲基丁烷压力为60乇(8kPa),芳族化合物在所述转化条件下能够通过甲醇和/或二甲醚进行烷基化,以提供含有C 2 -C 4烯烃和C 9或C 9+芳族化合物的物流; 2) 使所述流形成基本上C2至C4烯烃产物流和基本上C9或C9 +芳族化合物流; 和3)将至少一部分所述基本上C9或C9 +芳族化合物流再循环到步骤1)。