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1. 发明申请

US20100008873A1 Use of benzotriazole derivatives for photostabilisation 有权
标题翻译：苯并三唑衍生物用于光稳定化
公开(公告)号：US20100008873A1
公开(公告)日：2010-01-14
申请号：US11919104
申请日：2006-04-20
申请人： Stefan Müller , Jochen Giesinger , Thomas Ehlis , Bernd Herzog , Peter König , Gilbert Kreyer , Katja Quass
发明人： Stefan Müller , Jochen Giesinger , Thomas Ehlis , Bernd Herzog , Peter König , Gilbert Kreyer , Katja Quass
IPC分类号： A61K8/49 , A61P17/04
CPC分类号： A61Q17/04 , A61K8/496 , A61K2800/52
摘要： Use of benzotriazole derivatives of formula (1), wherein R1 is C1-C30alkyl; C1C5alkoxy; C1-C5alkoxycarbonyl; C5-C7cycloalkyl; C6-C10aryl; aralkyl; —SO3M; a radical of formula (1a) R3 is hydrogen; C1C5alkyl; C1C5alkoxy; halogen, preferably Cl; or hydroxy; R4 and R5 are each independently of the other hydrogen; or d-C5alkyl; m is 1 or 2; n is O or 1; if m=1, R2 is hydrogen; unsubstituted or phenyl-substituted d-C1-C12alkyl; or C6-C10aryl; if m=2, R2 is the direct bond; or —(CH2)p—; and p is 1 to 3; for enhancing the photostability of cosmetic or dermatologic compositions comprising at least one further organic UV absorber.
摘要翻译：式（1）的苯并三唑衍生物的用途，其中R 1是C 1 -C 30烷基; C1C5烷氧基 C1-C5烷氧基羰基; C5-C7环烷基; C6-C10芳基; 芳烷基 -SO3M; 式（1a）的基团R 3是氢; C 1 -C 5烷基; C1C5烷氧基卤素，优选Cl; 或羟基; R4和R5各自独立地为氢; 或d-C 5烷基; m为1或2; n为0或1; 如果m = 1，则R2为氢; 未取代或苯基取代的d-C 1 -C 12烷基; 或C 6 -C 10芳基; 如果m = 2，则R2是直接键; 或 - （CH 2）p - ; p为1〜3; 用于增强包含至少一种另外的有机UV吸收剂的化妆品或皮肤病学组合物的光稳定性。

2. 发明授权

US08361446B2 Use of benzotriazole derivatives for photostabilisation 有权
标题翻译：苯并三唑衍生物用于光稳定化
公开(公告)号：US08361446B2
公开(公告)日：2013-01-29
申请号：US11919104
申请日：2006-04-20
申请人： Stefan Müller , Jochen Giesinger , Thomas Ehlis , Bernd Herzog , Peter König , Gilbert Kreyer , Katja Quass
发明人： Stefan Müller , Jochen Giesinger , Thomas Ehlis , Bernd Herzog , Peter König , Gilbert Kreyer , Katja Quass
IPC分类号： A61K8/49 , A61P17/04
CPC分类号： A61Q17/04 , A61K8/496 , A61K2800/52
摘要： Use of benzotriazole derivatives of formula (1), wherein R1 is C1-C30alkyl; C1C5alkoxy; C1-C5alkoxycarbonyl; C5-C7cycloalkyl; C6-C10aryl; aralkyl; —SO3M; a radical of formula (1a) R3 is hydrogen; C1C5alkyl; C1C5alkoxy; halogen, preferably Cl; or hydroxy; R4 and R5 are each independently of the other hydrogen; or d-C5alkyl; m is 1 or 2; n is O or 1; if m=1, R2 is hydrogen; unsubstituted or phenyl-substituted d-C1-C12alkyl; or C6-C10aryl; if m=2, R2 is the direct bond; or —(CH2)p—; and p is 1 to 3; for enhancing the photostability of cosmetic or dermatologic compositions comprising at least one further organic UV absorber.
摘要翻译：式（1）的苯并三唑衍生物的用途，其中R 1是C 1 -C 30烷基; C1C5烷氧基 C1-C5烷氧基羰基; C5-C7环烷基; C6-C10芳基; 芳烷基 -SO3M; 式（1a）的基团R 3是氢; C 1 -C 5烷基; C1C5烷氧基卤素，优选Cl; 或羟基; R4和R5各自独立地为氢; 或d-C 5烷基; m为1或2; n为0或1; 如果m = 1，则R2为氢; 未取代或苯基取代的d-C 1 -C 12烷基; 或C 6 -C 10芳基; 如果m = 2，则R2是直接键; 或 - （CH 2）p - ; p为1〜3; 用于增强包含至少一种另外的有机UV吸收剂的化妆品或皮肤病学组合物的光稳定性。

3. 发明授权

US08119107B2 Photo-stable cosmetic or dermatological compositions 有权
标题翻译：光稳定化妆品或皮肤病学成分
公开(公告)号：US08119107B2
公开(公告)日：2012-02-21
申请号：US11663610
申请日：2005-09-19
申请人： Stefan Müller , Bernd Herzog , Katja Quass
发明人： Stefan Müller , Bernd Herzog , Katja Quass
IPC分类号： A61Q17/02
CPC分类号： A61K8/066 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/415 , A61K8/893 , A61K8/97 , A61K2800/52 , A61K2800/57 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00
摘要： Disclosed is the use of an effective photo-stabilizing amount of stabilizing agent (a) selected from a diphenylacrylate UV filter (a1), a benzylidene amphor derivative (a2), an organosiloxane comprising benzalemalonate groups (a3), a fluoren derivative (a4), and a naphthalene dicarboxylic acid derivative (a5) for improving the stability with respect to UV radiation of a cosmetic or dermatological composition comprising a UV filter combination of at least one dibenzoylmethane derivative (b) and of at least one specific amino-substituted 2-hydroxybenzophenone derivative (c).
摘要翻译：公开了使用有效的光稳定剂量的选自二苯基丙烯酸酯紫外线过滤器（a1），亚苄基双酚衍生物（a2），包含亚苄基丙二酸酯基（a3）的有机硅氧烷，芴衍生物（a4）和用于提高化妆品或皮肤病学组合物的UV辐射稳定性的萘二羧酸衍生物（a5），其包含至少一种二苯甲酰甲烷衍生物（b）和至少一种特定氨基取代的2- 羟基二苯甲酮衍生物（c）。

4. 发明申请

US20100143272A1 Photo-stable cosmetic or dermatological compositions 有权
标题翻译：光稳定化妆品或皮肤病学成分
公开(公告)号：US20100143272A1
公开(公告)日：2010-06-10
申请号：US11663610
申请日：2005-09-19
申请人： Stefan Müller , Bernd Herzog , Katja Quass
发明人： Stefan Müller , Bernd Herzog , Katja Quass
IPC分类号： A61K8/36 , A61Q17/04
CPC分类号： A61K8/066 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/415 , A61K8/893 , A61K8/97 , A61K2800/52 , A61K2800/57 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00
摘要： Disclosed is the use of an effective photo-stabilizing amount of stabilizing agent (a) selected from a diphenylacrylate UV filter (a1), a benzylidene amphor derivative (a2), an organosiloxane comprising benzalemalonate groups (a3), a fluoren derivative (a4), and a naphthalene dicarboxylic acid derivative (a5) for improving the stability with respect to UV radiation of a cosmetic or dermatological composition comprising a UV filter combination of at least one dibenzoylmethane derivative (b) and of at least one specific amino-substituted 2-hydroxybenzophenone derivative (c).
摘要翻译：公开了使用有效的光稳定剂量的选自二苯基丙烯酸酯紫外线过滤器（a1），亚苄基双酚衍生物（a2），包含亚苄基丙二酸酯基（a3）的有机硅氧烷，芴衍生物（a4）和用于提高化妆品或皮肤病学组合物的UV辐射稳定性的萘二羧酸衍生物（a5），其包含至少一种二苯甲酰甲烷衍生物（b）和至少一种特定氨基取代的2- 羟基二苯甲酮衍生物（c）。

5. 发明授权

US09066872B2 Stabilization of cosmetic compositions 有权
标题翻译：化妆品组合物的稳定化
公开(公告)号：US09066872B2
公开(公告)日：2015-06-30
申请号：US12673596
申请日：2008-08-26
申请人： Bernd Herzog , Katja Quass , Stephanie Acker
发明人： Bernd Herzog , Katja Quass , Stephanie Acker
IPC分类号： A01N43/66 , A61K31/53 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/49 , A61Q17/04
CPC分类号： A61K8/4973 , A61K8/35 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/4966 , A61K2800/592 , A61Q17/04
摘要： Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) di-alkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; —COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or —COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (C2) dibenzoylmethane derivatives.
摘要翻译：公开了使用选自（a1）二苯基丙烯酸酯的UV吸收剂; （a2）式（1）的羟基苯基三嗪，其中R 1，R 2和R 3彼此独立地是C 1 -C 18烷基; （a3）式（2）的苯并三唑衍生物，其中R4是至少三个具有8至30个碳原子并具有式（2a）的异构支链仲烷基的随机统计混合物; E1是直链C1-C14烷基; E2是直链C4-C15烷基; 其中E1加E2的总碳原子数为7〜29; R5是C1-C5烷基; 和（a4）萘二甲酸二烷基酯; 用于稳定化妆品组合物，其包含（b）式（3）的对称三嗪衍生物，其中A是式（3a）的基团; 或（3b）R 6和R 10彼此独立地为氢; C1-C18烷基; 或C6-C12芳基; R 7，R 8和R 9彼此独立地为氢; 或式（3c）的基团，其中在式（3a）中，基团R7，R8和R9中的至少一个是式（3c）的基团; R 11，R 12，R 13和R 14彼此独立地为氢; 羟基; 卤素; C1-C18烷基; C1-C18烷氧基; C6-C12芳基; 联苯基 C 6 -C 12芳氧基; C1-C18烷硫基; 羧基; -COOM; C 1 -C 18烷基羧基; 氨基羰基; 单或二C1-C18烷基氨基; C1-C10酰氨基; 或-COOH; M是碱金属离子; x为1或2; y为2〜10的数; 和选自（c1）肉桂酸衍生物的紫外线吸收剂; 和（C2）二苯甲酰甲烷衍生物。

6. 发明申请

US20110104088A1 STABILIZATION OF COSMETIC COMPOSITIONS 有权
标题翻译：化妆品组合物的稳定性
公开(公告)号：US20110104088A1
公开(公告)日：2011-05-05
申请号：US12673596
申请日：2008-08-26
申请人： Bernd Herzog , Katja Quass , Stephanie Acker
发明人： Bernd Herzog , Katja Quass , Stephanie Acker
IPC分类号： A61K8/49 , A61Q17/04
CPC分类号： A61K8/4973 , A61K8/35 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/4966 , A61K2800/592 , A61Q17/04
摘要： Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) di-alkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; —COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or —COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (C2) dibenzoylmethane derivatives.
摘要翻译：公开了使用选自（a1）二苯基丙烯酸酯的UV吸收剂; （a2）式（1）的羟基苯基三嗪，其中R 1，R 2和R 3彼此独立地是C 1 -C 18烷基; （a3）式（2）的苯并三唑衍生物，其中R4是至少三个具有8至30个碳原子并具有式（2a）的异构支链仲烷基的随机统计混合物; E1是直链C1-C14烷基; E2是直链C4-C15烷基; 其中E1加E2的总碳原子数为7〜29; R5是C1-C5烷基; 和（a4）萘二甲酸二烷基酯; 用于稳定化妆品组合物，其包含（b）式（3）的对称三嗪衍生物，其中A是式（3a）的基团; 或（3b）R 6和R 10彼此独立地为氢; C1-C18烷基; 或C6-C12芳基; R 7，R 8和R 9彼此独立地为氢; 或式（3c）的基团，其中在式（3a）中，基团R7，R8和R9中的至少一个是式（3c）的基团; R 11，R 12，R 13和R 14彼此独立地为氢; 羟基; 卤素; C1-C18烷基; C1-C18烷氧基; C6-C12芳基; 联苯基 C 6 -C 12芳氧基; C1-C18烷硫基; 羧基; -COOM; C 1 -C 18烷基羧基; 氨基羰基; 单或二C1-C18烷基氨基; C1-C10酰氨基; 或-COOH; M是碱金属离子; x为1或2; y为2〜10的数; 和选自（c1）肉桂酸衍生物的紫外线吸收剂; 和（C2）二苯甲酰甲烷衍生物。

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