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    • 1. 发明授权
    • Process for preparing clustered functional polyorganosiloxanes, and methods for their use
    • 聚簇功能聚有机硅氧烷的制备方法及其使用方法
    • US09593209B2
    • 2017-03-14
    • US13508375
    • 2010-11-03
    • Stanton DentKai SuLauren TongeJames Tonge
    • Stanton DentKai SuLauren TongeJames Tonge
    • C08G77/20C08G77/50C08L83/14
    • C08G77/50C08L83/14
    • A hydrosilylation process is used to prepare a polyorganosiloxane having clustered functional groups at the polyorganosiloxane chain terminals. The ingredients used in the process include a) a polyorganosiloxane having an average of at least 2 aliphatically unsaturated organic groups per molecule, b) a polyorganohydrogensiloxane having an average of 4 to 15 silicon atoms per molecule and at least 4 silicon bonded hydrogen atoms for each aliphatically unsaturated organic group in ingredient a), c) a reactive species having, per molecule at least 1 aliphatically unsaturated organic group and 1 or more curable groups; and d) a hydrosilylation catalyst. The resulting clustered functional polyorganosiloxane is useful in a curable silicone composition for electronics applications.
    • 使用氢化硅烷化方法制备聚有机硅氧烷链末端具有聚簇官能团的聚有机硅氧烷。 在该方法中使用的成分包括a)每分子平均具有至少2个不饱和有机基团的聚有机硅氧烷,b)每个分子平均具有4至15个硅原子的平均有机硅氢氧化硅和每个分子具有至少4个硅键合的氢原子 成分a)中的脂族不饱和有机基团,c)每分子具有至少1个脂族不饱和有机基团和1个或更多个可固化基团的反应性物质; 和d)氢化硅烷化催化剂。 所得聚集的官能聚有机硅氧烷可用于电子应用的可固化硅氧烷组合物。
    • 2. 发明申请
    • Process for Preparing Clustered Functional Polyorganosiloxanes, and Methods for Their Use
    • 制备聚合功能性聚有机硅氧烷的方法及其使用方法
    • US20120245272A1
    • 2012-09-27
    • US13508375
    • 2010-11-03
    • Stanton DentKai SuLauren TongeJames Tonge
    • Stanton DentKai SuLauren TongeJames Tonge
    • C08F8/00C08L83/07
    • C08G77/50C08L83/14
    • A hydrosilylation process is used to prepare a polyorganosiloxane having clustered functional groups at the polyorganosiloxane chain terminals. The ingredients used in the process include a) a polyorganosiloxane having an average of at least 2 aliphatically unsaturated organic groups per molecule, b) a polyorganohydrogensiloxane having an average of 4 to 15 silicon atoms per molecule and at least 4 silicon bonded hydrogen atoms for each aliphatically unsaturated organic group in ingredient a), c) a reactive species having, per molecule at least 1 aliphatically unsaturated organic group and 1 or more curable groups; and d) a hydrosilylation catalyst. The resulting clustered functional polyorganosiloxane is useful in a curable silicone composition for electronics applications.
    • 使用氢化硅烷化方法制备聚有机硅氧烷链末端具有聚簇官能团的聚有机硅氧烷。 在该方法中使用的成分包括a)每分子平均具有至少2个不饱和有机基团的聚有机硅氧烷,b)每个分子平均具有4至15个硅原子的平均有机硅氢氧化硅和每个分子具有至少4个硅键合的氢原子 成分a)中的脂族不饱和有机基团,c)每分子具有至少1个脂族不饱和有机基团和1个或更多个可固化基团的反应性物质; 和d)氢化硅烷化催化剂。 所得聚集的官能聚有机硅氧烷可用于电子应用的可固化硅氧烷组合物。
    • 3. 发明授权
    • Synthesis of polymer nanostructures with conductance switching properties
    • 具有电导转换性能的聚合物纳米结构的合成
    • US08968602B2
    • 2015-03-03
    • US12441706
    • 2007-10-02
    • Kai SuNurxat NurajeLingzhi ZhangHiroshi MatsuiNan Loh Yang
    • Kai SuNurxat NurajeLingzhi ZhangHiroshi MatsuiNan Loh Yang
    • H01B1/00H01M4/88H01L51/00H01B1/12H01L51/05
    • H01L51/0037H01B1/124H01L51/0575H01L51/0591
    • The present invention is directed to crystalline organic polymer nanoparticles comprising a conductive organic polymer; wherein the crystalline organic polymer nanoparticles have a size of from 10 nm to 200 nm and exhibits two current-voltage states: (1) a high resistance current-voltage state, and (2) a low resistance current-voltage state, wherein when a first positive threshold voltage (Vth1) or higher positive voltage, or a second negative threshold voltage (Vth2) or higher negative voltage is applied to the nanoparticle, the nanoparticle exhibits the low-resistance current-voltage state, and when a voltage less positive than the first positive threshold voltage or a voltage less negative than the second negative threshold voltage is applied to the nanoparticle, the nanoparticle exhibits the high-resistance current-voltage state. The present invention is also directed methods of manufacturing the nanoparticles using novel interfacial oxidative polymerization techniques.
    • 本发明涉及包含导电有机聚合物的结晶有机聚合物纳米颗粒; 其中所述结晶有机聚合物纳米颗粒具有10nm至200nm的尺寸,并且具有两种电流 - 电压状态:(1)高电阻电流 - 电压状态,和(2)低电阻电流 - 电压状态,其中当 第一正阈值电压(Vth1)或更高的正电压或第二负阈值电压(Vth2)或更高的负电压施加到纳米颗粒,纳米颗粒呈现低电阻电流 - 电压状态,并且当电压小于 将第一正阈值电压或比第二负阈值电压小的电压施加到纳米颗粒,纳米颗粒呈现高电阻电流 - 电压状态。 本发明还涉及使用新的界面氧化聚合技术制造纳米颗粒的方法。
    • 4. 发明授权
    • Composition including a siloxane and a method of forming the same
    • 包含硅氧烷的组合物及其形成方法
    • US08222364B2
    • 2012-07-17
    • US12296815
    • 2007-04-10
    • Kai SuDuane R. BujalskiPeter Y. LoEric Kolb
    • Kai SuDuane R. BujalskiPeter Y. LoEric Kolb
    • C08G77/04C08G77/12
    • C08G77/38C08G77/12C08G77/20C08G77/70C08L83/04C08L83/00
    • A composition includes a siloxane of the formula: (RMe2SiO1/2)a(MeRSiO2/2)b(RSiO3/2)c(SiO4/2)d wherein a is at least 2, b is from 3 to 20, c is from 0 to 10, d is from 0 to 10, and each R is independently of the formula —CR′2—CR′2—Y—Z or CR′2—CR′2—Z, wherein each R′ is independently a hydrogen atom or a C1 to C10 hydrocarbyl free of aliphatic unsaturation so long as at least one R′ is a hydrogen atom, Y is a divalent organic group, and Z is a polycyclic group containing at least one aromatic ring. A method of making the siloxane includes charging (HMe2SiO1/2)a(MeHSiO2/2)b(HSiO3/2)c(SiO4/2)d, a platinum catalyst, and an alkene of the formula CR′2═CR′—Y—Z or CR′2═CR′—Z into a reactor to form the siloxane. The siloxane is useful as a component in holographic storage media for photopolymer-based holographic data storage applications. The siloxane exhibits excellent compatibility when mixed with a polymerizable component before the polymerizable component is cured. Furthermore, the siloxane exhibits excellent diffusion from polymers of the polymerizable component after partial and complete curing. The siloxane also has a high refractive index while maintaining the excellent compatibility and diffusion properties when mixed with polymerizable component.
    • 组合物包括下式的硅氧烷:(RMe2SiO1 / 2)a(MeRSiO2 / 2)b(RSiO3 / 2)c(SiO4 / 2)d其中a为至少2,b为3至20,c为 0至10,d为0至10,并且每个R独立于式-CR'2-CR'2-Y-Z或CR'2-CR'2-Z,其中每个R'独立地为氢 原子或不含脂肪族不饱和键的C1〜C10烃基,只要至少一个R'为氢原子,Y为二价有机基团,Z为含有至少一个芳环的多环基团。 制备硅氧烷的方法包括将(Mee 2 SiO 2/2)a(MeHSiO 2/2)b(HSiO 3/2)c(SiO 4/2)d,铂催化剂和式CR'2 = CR'- Y-Z或CR'2 = CR'-Z进入反应器以形成硅氧烷。 硅氧烷可用作用于基于光聚合物的全息数据存储应用的全息存储介质中的组分。 当可聚合组分固化之前,与可聚合组分混合时,硅氧烷显示出优异的相容性。 此外,部分和完全固化后,硅氧烷表现出可聚合组分的聚合物的极好扩散。 当与可聚合组分混合时,硅氧烷还具有高折射率,同时保持优异的相容性和扩散性。
    • 5. 发明申请
    • SYNTHESIS OF POLYMER NANOSTRUCTURES WITH CONDUCTANCE SWITCHING PROPERTIES
    • 具有导电开关特性的聚合物纳米结构的合成
    • US20090314998A1
    • 2009-12-24
    • US12441706
    • 2007-10-02
    • Kai SuNurxat NurajeLingzhi ZhangHiroshi MatsuiNan Loh Yang
    • Kai SuNurxat NurajeLingzhi ZhangHiroshi MatsuiNan Loh Yang
    • H01B1/12
    • H01L51/0037H01B1/124H01L51/0575H01L51/0591
    • The present invention is directed to crystalline organic polymer nanoparticles comprising a conductive organic polymer; wherein the crystalline organic polymer nanoparticles have a size of from 10 nm to 200 nm and exhibits two current-voltage states: (1) a high resistance current-voltage state, and (2) a low resistance current-voltage state, wherein when a first positive threshold voltage (Vth1) or higher positive voltage, or a second negative threshold voltage (Vth2) or higher negative voltage is applied to the nanoparticle, the nanoparticle exhibits the low-resistance current-voltage state, and when a voltage less positive than the first positive threshold voltage or a voltage less negative than the second negative threshold voltage is applied to the nanoparticle, the nanoparticle exhibits the high-resistance current-voltage state. The present invention is also directed methods of manufacturing the nanoparticles using novel interfacial oxidative polymerization techniques.
    • 本发明涉及包含导电有机聚合物的结晶有机聚合物纳米颗粒; 其中所述结晶有机聚合物纳米颗粒具有10nm至200nm的尺寸,并且具有两种电流 - 电压状态:(1)高电阻电流 - 电压状态,和(2)低电阻电流 - 电压状态,其中当 第一正阈值电压(Vth1)或更高的正电压或第二负阈值电压(Vth2)或更高的负电压施加到纳米颗粒,纳米颗粒呈现低电阻电流 - 电压状态,并且当电压小于 将第一正阈值电压或比第二负阈值电压小的电压施加到纳米颗粒,纳米颗粒呈现高电阻电流 - 电压状态。 本发明还涉及使用新的界面氧化聚合技术制造纳米颗粒的方法。
    • 8. 发明申请
    • Method and apparatus for holding a mold assembly and molding an optical lens using the same
    • 用于保持模具组件并使用其组装光学透镜的方法和装置
    • US20050001140A1
    • 2005-01-06
    • US10894684
    • 2004-07-20
    • Kai SuRichard Lu
    • Kai SuRichard Lu
    • B29D11/00
    • B29D11/00413B29D11/00432B29D11/00528B29L2011/0016Y10S425/808Y10T428/31909
    • An apparatus and method for holding a mold assembly and molding an optical lens using the same. In one aspect, the present invention provides an apparatus for holding a mold assembly, wherein the mold assembly includes a front mold, a back mold and a strip wrapping around the edges of the front mold and back mold to form a sleeve. In one embodiment, the apparatus includes a first portion and a second portion. The first portion has a top part, a bottom part, and a middle part connecting the top part and the bottom part, the middle part including a base and a holder coupled to the base. The second portion has a top part, a bottom part, and a middle part connecting the top part and the bottom part, the middle part including a base and a holder coupled to the base. The first portion and the second portion are pivotally coupled together at the bottom parts so that the top part of the first portion and the top part of the second portion can be closed to define a housing for receiving the mold assembly therein, wherein the top part of the first portion and the top part of the second portion can also be opened for receiving the mold assembly in the housing.
    • 一种用于保持模具组件并使用其组装光学透镜的装置和方法。 一方面,本发明提供了一种用于保持模具组件的装置,其中模具组件包括前模具,后模具和围绕前模和后模的边缘缠绕以形成套筒的条带。 在一个实施例中,该装置包括第一部分和第二部分。 第一部分具有顶部,底部和连接顶部和底部的中间部分,中间部分包括基部和联接到基部的保持器。 第二部分具有顶部,底部和连接顶部和底部的中间部分,中间部分包括基部和联接到基部的保持器。 第一部分和第二部分在底部枢转地联接在一起,使得第一部分的顶部和第二部分的顶部可以被关闭以限定用于在其中容纳模具组件的壳体,其中顶部 的第一部分和第二部分的顶部也可以被打开用于在壳体中接收模具组件。
    • 9. 发明授权
    • Process of producing fibers from curable alk-1-enyl ether functional
siloxane resins
    • 由可固化烷-1-烯基醚官能的硅氧烷树脂生产纤维的方法
    • US5814271A
    • 1998-09-29
    • US903553
    • 1997-07-31
    • Duane Ray BujalskiKai SuGregg Alan Zank
    • Duane Ray BujalskiKai SuGregg Alan Zank
    • C08L83/07C04B35/571C08G77/20C08G77/50C08G77/58C08L83/14D01F9/10C04B35/56
    • C08G77/58C04B35/571C08G77/50C08L83/14
    • The present invention relates to a method for preparing a ceramic fiber wherein the method comprises (A) forming a green fiber from an alk-1-enyl ether functional siloxane resin of the general formula (R.sup.1 SiO.sub.3/2).sub.q (R.sup.2 SiO.sub.3/2).sub.r (R.sup.1.sub.w R.sup.2.sub.x RSiO.sub.(3-w-x)/2).sub.s (R.sup.1.sub.w R.sup.2.sub.x R.sup.3 SiO.sub.(3-w-x)/2).sub.t wherein R is an alk-1-enyl ether group; each R.sup.1 is selected from an aryl group having from 6 to 10 carbon atoms; each R.sup.2 is selected from an alkyl group having from 1 to 4 carbon atoms; R.sup.3 is an alkenyl group having from 2 to 10 carbon atoms; w has a value of 0, 1 or 2; x has a value of 0, 1, or 2 with the provisio that w+x.ltoreq.2; q has a value of 0 to 0.98; r has a value of 0 to 0.98; s is greater than zero; t.gtoreq.0; s+t=0.02 to 0.5 and q+r+s+t=1; (B) curing the green fiber to render it non-fusible; and (C) heating the non-fusible fiber in an inert environment to a temperature above 800.degree. C. to convert it to a ceramic fiber.
    • 本发明涉及一种制备陶瓷纤维的方法,其中所述方法包括(A)由通式(R1SiO3 / 2)q(R2SiO3 / 2)r的烷-1-烯基醚官能的硅氧烷树脂形成绿色纤维 (R1wR2xRSiO(3-wx)/ 2)s(R1wR2xR3SiO(3-wx)/ 2)t其中R是烷-1-烯基醚基团; 每个R 1选自具有6至10个碳原子的芳基; 每个R 2选自具有1至4个碳原子的烷基; R3是具有2至10个碳原子的烯基; w的值为0,1或2; x的值为0,1或2,条件是w + x = 2; q的值为0〜0.98; r的值为0〜0.98; s大于零; t> / = 0; s + t = 0.02〜0.5,q + r + s + t = 1; (B)固化绿色纤维使其不易熔; 和(C)将惰性纤维在惰性环境中加热到高于800℃的温度,将其转化成陶瓷纤维。