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    • 3. 发明授权
    • Ceramic ferroelectric composite materials with enhanced electronic
properties BSTO-Mg based compound-rare earth oxide
    • 具有增强电子性能的陶瓷铁电复合材料BSTO-Mg基复合稀土氧化物
    • US6074971A
    • 2000-06-13
    • US191546
    • 1998-11-13
    • Luna H. ChiuLouise C. SenguptaSteven StowellSomnath SenguptaJennifer Synowczynski
    • Luna H. ChiuLouise C. SenguptaSteven StowellSomnath SenguptaJennifer Synowczynski
    • C04B35/053C04B35/465C04B35/468C04B35/47
    • C04B35/053C04B35/465
    • Ceramic ferroelectric composite materials comprising barium strontium titte/magnesium and oxygen-containing compound composite further doped with rare earth (lanthanide) oxides. More particularly, these inventive composites are comprised of Ba.sub.1-x Sr.sub.x TiO.sub.3 /Mg--O based compound/rare earth oxide composite, wherein x is greater than or equal to 0.0 but less than or equal to 1.0, and wherein the weight ratio of BSTO to Mg compound may range from 99.75-20 wt. % BSTO to 0.25-80 wt. % Mg compound, and wherein said rare earth oxide additive comprises less than about 10 mole percent of the composite. The rare earth oxides of the composite include all oxides of the lanthanide series elements including scandium and yttrium, as well as combinations thereof. The magnesium-based compound may be selected from the group consisting of MgO, MgZrO.sub.3, MgZrSrTiO.sub.3, MgTiO.sub.3, and MgCO.sub.3. This new class of composite materials has enhanced electronic properties including: low dielectric constants; substantially decreased electronic loss (low loss tangents); increased tunability; increased temperature stability; decreased sintering temperatures; and low curie temperatures. The electronic properties of these new materials can be tailored for various applications including phased array antenna systems, capacitors, transmission wire, wireless communication, and pyroelectric guidance devices.
    • 包含钛酸锶钡/镁的陶瓷铁电复合材料和进一步掺杂稀土(镧系元素)氧化物的含氧化合物复合材料。 更具体地说,这些本发明的复合材料包括Ba1-xSrxTiO3 / Mg-O基化合物/稀土氧化物复合材料,其中x大于或等于0.0但小于或等于1.0,并且其中BSTO与Mg的重量比 化合物可以为99.75-20wt。 %BSTO为0.25-80wt。 %Mg化合物,并且其中所述稀土氧化物添加剂包含小于约10摩尔%的复合材料。 复合材料的稀土氧化物包括镧系元素的所有氧化物,包括钪和钇,以及它们的组合。 镁基化合物可以选自MgO,MgZrO3,MgZrSrTiO3,MgTiO3和MgCO3。 这种新型复合材料具有增强的电子性能,包括:低介电常数; 电子损失大幅减少(低损耗切线); 增加可调性; 提高温度稳定性; 降低烧结温度; 和低居里温度。 这些新材料的电子特性可以适用于各种应用,包括相控阵天线系统,电容器,传输线,无线通信和热释电引导装置。